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  • Chemistry  (64)
  • EARTH RESOURCES AND REMOTE SENSING  (21)
  • 1990-1994  (85)
  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 1433-1439 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: It is generally believed that oil samples heat faster in a microwave oven than do water samples of the same mass. For sufficiently large and thich samples this conventional wisdom is indeed correct, but this trend can be far from true in smaller samples. In a commercially-made home microwave oven, we observed that with decreasing sample size the heating rate of a water sample increases much faster than that of an oil sample. At 50 g the heating rate of a water sample is several times greater than that of an oil sample. Additionally, in studies of cylindrical samples in a customized oven having a unidirectional microwave source, the heating rate of water samples smaller than 2.4 cm in radius is greater than that of oil samples and is a strongly oscillatory increasing function of decreasing sample radius. Combining Maxwell's theory of microwave penetration and the heat conduction equation, we show that this previously unreported oscillatory heating behavior results from the added power absorbed by samples due to resonant absorption of microwaves. The added power arises from standing waves produced by internally reflected microwaves. This effect is small for oil because only 3% of the microwave power is reflected at an oil-air interface. On the other hand, 64% is reflected at a water-air interface, which causes strong resonant heating. Our findings might prove to be useful for future consumer food product development or oven design.
    Additional Material: 6 Ill.
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 1268-1272 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 7 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 37 (1991), S. 313-322 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Transient temperature profiles in multilayer slabs are predicted, by simultaneously solving Maxwell's equations with the heat conduction equation, using Galerkin finite elements. It is assumed that the medium is homogeneous and has temperature-dependent dielectric and thermal properties. The method is illustrated with applications involving the heating of food and polymers with microwaves. The temperature dependence of dielectric properties affects the heating appreciably, as is shown by comparison with a constant property model.
    Additional Material: 7 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 38 (1992), S. 1577-1592 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Transient temperature profiles for long rods of lossy dielectric materials with thermally-dependent dielectric properties exposed to uniform plane waves are obtained. Maxwell's equation and the heat equation are simultaneously solved using the finite element method to predict the power absorbed and the resulting temperature rise in samples of square and circular cross-section. Following the method introduced recently, we derive an exact radiation boundary condition which is independent of the rod cross-section. For a cylindrical sample, the boundary condition is imposed on the cylinder itself. For a square rod, the boundary condition is imposed on a cylinder containing the rod. The temperature dependence of dielectric properties and sample dimensions appreciably influence heating patterns. For square samples, the edges focus radiation, causing preferential heating at the edges. This effect is pronounced for larger samples. In addition, the incident wave polarization influences the heating of the rod. For waves where the electric field is polarized along the long axis of the sample (TMz polarization) the power absorbed is higher than when the electric field is perpendicular to the axis (TEz polarization). A case involving runaway heating is also investigated.
    Additional Material: 9 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 37 (1991), S. 1789-1800 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The finite element method was used to model microwave thawing of pure-water and 0.1-M NaCl cylinders. The electromagnetic field was described by Maxwell's equations with temperature-dependent dielectric properties, while the heat equation, coupled with the Stefan and Robin conditions, was used to describe the thawing process. An additional equation for the frozen volume fraction was used, when necessary, to account for the presence of a mushy region. Two microwave frequencies, 915 MHz and 2,450 MHz, were examined and the microwave radiation was assumed to be radially isotropic and normal to the surface of the cylinder. Results show that a two-phase mushy region may exist, and an additional thawing front may appear at the center of the cylinder. Salt cylinders have a higher dielectric loss than pure-water cylinders and therefore thaw more quickly. Internal resonance occurs when the wavelength of the radiation is a harmonic of the cylinder radius. Resonance increases power deposition and expedites the thawing process. The onset of resonance alters thawing times and complicates the development of heuristic rules for microwave thawing.
    Additional Material: 12 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 28 (1990), S. 1455-1472 
    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The synthesis is described of some acrylate based polymers containing both a mesogenic group (4-cyanophenyl benzoate) connected to the polymer backbone by a flexible spacer, and varying degrees of crosslinking, introduced by copolymerization. Optical and calorimetric techniques are used to determine the phase behavior, which is found to depend strongly on the crosslink density (and the flexible spacer length); though (nominally) a relatively high degree of crosslinking is possible without completely destroying the liquid crystal phase. Mechanical measurements in conjunction with supplementary analytical data, where available, are used to determine the efficiency of copolymerization at introducing intermolecular crosslinking. Some possible explanations for the unexpectedly low efficiency of this process are discussed. The properties of materials prepared in this fashion are compared briefly with some examples where crosslinking is introduced after polymerization; this latter process is seen to be rather more efficient.
