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  • Inorganic Chemistry  (3)
  • Electronic atlas
  • Lung surfactant secretion
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  • 1
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Biochimica et Biophysica Acta (BBA)/Biomembranes 939 (1988), S. 449-458 
    ISSN: 0005-2736
    Keywords: (Rat lung) ; Fluorescent probe ; Lung surfactant secretion ; Sodium ion/proton antiport ; Type II cell ; pH, intracellular
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Biology , Chemistry and Pharmacology , Medicine , Physics
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Biochimica et Biophysica Acta (BBA)/Biomembranes 902 (1987), S. 317-326 
    ISSN: 0005-2736
    Keywords: (Rat lung) ; Carbocyanine dye ; Lung surfactant secretion ; Terbutaline ; Tetradecanoylphorbol acetate ; Tetraphenylmethylphosphonium ion ; Transmembrane potential ; Type II cell
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Biology , Chemistry and Pharmacology , Medicine , Physics
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 107 (1974), S. 3818-3834 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Systematic Investigations on the Behaviour of Organotin Compounds toward. Liquid Sulfur Dioxide, VII. Cleavage of Tin-Oxygen Bond with So2The hexaorganodistannoxanes 1a and b react with SO2 to yield bis(triorganotin) sulfites 2a, b. At higher temperatures, a disproportionation takes place yielding the sulfinates 3a, b resp. 5a, b and diorganotin sulfites 4a, b; possible reaction mechanisms are discussed. As by-products result the sulfates 6a and 8a as well as the thioester 7a. Triorganotin hydroxides 10a-c react in the same way. 4a-c are also obtained by addition of SO2 to diorganotin oxides 9a-c. The triorganotin alkoxides and phenoxides 11 and 13 add 1 mole of SO2 yielding the very sensitive triorganotin organylsulfites of which only 12 could be isolated. The constitution of the newly prepared compounds has been established by means of their i.r. and 1H n.m.r. spectra.
    Notes: Die Hexaorganodistannoxane 1a und b reagieren mit SO2 unter milden Bedingungen zu den Bis(triorganozinn)-sulfiten 2a, b. Bei höheren Temperaturen erfolgt dagegen eine Disproportionierung zu den Sulfinaten 3a, b bzw. 5a, b und Diorganozinn-sulfiten 4a, b; mögliche Reaktionsmechanismen werden diskutiert. Als Nebenprodukte entstehen die Sulfate 6a und 8a sowie der Thioester 7a. Analog verhalten sich die Triorganozinn-hydroxide 10a-c. 4a-c erhält man auch durch Addition von SO2 an Diorganozinn-oxide 9a-c. Die Triorganozinn-alkoxide und -phenoxide 11 und 13 addieren 1 mol SO2 unter Bildung der sehr hydrolyseempfindlichen Triorganozinn-organylsulfite, von denen nur 12 isoliert werden konnte. Die Konstitution der neu dargestellten Verbindungen wurde mit Hilfe ihrer IR- und 1H-NMR-Spektren gesichert.
    Additional Material: 4 Tab.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 94 (1961), S. 392-397 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Tertiäre aromatische sowie aliphatisch- bzw. cycloaliphatisch-aromatische Phosphine reagieren mit Kalium oder Natrium unter Abspaltung eines Aryl oder Alkylrestes und Bildung von Alkaliphosphiden des Typs MePR2 bzw. MePRR'. Für eine Spaltungsreaktion ist die Anwesenheit eines aromatischen Restes im tert. Phosphin Voraussetzung. Während sich tert. aliphatische und cycloaliphatische Phosphine gegenüber Kalium indifferent verhalten, liefert bei analoger Reaktion beispielsweise Diäthylphenylphosphin Kalium-äthyl-phenyl-phosphid. Die Alkali-phosphide sind sehr reaktionsfähig und dienen zur Synthese weiterer phosphororganischer Verbindungen. Sie liefern bei der oxydativen Hydrolyse die entsprechenden Phosphinsäuren und mit Alkylhalogeniden Phosphoniumsalze.
