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  • 1
    Publication Date: 2022-05-26
    Description: Author Posting. © American Meteorological Society, 2014. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Climate 27 (2014): 8981–9005, doi:10.1175/JCLI-D-12-00565.1.
    Description: Version 1 of the Community Earth System Model, in the configuration where its full carbon cycle is enabled, is introduced and documented. In this configuration, the terrestrial biogeochemical model, which includes carbon–nitrogen dynamics and is present in earlier model versions, is coupled to an ocean biogeochemical model and atmospheric CO2 tracers. The authors provide a description of the model, detail how preindustrial-control and twentieth-century experiments were initialized and forced, and examine the behavior of the carbon cycle in those experiments. They examine how sea- and land-to-air CO2 fluxes contribute to the increase of atmospheric CO2 in the twentieth century, analyze how atmospheric CO2 and its surface fluxes vary on interannual time scales, including how they respond to ENSO, and describe the seasonal cycle of atmospheric CO2 and its surface fluxes. While the model broadly reproduces observed aspects of the carbon cycle, there are several notable biases, including having too large of an increase in atmospheric CO2 over the twentieth century and too small of a seasonal cycle of atmospheric CO2 in the Northern Hemisphere. The biases are related to a weak response of the carbon cycle to climatic variations on interannual and seasonal time scales and to twentieth-century anthropogenic forcings, including rising CO2, land-use change, and atmospheric deposition of nitrogen.
    Description: The CESM project is supported by the National Science Foundation and the Office of Science (BER) of the U.S. Department of Energy. Computing resources were provided by the Climate Simulation Laboratory at NCAR’s Computational and Information Systems Laboratory (CISL), sponsored by the National Science Foundation and other agencies. This research was enabled by CISL compute and storage resources. SCD acknowledges support from the National Science Foundation (NSF AGS-1048827). This research is supported in part by the U.S. Department of Energy (DOE), Office of Science, Biological and Environmental Research. Oak Ridge National Laboratory is managed by UT-BATTELLE for DOE under contract DE-AC05-00OR22725.
    Description: 2015-06-15
    Keywords: Carbon cycle ; Climate models ; Coupled models ; Model evaluation/performance
    Repository Name: Woods Hole Open Access Server
    Type: Article
    Format: application/pdf
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  • 2
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 102 (1969), S. 4032-4042 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Kondensation von 2.5-Diamino-4-methylamino-6-oxo-1.6-dihydro-pyrimidin (4) mit Acetylbrenztraubensäureester liefert bei pH 1 überraschenderweise 82% 8.9-Dimethylguanin (16) und 15% 6.8-Dimethyl-isoxanthopterin (11), während bei pH 5 erwartungsgemäß 8-Methyl-6-acetonyl-isoxanthopterin (10) resultiert. Nach Isotopenversuchen mit 4-14C-markiertem Acetylbrenztraubensäureester findet sich dieses Atom in der 8-Position des Purin Derivates wieder. Analoge Umsetzungen mit einer Reihe von 4(5)-Amino-5(4)-alkyl(aryl)-amino-pyrimidinen (5-9) bzw. entsprechend substituierten o-Diamino-pyridinen (25,26) und mit N-Methyl-o-phenylendiamin werden beschrieben. pKa-Werte und UV-Spektren der synthetisierten Produkte wurden bestimmt.
    Additional Material: 1 Tab.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 106 (1973), S. 3203-3215 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Pteridines, LIX. Synthesis of 7-Amino-, 7-Hydroxy- and 7-Methoxylumazine 5-Oxides and a new Pteridine → Purine Transformation7-Hydroxy- (5,7) and 7-methoxy-6-methyllumazines (6,8) can be converted to the corresponding 5-oxides 12-15 by H2O2 oxidation. Refluxing in acetic anhydride lead to deoxygenation of the 7-methoxylumazine 5-oxides (13,15) whereas the corresponding 7-hydroxy derivatives (12, 14) react under ring contraction to 1,3-disubstituted uric acids (25, 26). A possible reaction mechanism of this pteridine → purine transformation will be discussed on the basis of isotope experiments.
    Notes: 7-Hydroxy- (5, 7) und 7-Methoxy-6-methyllumazine (6, 8) lassen sich durch Oxidation mit H2O2 in die entsprechenden 5-Oxide 12-15 überführen. Beim Kochen mit Acetanhydrid werden die 7-Methoxylumazin-5-oxide (13, 15) zu den Ausgangsverbindungen desoxygeniert, während die entsprechenden 7-Hydroxy-Derivate (12, 14) unter Ringverengung 1,3-disubstituierte Harnsäuren (25,26) liefern. Ein möglicher Reaktionsmechanismus dieser Pteridin → Purin-Umwandlung wird auf der Basis von Isotopenexperimenten diskutiert.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 104 (1971), S. 3069-3072 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Pteridines, XLVII The Structure of Xanthopterin-peroxide and its Transformation into Melanuric AcidThe structure of „xanthopterin-peroxids“ (2) is discussed and a mechanism for its transformation to melanurenic acid (4) by hydrogen peroxide is proposed on the basis of 14C-experiments.
    Notes: Die Struktur des „Xanthopterin-peroxide“ (2) wird diskutiert und für seine Umwandlung in Melanurensäure (4) mittels H2O2 auf der Basis von 14C-Experimenten ein Mechanismus vorgeschlagen.
    Type of Medium: Electronic Resource
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