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  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 30 (1984), S. 502-504 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 18 (1972), S. 169-173 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Gas absorption by eddies at the free surface of a strongly turbulent liquid is interpreted quantitatively in terms of the Levich approach. The mass transfer coefficient is calculated to vary as Re to a relatively high power (1.3 to 1.5).Experiments on free turbulent jets of liquids in gas are in general accord with this theory. For turbulent films of liquids flowing over large roughness elements in “wake-interference” flow, the turbulence is anomalously efective in promoting gas absorption.Traces of surface-active agents suppress the surface renewal. This is analyzed theoretically: the results compare favorably with gas-absorption for stirred cells and flow experiments over smooth plates. For “wake-interference” flow over rough plates, the reduction in the rate of gas absorption by surface-active material is more pronounced than predicted for ordinary turbulence. But even in the presence of a surface-active agent, the roughness still gives an advantage in mass transfer rates as compared with smooth plates.
    Additional Material: 8 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 24 (1978), S. 524-530 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Experimental values of the surface velocities vs of water jets have been obtained by high speed flash cine photography of talc particles on the surfaces of both laminar and turbulent jets. Values of the surface ages as defined variously by Defay and Hommelen (1958), Hansen (1964), and Harper (1973) have been obtained from our data for both pure water and for dilute solutions of surface active agents.We find, by comparison with published entry length corrections for gas absorption, that x/vs gives the most reasonable age of the surface at any distance x along a jet of pure water.If a surface active agent is present in the water, the amount of adsorption of a few millimeters downstream from the nozzle is of the order ten times greater than calculated for laminar jets and five to six times greater than calculated for turbulent jets at Ren = 18 800. This we ascribe to liquid circulation in the jet adjacent to the nozzle, caused by the Marangoni surface flow, which also reduces vs significantly.
    Additional Material: 12 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 21 (1975), S. 599-600 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 334 (1992), S. 34-36 
    ISSN: 0941-1216
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A new, high yield synthesis of [Pd2Cl2(m̈-dmpm)2] (dmpm = bis(dimethylphosphino)methane), which avoids the use of the ill-defined, polymeric substance [PdCl(CO)]n as a starting material, is described. The procedure involves ligand metathesis of [Pd2Cl2(m̈-dppm)2] (dppm = bis(diphenylphosphino) methane) with dmpm using a solvent in which both [Pd2Cl2(m̈-dppm)2] and [Pd2Cl2(m̈-dmpm)2] are only sparingly soluble. Yields of 〉 98% are routinely obtained.
    Additional Material: 1 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 5 (1972), S. 185-192 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: Using a parametrie representation, it was proved in 19591 that the static and kinematic approaches to the plastic collapse problem are dual linear programming problems. In this paper, the generalized parameters used previously are given physical meaning and shown to be readily programmed for computer application. One important advantage of the method is that the equations can be written in general terms such that no assumptions regarding the structural from need to be built into the program. The application is extended to the more general problem of automatic plastic design and it is shown that the inclusion of a serviceability constraint (e.g. no plastic hinges at a given load factor) is trivial in this formulation. The difficult problem of several loading cases is shown to be readily, treated by designing for a given load factor for shakedown rather than plastic collapse. Thought this latter facility, by its dependence on elastic behavior, requires iteration of the stiffness of the structure, repaid convergence appears to be generally obtained. Finally a method is suggested whereby an adequate allowance for frame instability may be made without destroying the linearity of the equations. Thought the equations, as developed, have application to steel framed structures in mind, the extension to the limit design of reinforced concrete structures appears to present no addition complications.
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  • 7
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 12 (1978), S. 1507-1541 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: In the stressed-skin analysis of metal structures it is vital to have a simple yet accurate treatment of the shear deformation of profiled metal sheeting. A suitable theory is developed in this paper for the two important cases of sheeting fastened to the supporting structure through every and alternate troughs of the corrugations. Various practical factors are taken into account. The results of an extensive series of numerical investigations are presented as a simple equation and a set of tables.
    Additional Material: 20 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    International Journal of Numerical Modelling: Electronic Networks, Devices and Fields 7 (1994), S. 35-41 
    ISSN: 0894-3370
    Keywords: Engineering ; Electrical and Electronics Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Electrical Engineering, Measurement and Control Technology
    Notes: The eigenmodes in electromagnetic cavities, loaded with arbitrarily shaped dielectric materials, are computed by the edge element method. The computation shows that the well known ‘spurious modes’ no longer appear. Formulae are given and verified so that the number of zero eigenvalues, which come from ∇ × H = 0, may be accurately predicted. Formulae for the order and density of the global matrices are given for a rectangular cavity regularly divided into bricks and tetrahedra, allowing an associated comparison between the contrasting edge and nodal element formulations. Comparison of the computed results with available theoretical and previously published data show the edge element approach to be a robust, accurate and effective method.
    Additional Material: 1 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Particle and Particle Systems Characterization 5 (1988), S. 116-121 
    ISSN: 0934-0866
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Aspects of measuring the particle size distribution and median diameters of fine boron powders have been investigated. It has been demonstrated that high concentrations, typically 20 w/o, of wetting agent are necessary in a predispersion stage, especially if the material has a wide range of particle size. Measurements were made with both Coulter counting and a light scattering technique from which it has been demonstrated that for particles of median diameter in the range 10-30 μm, the latter oversizes with respect to the former by as much as 30%.
    Additional Material: 8 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    Journal of Biomedical Materials Research 27 (1993), S. 851-859 
    ISSN: 0021-9304
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine , Technology
    Notes: Primary bone cells, isolated from the periosteally stripped calvariae of neonate rats, were cultured on 60Co γ-irradiation-sterilized bacteriologic-grade polystyrene that had been either surface treated with concentrated sulfuric acid or received further γ-irradiation treatments facilitated cell colonization of the polystyrene compared to those surfaces not treated in the laboratory. x-Ray photoelectron spectroscopy (XPS) showed that the two treatments introduced different chemical groups onto the polymer surface and that cell adhesion was related to γ-irradiation in a dose-dependent manner. These results show that simple biologic assays, such as cell colonization, are not able to distinguish between differences in surface chemistry demonstrated by such a routinely employed surface analysis technique. Thus, there is a need to develop more sensitive biologic assays that provide functional information of a precision that can be correlated with subtle changes in substratum surface chemistry. Further, we argue that because cells isolated by tissue digestion using proteolytic enzymes respond more readily to changes in the surface chemistry of the substratum they colonize, compared to explanted cells; biologic assays designed for biomaterials testing must take into account changes effected in cell adhesion behavior by isolation procedures. © 1993 John Wiley & Sons, Inc.
    Additional Material: 5 Ill.
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