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  • 1
    Digitale Medien
    Digitale Medien
    Springer
    Nutrient cycling in agroecosystems 19 (1989), S. 169-174 
    ISSN: 1573-0867
    Schlagwort(e): Boronia ; Boronia megastigma Nees ; flower production ; nitrogen nutrition ; nitrogen sources ; nitrogen toxicity
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Land- und Forstwirtschaft, Gartenbau, Fischereiwirtschaft, Hauswirtschaft
    Notizen: Abstract Nitrogen was supplied from two fast release sources, ammonium sulfate ((NH4)2SO4) and calcium nitrate (Ca(NO3)2) and a slow release source, isobutylidene diurea (IBDU) to boronia, a new flower crop native to Australia. At lower rates (25 kg per ha), N availability from different sources, as indicated by the leaf N concentration, did not differ within a month after application but three months after application, N availability was higher from IBDU than from (NH4)2SO4 or Ca(NO3)2. At 50 or 100 kg per ha, N availability was higher throughout the year from (NH4)2SO4 or Ca(NO3)2 than from IBDU, thereby allowing luxury consumption and causing toxicity. The flower yield increased with increasing N rates. Complete doses of all N rates which were applied early during the vegetative growth gave the highest yields and the same N rates applied in split doses at different phases of plant growth decreased the yields. In addition, high N availability during flowering (caused by a split dose) further decreased the yield. At all application times, IBDU gave the highest yield and the differences in yields with (NH4)2SO4 and Ca(NO3)2 were not significant. The leaf N concentration associated with maximum yield declined as the plant advanced towards flowering.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 2
    Digitale Medien
    Digitale Medien
    Springer
    Chromatographia 30 (1990), S. 493-499 
    ISSN: 1612-1112
    Schlagwort(e): Gas chromatography ; Chemical potential of solutes ; Ideal dilute solutions ; Effect of size of solvent molecule
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Summary Gas-liquid chromatography allows the rapid experimental determination of the Henry coefficient of molecular probes if a number of precautions are taken. From a knowledge of the temperature dependence of the related standard chemical potential, the standard partial molar enthalpy, entropy and the mean heat capacity difference can be calculated. These functions determine the retention behaviour of the probe over a temperature range of more than 100 K with a precision better than 1%. They also give the necessary information to verify and to develop models for ideal dilute solutions and for the calculation of interaction forces. The choice of specific solvents is examined and justified and the experimental determination of retention data is discussed especially with reference to the precautions to observe in order to measure retention governed by gas-liquid partition only. Calculation of the standard chemical potential related to the molal Henry coefficient is advocated and the dependence of the standard chemical potential on size and shape of the solvent molecule based on data collected on paraffinic stationary phases is examined. This latter function is shown to depend linearly on the inverse of the molar mass of the solvent. Comparison with literature data demonstrates the general validity of this finding and that the shape of the solvent molecule is of less importance.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 3
    ISSN: 1612-1112
    Schlagwort(e): Gas chromatography ; Sociation constants ; Hydrogen bonding solutes ; Nearly ideal binary solvent theory ; Isosteric solvents
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Summary Gas chromatographic data measured on mixtures of 19,24-dioctadecyldotetracontane, A≡C78, and 18,23-dioctadecyl-1-hentetracontanol, POH, allow the determination of the standard chemical potential of a solute on an ideal stationary phase with primary alcohol groups at ideal dilution. The Nearly Ideal Binary Solvent Theory provides the link between these data and the sociation constant of the solute with the primary alcohol. The method was applied to calculate sociation constants of a series of hydrogen bonding solutes. Results are compared with those determined by spectroscopy and calorimetry.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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