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The radiolysis of tryptophan and leucine with32Pβ-radiation (1980)

Blair, Neal E. ; Bonner, William A.

Springer

Journal of molecular evolution 15 (1980), S. 21-28

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ISSN: 1432-1432

Keywords: β-radiolysis ; Asymmetric radiolysis ; Vester-Ulbricht Hypothesis ; Origin of optical activity

Source: Springer Online Journal Archives 1860-2000

Topics: Biology

Notes: Summary We have extended earlier experiments on the radiolysis of DL-tryptophan using32Pβ-radiation to longer reaction times, observing complete destruction of the tryptophan by secondary, non-radiolytic processes. We have also undertaken the irradiation of DL-leucine with32Pβ's at -196°, achieving radiolyses to the extents of ca. 20–30%, but observing no concomittant asymmetric bias. The implications of these observations are discussed with regard to the Vester-Ulbricht mechanism for the origin of optical activity.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF01732580

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