ALBERT

Description: The 1992 global average total ozone, measured by the Total Ozone Mapping Spectrometer (TOMS) on the Nimbus-7 satellite, was 2 to 3 percent lower than any earlier year observed by TOMS (1979 to 1991). Ozone amounts were low in a wide range of latitudes in both the Northern and Southern Hemispheres, and the largest decreases were in the regions from 10 to 20 deg S and 10 to 60 deg N. Global ozone in 1992 is at least 1.5 percent lower than would be predicted by a statistical model that includes a linear trend and accounts for solar cycle variation and the quasi-biennial oscillation. These results are confirmed by comparisons with data from other ozone monitoring instruments: the SBUV/2 instrument on the NOAA-11 satellite, the TOMS instrument on the Russian Meteor-3 satellite, the World Standard Dobson Instrument 83, and a collection of 22 ground-based Dobson instruments.

Description: Total Ozone Mapping Spectrometer (TOMS) measurements of equatorial total ozone following the eruption of Mt. Pinatubo show a decrease of up to 6 percent over climatology. Ozone losses begin approximately a month following the eruption, consistent with the time required for the SO2 to convert to sulfuric acid aerosol. The thick aerosol layer interferes with the TOMS retrieval, but this interference is small and easily accounted for in the retrieval. Ozone values remain below climatology until December, 1991. Ozonesonde data from Natal, Brazil taken before and two months after the eruption support TOMS observations of ozone loss. These sondes show that the ozone loss region is confined to a 2-3 km thick layer between 24 and 28 km.

Description: The ozone profiles measured by SBUV in the region of the Antarctic ozone minimum are in error as archived for altitudes below the 7 mb level in the atmosphere because of the lack of a reasonable climatology to use for the initial guess profile. The ozone profile error in this region is examined, and it is shown that use of a reasonable climatology in this unusual region results in ozone profiles that agree substantially better with the balloon observations available from the Syowa station. The corrected profiles show that by 1984 there was 35 percent less ozone in the 15 to 30 km region than in 1979, and 14 percent less even in the 40 to 50 km region.

Description: Until recently, Umkehr data taken by 20 Dobson stations around the world have been the principal source of information about the behavior of upper stratospheric ozone. Umkehr results are used also for detecting drifts in satellite instruments and for determining intersatellite biases. However, a systematic evaluation of the quality of Umkehr data taken by the various stations has been lacking. Five years of ozone profile data from the Solar Backscattered Ultraviolet (SBUV) have been used to examine and intercompare the quality of Umkehr stations, and to assess the degradation of their performance after the El Chichon volcano eruption in southern Mexico. In contrast to Umkehr, the SBUV ozone measurments in layers 7 through 9 (1-8 mb) were unaffected by the massive amounts of dust and gases ejected by El Chichon.

Description: A study is reported based on four years of SBUV data and five years of published ozonesonde data. The Solar Backscatter Ultraviolet Experiment (SBUV), has been operating continuously since November 1978, providing some 1000 profiles per day. The data are of excellent quality from about 50 km down to the tropopause. By combining the satellite-derived data with ozonesonde data, a data base of standard ozone profiles and variance/covariance matrices has been developed, defining the observed variation of the atmospheric ozone around the mean profiles. Highlights of the data base are presented along with parameters of an analytical fit that describes the essential features of the data set. Although the data base was created specifically for use as a priori profiles for SBUV and Umkehr retrievals, it should be useful in other remote sensing applications and in modeling the UV radiation fields in the stratosphere. Another suggested application is in estimating ozone above the peak altitude of the ozone balloons.

Description: An evaluation of the optical effects of stratospheric aerosol layers on total ozone retrieval from space by the TOMS/SBUV type instruments is presented here. Using the Dave radiative transfer model we estimate the magnitude of the errors in the retrieved ozone when polar stratospheric clouds (PSC's) or volcanic aerosol layers interfere with the measurements. The largest errors are produced by optically thick water ice PSC's. Results of simulation experiments on the effect of the Pinatubo aerosol cloud on the Nimbus-7 and Meteor-3 TOMS products are presented.

