ISSN:
0009-2940
Keywords:
Silylgermanes
;
Silyl potassium
;
Germyl potassium
;
Silylation by silyl esters of sulfonic acids
;
Process gases for photovoltaics
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
An Improved Preparation of Silyl- and Germylpotassium and Synthesis of SilylgermanesThe preparation of KSiH3 and KGeH3 is improved, and several syntheses of silylgermane, H3Si - GeH3, are described. A series of other potential processing gases for PE-CVD is prepared: H3Ge - SiR1R2R3 (R1, R2, R3 = H, H, Me; H, H, Et; H, H, tBu; H, H, Ph; H, Me, Me; Et, Et, Et; H, Me, Ph; H, Me, GeH3). A new method for the preparation of silylgermanes by the reaction of silyl esters of sulfonic acids (RSO3H, R = C4,F9, Me, Ph) with KGeH3 is reported.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19911241105
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