ISSN:
1434-193X
Keywords:
Palladium(0)-catalyzed reactions
;
C-C coupling
;
Heck reaction
;
Di- and oligomeric porphyrins
;
Chemistry
;
General Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Using palladium(0)-catalyzed coupling reactions we were able to synthesize mono-, di-, and trimeric porphyrins linked by di- and trivinylbenzenes. The reactions were carried out with palladium(II) acetate in DMF under phase-transfer conditions. These coupling conditions are new in the field of porphyrin chemistry and proved to be a useful tool in the synthesis of C-C linked oligomeric porphyrins, as these compounds can be obtained in a simple one pot reaction with good yields.
Type of Medium:
Electronic Resource
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