    Additional Material: 8 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 28 (1990), S. 3107-3122 
    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A soluble aromatic poly (amic acid) film was converted to a soluble polyimide by staging at 25°C intervals to 325°C and characterized at each interval by several analytical methods. The behavior observed was consistent with an interpretation that a reduction occurred in molecular weight of the poly (amic acid) during the initial stages of cure before the ultimate molecular weight was achieved as a polyimide. This interpretation was supported by the results of solution viscosity, gel permeation chromatography, low angle laser light scattering photometry, and infrared spectroscopy analyses. The results of this study serve to increase our fundamental understanding of how polyimides are thermally formed from poly (amic acid)s.
    Additional Material: 9 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 28 (1990), S. 3701-3724 
    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A series of alkylthio-substituted aromatic diamines was synthesized using a convenient high yield procedure. The method consisted of heating a mixture of dialkyl disulfide and aromatic diamine in the presence of cuprous iodide or other Lewis acid catalyst. Dialkyl disulfide was continually replenished as consumed, throughout the reaction, to maintain the desired reaction temperature. Compounds so prepared were isolated by first precipitating the catalyst with solid caustic and then vacuum flashing the crude products. When desired, the final product purity could be increased by washing with acid to remove starting material or reaction intermediates. The final products were often liquids or low melting solids and showed utility as curatives for polyurethane cast elastomers. Alkylthio substitution of the aromatic diamines lowered reactivity toward isocyanates and generally provided for facile processing during molding. The series of derivatives allowed for great flexibility in controlling both diamine reactivity and the physical properties of the final elastomers. These benefits arose from the diverse electronic, steric and isomeric properties of the derivatives. Polymers were prepared from the alkylthio-substituted compounds and commercially available TDI-based prepolymers using conventional cast elastomer techniques. The physical properties of the polymers were determined and their relation to alkylthiodiamine structure examined.
    Additional Material: 7 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 31 (1993), S. 1709-1717 
    ISSN: 0887-624X
    Keywords: poly(methyl vinyl ether); poly(butyl vinyl ether) ; poly(2-ethyl-2-oxazoline) ; block copolymers ; living cationic polymerization ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A method for the synthesis of well-defined poly(alkyl vinyl ether-2-ethyl-2-oxazoline) diblock copolymers with hydrolytically stable block linkages has been developed. Monofunctional poly(alkyl vinyl ether) oligomers with nearly Poisson molecular weight distributions were prepared via a living cationic polymerization method using chloroethyl vinyl ether together with HI/ZnI2 as the initiating system and lithium borohydride as the termination reagent. Using the resultant chloroethyl ether functional oligomers in combination with sodium iodide as macroinitiators, 2-ethyl-2-oxazoline was polymerized in chlorobenzene/NMP to afford diblock copolymers. A series of poly(methyl vinyl ether-2-ethyl-2-oxazoline) diblock materials were found to have polydispersities of ≈ 1.3-1.4 and are microphase separated as indicated by two Tg's in their DSC thermograms. These copolymers are presently being used as model materials to study fundamental parameters important for steric stabilization of dispersions in polar media. © 1993 John Wiley & Sons, Inc.
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  • 10
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 32 (1994), S. 2257-2265 
    ISSN: 0887-624X
    Keywords: helix in amylopectin-iodine complex ; I4 unit in amylopectin-iodine complex ; spectra of amylopectin-iodine complex ; amylopectin-iodine chromophore composition ; amylopectin fine structures and complex formation ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A partial hydrolysis of amylose followed by the addition of iodine provides a spectrum almost identical to that of the amylopectin-iodine (API) complex suggesting the involvement of smaller “amylose-like” units in the API complex. Our theoretical studies on different polyiodine and polyiodide species suggest that a nearly linear I4 unit stabilized within the cavity of a small “amylose-like” helix is responsible for the characteristic API spectrum. Since there are 2.75 anhydroglucose residues (AGU) for every iodine atom in the amylose-iodine (AI) complex and a structural similarity exists between the API and the AI (amylose-iodine) complexes, we identify (C6H10O5)11I4 to be the chromophore in the API complex. © 1994 John Wiley & Sons, Inc.
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