ISSN:
1612-1112
Keywords:
Column liquid chromatography
;
Indirect detection of non-electrolytes
;
Simulation of induced peaks
;
RP systems
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Summary Induced peaks observed in indirect detection of nonelectrolytes in high-performance liquid chromatography are simulated. The equation representing the signal intensity of the induced peaks is derived, and it is verified by the experimental results. The peak area is proportional to (K b ′ +1) k a ′ /| a ′ —k b ′ |, where k a ′ ad k b ′ are the capacity factors of the visualization agent and the analyte, respectively.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF02259025
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