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  • Chemistry  (17)
  • Flexural fatigue  (1)
  • Nickel coated graphite  (1)
  • Atomic, Molecular, and Optical Physics
  • 1990-1994  (19)
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Keywords
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Year
  • 1
    ISSN: 1573-4897
    Keywords: Flexural fatigue ; Glass reinforced composites
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Conclusions Flexural fatigue of uniaxially and biaxially stressed IPN/glass mat composites was investigated using four point bend (4PB) and concentrically loaded (CL) specimen geometries. Regions of nearly constant bending moment between the inner spans of a 4PB beam and within the inner annulus of a CL circular plate yield quasi-uniform uniaxial and biaxial stress, respectively, on the tensile faces. The specimen dimensions were optimized for both loading geometries to give: (1) reduced specimen deflection through maximizing the ratio of the induced tensile stresses to the applied load, (2) minimized contact stresses by maximizing the induced stress with respect to the unit contact load, and (3) a large material volume exposed to the maximum cyclic stress (i.e., statistical fracture initiation). A power model was used to analyze the fatigue data for the 4PB and CL specimens. Both IPN composite materials studied fatigued more rapidly under the more severe loading conditions imposed by the CL specimen geometry. Fractography revealed that debond fracture was the dominant damage process for both geometries. The initial debond cracks were uniformly distributed throughout the stressed regions, confirming the presence of nearly uniform tensile stress. Damage localization followed after further cycling and was characterized by a locally high debond fracture density, fiber fracture, and always occurred where several glass strands crossed near the specimen surface. Final specimen failure resulted from the preferential growth of dominant cracks through the specimen thickness.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Applied composite materials 1 (1994), S. 231-245 
    ISSN: 1573-4897
    Keywords: MMC ; Nickel coated graphite ; Squeeze casting ; Instable interface ; Electroplating
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Metal Matrix Composites (MMC's) reinforced with continuous fibers were generally fabricated by a foil-sandwich technique or by liquid metal infiltration. Liquid metal infiltration may be used to cast final shapes in molds containing fiber preforms. It is also used to make composite wire from which may be fabricated panels and shapes by hot-press diffusion bonding or pultrusion. The major drawback of this method is that the molten matrix must wet the fiber for successful infiltration to occur, requiring special fiber surface treatments or matrix additives, and that, molten metals generally dissolve or degrade the fibers, necessitating a barrier coating on the fibers. All these problems can be solved using carbon fibers coated with metallic layers, e.g. nickel. This work analyses an easy method to produce modified carbon fibers by electroplating and the process of its recristallization. The topography of the growth front of the deposit has been studied. At temperatures higher than about 300° C an annealing under vacuum is required, because of the high reactivity of metal coating, nevertheless the heat treatment of metal deposit produces always an embrittled material.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Brookfield, Conn. : Wiley-Blackwell
    Polymer Composites 12 (1991), S. 333-337 
    ISSN: 0272-8397
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The effect of water absorption on the stress transferability across E-glass fiber/nylon 6 interface has been studied using the embedded single fiber composite technique. The behavior of silane coated fiber and untreated fiber composites after periods of water immersion were compared. The silane coating provided both higher interfacial shear stress transferability and protection from permanent water damage in the interphase region. It was found that water absorption in the nylon matrix reduced the shear stress transferability through plasticization of the matrix, weakening of the interface, and the development of tensile swelling stresses at the phase boundaries. In untreated materials the shear stress transferability was limited by decoupling of the matrix from the broken fiber ends by either interface slippage or local plane strain fracture in the interphase region near the fiber end. In the silane treated materials the shear stress transferability was limited by constrained yielding of the polysiloxane/nylon interphase at the fiber end, thus indicating plasticization of the matrix was the primary factor. After 20 days of water immersion, there was permanent deterioration of stress transferability in the untreated samples, but very little permanent damage in the treated samples.
    Additional Material: 3 Ill.
