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  • Chemistry  (3)
  • Exobiology  (3)
  • Aqueous solution  (1)
  • 5'-O-demethyl-8-O-methyl-dioncophylline A
  • 1995-1999
  • 1990-1994  (3)
  • 1985-1989  (4)
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  • 1
    Digitale Medien
    Digitale Medien
    Springer
    Journal of solution chemistry 16 (1987), S. 985-997 
    ISSN: 1572-8927
    Schlagwort(e): Aqueous solution ; cell constant ; conductance ; electrolytic conductivity ; potassium chloride ; primary ; resistance ; resistivity, secondary, standards, and temperature scale
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Measurements of aqueous electrolytic conductance are performed routinely in a variety of disciplines and industries. Conductivity is a measure of the ionic content in solution and thus has applications in pharmaceuticals, power plants, rainwater, lake surveys, and oceanography, to name a few. A thorough review of the measurement of and standards for aqueous electrolytic conductance is herein presented. At present, the most precise and accurate standards have been set forth by the International Organization of Legal Metrology (OIML), and have been adopted by most other standards organizations. However, the uncertainty assigned to these standards, especially the secondary standards, is somewhat larger than would be expected from the physical aspects of the measurement. Several changes in the units and measurement scales, including temperature, volume, molar mass, resistance, and concentration obfuscate the accuracy of these standards. In addition to the review, research is proposed, using a conductance cell with variable length, to establish new standards for aqueous electrolytic conductance.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 2
    ISSN: 1040-0397
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: A method using sodium amalgam electrodes has been developed to study the effect of protein on activity measurements and residual liquid junction potential of sodium in protein-containing solutions. It was tested for reliability by application to aqueous sodium chloride solutions before it was applied to protein-containing solutions. The experimentally determined activity coefficients are in good agreement with the activity coefficients for aqueous sodium chloride solutions reported in literature. Therefore, we used this method to measure the activity of NaCl solutions containing varying concentrations of bovine serum albumin (BSA). The electrode slope of the electrode responses in a protein-containing medium does not differ from that of pure aqueous solutions. A functional relationship has been established between the concentration of protein and the percent bias in the measurements. Measurements of electromotive force made in protein-containing solutions do not show any evidence of protein effect on liquid junction potential.
    Zusätzliches Material: 2 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 3
    Digitale Medien
    Digitale Medien
    New York : Wiley-Blackwell
    Die Makromolekulare Chemie 12 (1985), S. 105-123 
    ISSN: 0025-116X
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Physik
    Notizen: Certain polymerization reactions show the formation of medium molecular weights at the beginning of the reaction, although they can be considered to be polycondensations. The principle of equal reactivity of the end groups is not given in this case. Intermediates more reactive than the monomer are formed during the reaction. Poly(oxy-2,6-dimethyl-l,4-phenylene), poly(l,4-phenylene sulfide) and poly(l,4-phenylene) are examples of this type of reaction. The formation of radical ions in these reactions is discussed and they are compared to Bunnett's SRN1-reactions.
    Zusätzliches Material: 8 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 4
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    Surface and Interface Analysis 17 (1991), S. 947-950 
    ISSN: 0142-2421
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Physik
    Notizen: Auger spectra from highly samples (Al2O3, Si3N4) are collected in a gaseous environment. It is demonstrated that the build-up of negative surface charge can be reduced considerably under suitable conditions. It is proposed that the decharging of the surface is initiated by Auger neutralization of the ions formed in the gaseous environment in collisions with the primary keV electrons.
    Zusätzliches Material: 4 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 5
    facet.materialart.
    Unbekannt
    In:  Other Sources
    Publikationsdatum: 2011-08-24
    Beschreibung: The potential energy surface of the C4H7+ cation has been investigated with ab initio quantum chemical theory. Extended basis set calculations, including electronic correlation, show that cyclobutyl and cyclopropylcarbinyl cation are equally stable isomers. The saddle point connecting these isomers lies 0.6 kcal/mol above the minima. The global C4H7+ minimum corresponds to the 1-methylallyl cation, which is 9.0 kcal/mol more stable than the cyclobutyl and the cyclopropylcarbinyl cation and 9.5 kcal/mol below the 2-methylallyl cation. These results are in excellent agreement with experimental data.
    Schlagwort(e): Exobiology
    Materialart: Journal of the American Chemical Society (ISSN 0002-7863); Volume 110; 22; 7325-8
    Format: text
    Standort Signatur Erwartet Verfügbarkeit
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  • 6
    facet.materialart.
    Unbekannt
    In:  Other Sources
    Publikationsdatum: 2011-08-24
    Beschreibung: No abstract available
    Schlagwort(e): Exobiology
    Materialart: Journal of the American Chemical Society (ISSN 0002-7863); Volume 111; 1527-8
    Format: text
    Standort Signatur Erwartet Verfügbarkeit
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  • 7
    Publikationsdatum: 2019-07-13
    Beschreibung: No abstract available
    Schlagwort(e): Exobiology
    Materialart: Angewandte Chemie (International ed. in English) (ISSN 0570-0833); 29; 2; 183-5
    Format: text
    Standort Signatur Erwartet Verfügbarkeit
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