ISSN:
1612-1112
Keywords:
Column liquid chromatography
;
Alkyl bonded phases
;
Selectivity studies
;
N-alkylbenzamide congeners
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Summary Reversed-phase liquid chromatographic retention characteristics for the sixteen acyclic C1−C5 N-alkylbenzamide congeners were measured on various branched and linear, alkyl bonded hydrocarbon stationary phases. Retention factors, k′, were determined in acetonitrile-water mobile phase compositions on ethyl, n-octyl, n-dodecyl, n-octadecyl, 1-ethyladamantyl, 4-butyloctyl, and 2,4,4-trimethylpentyl stationary phases. Statistical analysis of the two main effects investigated — type of stationary phase and percentage of organic modifier (acetonitrile) in the mobile phase — described greater than ninety percent of the variability in the data for most of the comparisons. Selectivity effects due to variation in the mobile phase dominated the results.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF02321435
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