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  • 1
    ISSN: 0272-8397
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The resin film infusion process (RFIP), which is similar to resin transfer molding (RTM), was applied to investigate the possibility of manufacturing high performance stitched composites. With the objective of understanding the resin flow mechanisms and void formation in stitched fibrous perform, two recent technological developments in homogeneous tough resin and bendable stitching fibers were incorporated in producing stituched composites with RFIP. These included new lightly crosslinked thermosets (LXT) that were phenolic or amine based. Second, bendable carbon stitching reinforcement (T-900) was utilized as a stitching fiber. Flow characteristics were inferred by ultrasonic C-scan analysis of cured panels. Microscopic studies indicated that voids were distrubuted along the stitching fiber because of low consolidation pressure in the resin-rich area (stitching fiber region) where the fiber volume content was lower. In contrast to stitched composites, non-sitiched composites contained lower void content and irregular void distribution because of uniform fiber compaction. Microscopic studies of partially resin infused quasi-istropic stitched composites demonstrated that the resin flows along the stitching fiber region and then infuses into the fibrous preform. These infusion phebnomena were the result of anistropic permeability in the preform. Consequently, anisotropic resin flow in the stitched fibrous preform was found to be related to the heterogenous textile structure caused by the stitching process.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Brookfield, Conn. : Wiley-Blackwell
    Polymer Composites 13 (1992), S. 191-196 
    ISSN: 0272-8397
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The cure kinetics of two dicyanate resins were investigated by differential scanning calorimetry under isothermal and nonisothermal conditions. An autocatalytic kinetic model was proposed and a set of general kinetic parameters was calculated from the isothermal experiments. Good agreement between experimental data and the kinetic model has been obtained under different processing conditions, which demonstrated the validity and the usefulness of the analytical procedure and of the kinetic expression employed. Consequently, in its current form, the modeling methodology is capable of describing the degree of cure during a typical processing cycle and has the potential for comparing different resin formulations as well as the manifestations of cure in property development. Specifically, in this work the modeling methodology was tested using two distinct dicyanate resin systems while the development of the cure was also observed through dielectric analysis (DEA).
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
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