Description: We show the comparisons between ground-based measurements of spectrally integrated (300 nm to 380 nm) ultraviolet (UV) irradiance with satellite estimates from the Total Ozone Mapping Spectrometer (TOMS) total ozone and reflectivity data for the whole period of TOMS measurements (1979-2000) over the Meteorological Observatory of Moscow State University (MO MSU), Moscow, Russia. Several aspects of the comparisons are analyzed, including effects of cloudiness, aerosol, and snow cover. Special emphasis is given to the effect of different spatial and temporal averaging of ground-based data when comparing with low-resolution satellite measurements (TOMS footprint area 50-200 sq km). The comparisons in cloudless scenes with different aerosol loading have revealed TOMS irradiance overestimates from +5% to +20%. A-posteriori correction of the TOMS data accounting for boundary layer aerosol absorption (single scattering albedo of 0.92) eliminates the bias for cloud-free conditions. The single scattering albedo was independently verified using CIMEL sun and sky-radiance measurements at MO MSU in September 2001. The mean relative difference between TOMS UV estimates and ground UV measurements mainly lies within 1 10% for both snow-free and snow period with a tendency to TOMS overestimation in snow-free period especially at overcast conditions when the positive bias reaches 15-17%. The analysis of interannual UV variations shows quite similar behavior for both TOMS and ground measurements (correlation coefficient r=0.8). No long-term trend in the annual mean bias was found for both clear-sky and all-sky conditions with snow and without snow. Both TOMS and ground data show positive trend in UV irradiance between 1979 and 2000. The UV trend is attributed to decreases in both cloudiness and aerosol optical thickness during the late 1990's over Moscow region. However, if the analyzed period is extended to include pre-TOMS era (1968-2000 period), no trend in ground UV irradiance is detected.

Description: Deviations of radiosonde reports' geopotential heights from the zonal mean are examined. In the summer Northern Hemisphere stratosphere, systematic differences are found between radiosonde instrument types. Persistent meridional wind anomalies, approximately constant in magnitude and fixed in location, have previously been reported in the summer stratosphere, and one such anomaly over Europe is found to be co-located with boundaries between regions in which differing types of radiosonde instruments are used. The magnitude and orientation of the radiosonde geopotential height biases are consistent with the wind anomalies. Because the overall winds tend to be light in this region and season, these wind anomalies can represent significant perturbations of the flow and must be considered when interpreting the results of trajectory and diagnostic studies.

Description: A network of 10 southern hemisphere tropical and Subtropical stations, designated the Southern Hemisphere ADditional OZonesondes, (SHADOZ) project and established from operational sites, provided over 1000 ozone profiles during the period 1998-2000. Balloon-borne electrochemical concentration cell (ECC) ozonesondes, combined with standard radiosondes for pressure, temperature and relative humidity measurements, collected profiles in the troposphere and lower- to mid-stratosphere at: Ascension Island; Nairobi, Kenya; Irene, South Africa: Reunion Island, Watukosek Java; Fiji; Tahiti; American Samoa; San Cristobal, Galapagos; Natal, Brazil.

Description: NASA Goddard Space Flight Center's Airborne Raman Ozone, Temperature and Aerosol Lidar (AROTEL) measured extremely cold temperatures during all three deployments (December 1-16, 1999, January 14-29, 2000 and February 27-March 15, 2000) of the Sage III Ozone Loss and Validation Experiment (SOLVE). Temperatures were significantly below values observed in previous years with large regions regularly below 191 K and frequent temperature retrievals yielding values at or below 187 K. Temperatures well below the saturation point of type I polar stratospheric clouds (PSCs) were regularly encountered but their presence was not well correlated with PSCs observed by the NASA Langley Research Center's Aerosol Lidar co-located with AROTEL. Temperature measurements by meteorological sondes launched within areas traversed by the DC-8 showed minimum temperatures consistent in time and vertical extent with those derived from AROTEL data. Calculations to establish whether PSCs could exist at measured AROTEL temperatures and observed mixing ratios of nitric acid and water vapor showed large regions favorable to PSC formation. On several occasions measured AROTEL temperatures up to 10 K below the NAT saturation temperature were insufficient to produce PSCs even though measured values of nitric acid and water were sufficient for their formation.