    Type of Medium: Electronic Resource
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  • 5
    ISSN: 0044-2313
    Keywords: Silanediyldiphosphinite ; chelate complexes ; synthesis ; structure, multinuclear NMR spectroscopy ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Synthese eines neuen Silandiyldiphosphinits tBu2Si(OPPh2)2 und seine Reaktionen mit den Norbornadien-Komplexen C7H8M(CO)4 (M = Cr, Mo, W). Kristallstrukturen von cis-M(CO)4[tBu2Si(OPPh2)2] (M = Cr, Mo)Silandiyldiphosphinit tBu2Si(OPPh2)2 1 wurde dargestellt. 1 reagiert mit den Norbornadienkomplexen C7H8M(CO)4 (M = Cr, Mo, W) zu sechsgliedrigen Chelaten des Typs cis-M(CO)4[tBu2Si(OPPh2)2] 2-4. Die Kristallstrukturen des Chromkomplexes Cr(CO)4[tBuSi(OPPh2)2] 2 und des Molybdänkomplexes Mo(CO)4[tBuSi(OPPh2)2] 3 wurden bestimmt. Beide kristallisieren triklin (Raumgruppe P1) mit den Zellkonstanten: (2) a = 1 093(3) pm, b = 1 477(5) pm und c = 1 542(5) pm; α = 108.4(2)°, b̃ = 103.87(11)° und b̃ = 104.57(10)°; U = 2.143(12) nm3; Z = 2; (3) a = 1097.8(2) pm, b = 1 483.7(2) pm und c = 1 554.3(2) pm; α = 108.10(1)°, b̃ = 103.956(6)° und γ = 104.213(7)°; U = 2.1899(6) nm3; Z = 2. Beide Komplexe bestehen aus diskreten, leicht verdrillten oktaedrischen Monomeren mit annähernd planaren Chelatringen. Im Gegensatz hierzu wurde bei den Röntgenstrukturanalysen verwandter Komplexe Konformationen ermittelt, die von Twistboot zu „Chaiselongue“ variieren.
    Notes: Silanediyldiphosphinite tBu2Si(OPPh2)2 1 has been synthesised. 1 reacts with the norbornadiene complexes C7H8M(CO)4 (M = Cr, Mo, W) to give six-membered chelate rings of the type cis-M(CO)4[tBu2Si(OPPh2)2] 2-4. The crystal structures of the chromium and molybdenum complexes cis-Cr(CO)4[tBu2Si(OPPh2)2] 2 and cis-Mo(CO)4[tBu2Si(OPPh2)2] 3 have been determined. Both complexes crystallise in the triclinic system (space group P1) with unit cell parameters: (2) a = 1 093(3) pm, b = 1 477(5) pm and c = 1 542(5) pm; α = 108.4(2)°, b̃ = 103.87(11)° and b̃ = 104.57(10)°; U = 2.143(12) nm3; Z = 2; (3) a = 1 097.8(2) pm, b = 1 483.7(2) pm and c = 1 554.3(2) pm; α = 108.10(1)°, b̃ = 103.956(6)° and γ = 104.213(7)°; U = 2.1899(6) nm3; Z = 2. Both 2 and 3 consist of discrete, slightly distorted, octahedral monomers in which the six-membered chelate rings are essentially planar. In contrast, the conformations of the chelate rings found in crystal structures of analogous complexes vary from twist-boat to “chaise longue”.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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  • 6
    Publication Date: 2022-05-25
    Description: © The Author(s), 2018. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Chemical Geology 493 (2018): 210-223, doi:10.1016/j.chemgeo.2018.05.040.
    Description: The GEOTRACES Intermediate Data Product 2017 (IDP2017) is the second publicly available data product of the international GEOTRACES programme, and contains data measured and quality controlled before the end of 2016. The IDP2017 includes data from the Atlantic, Pacific, Arctic, Southern and Indian oceans, with about twice the data volume of the previous IDP2014. For the first time, the IDP2017 contains data for a large suite of biogeochemical parameters as well as aerosol and rain data characterising atmospheric trace element and isotope (TEI) sources. The TEI data in the IDP2017 are quality controlled by careful assessment of intercalibration results and multi-laboratory data comparisons at crossover stations. The IDP2017 consists of two parts: (1) a compilation of digital data for more than 450 TEIs as well as standard hydrographic parameters, and (2) the eGEOTRACES Electronic Atlas providing an on-line atlas that includes more than 590 section plots and 130 animated 3D scenes. The digital data are provided in several formats, including ASCII, Excel spreadsheet, netCDF, and Ocean Data View collection. Users can download the full data packages or make their own custom selections with a new on-line data extraction service. In addition to the actual data values, the IDP2017 also contains data quality flags and 1-σ data error values where available. Quality flags and error values are useful for data filtering and for statistical analysis. Metadata about data originators, analytical methods and original publications related to the data are linked in an easily accessible way. The eGEOTRACES Electronic Atlas is the visual representation of the IDP2017 as section plots and rotating 3D scenes. The basin-wide 3D scenes combine data from many cruises and provide quick overviews of large-scale tracer distributions. These 3D scenes provide geographical and bathymetric context that is crucial for the interpretation and assessment of tracer plumes near ocean margins or along ridges. The IDP2017 is the result of a truly international effort involving 326 researchers from 25 countries. This publication provides the critical reference for unpublished data, as well as for studies that make use of a large cross-section of data from the IDP2017. This article is part of a special issue entitled: Conway GEOTRACES - edited by Tim M. Conway, Tristan Horner, Yves Plancherel, and Aridane G. González.
