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Simulation of induced peaks in indirect detection of non-electrolytes in high-performance liquid chromatography

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Summary

Induced peaks observed in indirect detection of nonelectrolytes in high-performance liquid chromatography are simulated. The equation representing the signal intensity of the induced peaks is derived, and it is verified by the experimental results. The peak area is proportional to (K ′b +1) k ′a /| ′a —k ′b |, where k ′a ad k ′b are the capacity factors of the visualization agent and the analyte, respectively.

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Authors and Affiliations

  1. Department of Applied Chemistry, Faculty of Engineering, Nagoya University, Chikusa-ku, 464, Nagoya, Japan

    T. Takeuchi, S. Watanabe, K. Murase & D. Ishii

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  1. T. Takeuchi
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  2. S. Watanabe
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  3. K. Murase
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  4. D. Ishii
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Takeuchi, T., Watanabe, S., Murase, K. et al. Simulation of induced peaks in indirect detection of non-electrolytes in high-performance liquid chromatography. Chromatographia 25, 107–110 (1988). https://doi.org/10.1007/BF02259025

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  • DOI: https://doi.org/10.1007/BF02259025

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