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  • ENERGY PRODUCTION AND CONVERSION  (4)
  • COMPOSITE MATERIALS  (1)
  • 1
    Publication Date: 2011-08-17
    Description: New technologies for producing polysilicon are being developed to provide lower cost material for solar cells which convert sunlight into electricity. This article presents results for the BCL Process, which produces the solar-cell silicon by reduction of silicon tetrachloride with zinc vapor. Cost, sensitivity, and profitability analysis results are presented based on a preliminary process design of a plant to produce 1000 metric tons/year of silicon by the BCL Process. Profitability analysis indicates a sales price of $12.1-19.4 per kg of silicon (1980 dollars) at a 0-25 per cent DCF rate of return on investment after taxes. These results indicate good potential for meeting the goal of providing lower cost material for silicon solar cells.
    Keywords: ENERGY PRODUCTION AND CONVERSION
    Type: Solar Energy; 24; 4, 19; 1980
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  • 2
    Publication Date: 2011-08-18
    Description: A reduction in the cost of silicon for solar cells is an important objective in a project concerned with the reduction of the cost of electricity produced with solar cells. The cost goal for the silicon material is about $14 per kg (1980 dollars). The process which is currently employed to produce semiconductor grade silicon from trichlorosilane is not suited for meeting this cost goal. Other processes for producing silicon are, therefore, being investigated. A description is presented of results obtained for the DCS process which involves the production of dichlorosilane as a silicon source material for solar energy silicon. Major benefits of dichlorosilane as a silicon source material include faster reaction rates for chemical vapor deposition of silicon. The DCS process involves the reaction 2SiHCl3 yields reversibly SiH2Cl2 + SiCl4. The results of a cost analysis indicate a total product cost without profit of $1.29/kg of SiH2Cl2.
    Keywords: ENERGY PRODUCTION AND CONVERSION
    Type: Solar Energy; 27; 6, 19; 1981
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  • 3
    Publication Date: 2019-06-27
    Keywords: COMPOSITE MATERIALS
    Type: NASA-CR-154973 , QTPR-8 , ERDA/JPL-954343-77/3
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  • 4
    Publication Date: 2019-06-27
    Description: Initial results for gas thermal conductivity of silicon tetrafluoride and trichlorosilane are reported in respective temperature ranges of 25 to 400 C and 50 to 400 C. For chemical engineering analyses, the preliminary process design for the original silane process of Union Carbide was completed for Cases A and B, Regular and Minimum Process Storage. Included are raw material usage, utility requirements, major process equipment lists, and production labor requirements. Because of the large differences in surge tankage between major unit operations the fixed capital investment varied from $19,094,000 to $11,138,000 for Cases A and B, respectively. For the silane process the original flowsheet was revised for a more optimum arrangement of major equipment, raw materials and operating conditions. The initial issue of the revised flowsheet (Case C) for the silane process indicated favorable cost benefits over the original scheme.
    Keywords: ENERGY PRODUCTION AND CONVERSION
    Type: NASA-CR-157030 , ERDA/JPL-954343-78/1 , QTPR-1
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  • 5
    Publication Date: 2019-07-13
    Description: Results for process system properties, chemical engineering and economic analyses of the new technologies and processes being developed for the production of lower cost silicon for solar cells are presented. Analyses of process system properties are important for chemical materials involved in the several processes under consideration for semiconductor and solar cell grade silicon production. Major physical, thermodynamic and transport property data are reported for silicon source and processing chemical materials.
    Keywords: ENERGY PRODUCTION AND CONVERSION
    Type: NASA-CR-164009
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