    Description: We gratefully acknowledge financial support by the Scientific Committee on Oceanic Research (SCOR) through grants from the U.S. National Science Foundation, including grants OCE-0608600, OCE-0938349, OCE-1243377, and OCE-1546580. Financial support was also provided by the UK Natural Environment Research Council (NERC), the Ministry of Earth Science of India, the Centre National de Recherche Scientifique, l'Université Paul Sabatier de Toulouse, the Observatoire Midi-Pyrénées Toulouse, the Universitat Autònoma de Barcelona, the Kiel Excellence Cluster The Future Ocean, the Swedish Museum of Natural History, The University of Tokyo, The University of British Columbia, The Royal Netherlands Institute for Sea Research, the GEOMAR-Helmholtz Centre for Ocean Research Kiel, and the Alfred Wegener Institute.
    Keywords: GEOTRACES ; Trace elements ; Isotopes ; Electronic atlas ; IDP2017
    Repository Name: Woods Hole Open Access Server
    Type: Article
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  • 7
    Publication Date: 2022-05-26
    Description: © The Author(s), 2015. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Marine Chemistry 177 (2015): 1-8, doi:10.1016/j.marchem.2015.04.005.
    Description: The GEOTRACES Intermediate Data Product 2014 (IDP2014) is the first publicly available data product of the international GEOTRACES programme, and contains data measured and quality controlled before the end of 2013. It consists of two parts: (1) a compilation of digital data for more than 200 trace elements and isotopes (TEIs) as well as classical hydrographic parameters, and (2) the eGEOTRACES Electronic Atlas providing a strongly inter-linked on-line atlas including more than 300 section plots and 90 animated 3D scenes. The IDP2014 covers the Atlantic, Arctic, and Indian oceans, exhibiting highest data density in the Atlantic. The TEI data in the IDP2014 are quality controlled by careful assessment of intercalibration results and multi-laboratory data comparisons at cross-over stations. The digital data are provided in several formats, including ASCII spreadsheet, Excel spreadsheet, netCDF, and Ocean Data View collection. In addition to the actual data values the IDP2014 also contains data quality flags and 1-σ data error values where available. Quality flags and error values are useful for data filtering. Metadata about data originators, analytical methods and original publications related to the data are linked to the data in an easily accessible way. The eGEOTRACES Electronic Atlas is the visual representation of the IDP2014 data providing section plots and a new kind of animated 3D scenes. The basin-wide 3D scenes allow for viewing of data from many cruises at the same time, thereby providing quick overviews of large-scale tracer distributions. In addition, the 3D scenes provide geographical and bathymetric context that is crucial for the interpretation and assessment of observed tracer plumes, as well as for making inferences about controlling processes.
    Description: We gratefully acknowledge financial support by the Scientific Committee on Oceanic Research (SCOR) through grants from the U.S. National Science Foundation, including grants OCE-0608600, OCE-0938349, and OCE-1243377. Financial support was also provided by the UK Natural Environment Research Council, the Ministry of Earth Science of India, the Centre National de Recherche Scientifique, l'Université Paul Sabatier de Toulouse, the Observatoire Midi-Pyrénées Toulouse, the Universitat Autònoma de Barcelona, the Kiel Excellence Cluster The Future Ocean, the Swedish Museum of Natural History, The University of Tokyo, The University of British Columbia, The Royal Netherlands Institute for Sea Research, the GEOMAR-Helmholtz Centre for Ocean Research Kiel, and the Alfred Wegener Institute.
    Keywords: GEOTRACES ; Trace elements ; Isotopes ; Electronic atlas
    Repository Name: Woods Hole Open Access Server
    Type: Article
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