ISSN:
1612-1112
Keywords:
Gas chromatography
;
Sociation constants
;
Hydrogen bonding solutes
;
Nearly ideal binary solvent theory
;
Isosteric solvents
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Summary Gas chromatographic data measured on mixtures of 19,24-dioctadecyldotetracontane, A≡C78, and 18,23-dioctadecyl-1-hentetracontanol, POH, allow the determination of the standard chemical potential of a solute on an ideal stationary phase with primary alcohol groups at ideal dilution. The Nearly Ideal Binary Solvent Theory provides the link between these data and the sociation constant of the solute with the primary alcohol. The method was applied to calculate sociation constants of a series of hydrogen bonding solutes. Results are compared with those determined by spectroscopy and calorimetry.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF02268353
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