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  • 4
    ISSN: 0272-8397
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Mechanical properties of fiber reinforced composites depend on the formation of stable adhesive bonds between the constituents. In order to evaluate quantitatively the adhesion between liquid crystal polymer (LCP) fibers and a thermoplastic matrix of polycarbonate, the single fiber composite test (SFC), utilized for testing glass or carbon fiber composites, has been used. Neither chemical nor physical interaction has been found: the PC and LCP phases are completely incompatible. However, a mechanical friction between PC and LCP was observed during the drawing of the sample when the neck of the matrix started.
    Additional Material: 7 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    Brookfield, Conn. : Wiley-Blackwell
    Polymer Composites 13 (1992), S. 191-196 
    ISSN: 0272-8397
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The cure kinetics of two dicyanate resins were investigated by differential scanning calorimetry under isothermal and nonisothermal conditions. An autocatalytic kinetic model was proposed and a set of general kinetic parameters was calculated from the isothermal experiments. Good agreement between experimental data and the kinetic model has been obtained under different processing conditions, which demonstrated the validity and the usefulness of the analytical procedure and of the kinetic expression employed. Consequently, in its current form, the modeling methodology is capable of describing the degree of cure during a typical processing cycle and has the potential for comparing different resin formulations as well as the manifestations of cure in property development. Specifically, in this work the modeling methodology was tested using two distinct dicyanate resin systems while the development of the cure was also observed through dielectric analysis (DEA).
    Additional Material: 12 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    Brookfield, Conn. : Wiley-Blackwell
    Polymer Composites 14 (1993), S. 224-228 
    ISSN: 0272-8397
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The use of Wilhelmy plate techniques for studying the interactions of fibers with fluids of variable viscosity is discussed. The influence of hydrodynamic effects of force (F) VS. DEPTH (z) plots is interpreted on the basis of surface tension-independent added terms of the constitutive equation of the Wilhelmy experiment. Wetting experiments using pseudoplastic fluids (polyethyleneglycol/water solution) show that viscoelasticity is indeed important in the interpretation of Wilhelmy plate experiments. The comparison of wetting experiments performed on untreated and plasma-treated carbon fibers showed that at low stage speed and fluid viscosity, surface chemistry and morphology determines contact angles. At higher stage speeds and viscosities and advancing and receding angles are affected by surface chemistry-independent and hydrodynamics-dependent added contributions.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 44 (1992), S. 1465-1471 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Toughening epoxy resins can be achieved by blending a low percentage of Liquid Crystalline Polymer with the thermoset. The processing technique consists of the spinning of blends of a thermoplastic (Ardel) with the LCP (PET/PHB60). The bundled filaments are subsequently dissolved in the uncured epoxy resin (Epon 825). After curing, the LCP phase separates from the matrix in the form of microfibers with a very high aspect ratio, which act as crack stoppers and improve fracture toughness of the material.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 39 (1990), S. 1163-1174 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The viscoelastic properties of the amorphous and semicrystalline PEEK and of a PEEK-based composite (APC2) have been analyzed as a function of the aging time and related free volume relaxation, at temperatures close to the glass transition temperature. The effect of thermal treatments (physical aging) on the polymer amorphous phase of the three systems is presented. Creep tests approaching the “zero stress” were performed on samples subjected to different thermal histories. The presence of a second phase, namely crystallites and fibers, determines a loss of the mobility of the polymeric amorphous chains and consequently a decrease of the rate of free volume relaxation.
    Additional Material: 9 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 43 (1991), S. 839-844 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Additional Material: 8 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 41 (1990), S. 2691-2704 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Blends of polymethylmethacrylate (PMMA) and poly-ε-caprolactone (PCL) were prepared and characterized. The analysis of the glass transition temperature indicates no compatibility of the two polymers, which segregated into two distinct phases. The fracture strength of the blends can be explained on the basis of a constitutive model of spheres of PCL embedded in a PMMA matrix. The trend of water sorption confirms the hypothesis of phase segregation of PCL in the glassy matrix of PMMA.
    Additional Material: 7 Ill.
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