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  • Anthropogenic carbon  (3)
  • Anthropogenic climate change
  • Air-sea interaction
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  • 1
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2011. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Global Biogeochemical Cycles 25 (2011): GB3022, doi:10.1029/2010GB003892.
    Description: The North Atlantic Ocean accounts for about 25% of the global oceanic anthropogenic carbon sink. This basin experiences significant interannual variability primarily driven by the North Atlantic Oscillation (NAO). A suite of biogeochemical model simulations is used to analyze the impact of interannual variability on the uptake and storage of contemporary and anthropogenic carbon (Canthro) in the North Atlantic Ocean. Greater winter mixing during positive NAO years results in increased mode water formation and subsequent increases in subtropical and subpolar Canthro inventories. Our analysis suggests that changes in mode water Canthro inventories are primarily due to changes in water mass volumes driven by variations in water mass transformation rates rather than local air-sea CO2 exchange. This suggests that a significant portion of anthropogenic carbon found in the ocean interior may be derived from surface waters advected into water formation regions rather than from local gas exchange. Therefore, changes in climate modes, such as the NAO, may alter the residence time of anthropogenic carbon in the ocean by altering the rate of water mass transformation. In addition, interannual variability in Canthro storage increases the difficulty of Canthro detection and attribution through hydrographic observations, which are limited by sparse sampling of subsurface waters in time and space.
    Description: We would like to acknowledge funding from the NOAA Climate Program under the Office of Climate Observations and Global Carbon Cycle Program (NOAA‐NA07OAR4310098), NSF (OCE‐0623034), NCAR, the WHOI Ocean Climate Institute, a National Defense Science and Engineering Graduate Fellowship and an Environmental Protection Agency STAR graduate fellowship. NCAR is sponsored by the National Science Foundation.
    Keywords: North Atlantic Oscillation ; Anthropogenic carbon ; Carbon cycle ; Climate change ; Global climate model ; Mode waters
    Repository Name: Woods Hole Open Access Server
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  • 2
    Publication Date: 2022-05-25
    Description: This paper is not subject to U.S. copyright. The definitive version was published in Deep Sea Research Part I: Oceanographic Research Papers 74 (2013): 48-63, doi:10.1016/j.dsr.2012.12.005.
    Description: Detection and attribution of hydrographic and biogeochemical changes in the deep ocean are challenging due to the small magnitude of their signals and to limitations in the accuracy of available data. However, there are indications that anthropogenic and climate change signals are starting to manifest at depth. The deep ocean below 2000 m comprises about 50% of the total ocean volume, and changes in the deep ocean should be followed over time to accurately assess the partitioning of anthropogenic carbon dioxide (CO2) between the ocean, terrestrial biosphere, and atmosphere. Here we determine the changes in the interior deep-water inorganic carbon content by a novel means that uses the partial pressure of CO2 measured at 20 °C, pCO2(20), along three meridional transects in the Atlantic and Pacific oceans. These changes are measured on decadal time scales using observations from the World Ocean Circulation Experiment (WOCE)/World Hydrographic Program (WHP) of the 1980s and 1990s and the CLIVAR/CO2 Repeat Hydrography Program of the past decade. The pCO2(20) values show a consistent increase in deep water over the time period. Changes in total dissolved inorganic carbon (DIC) content in the deep interior are not significant or consistent, as most of the signal is below the level of analytical uncertainty. Using an approximate relationship between pCO2(20) and DIC change, we infer DIC changes that are at the margin of detectability. However, when integrated on the basin scale, the increases range from 8–40% of the total specific water column changes over the past several decades. Patterns in chlorofluorocarbons (CFCs), along with output from an ocean model, suggest that the changes in pCO2(20) and DIC are of anthropogenic origin.
    Description: Rik Wanninkhof, Geun-Ha Park, John L. Bullister, and Richard A. Feely appreciate the support from the NOAA Office of Atmospheric and Oceanic Research and the Climate Observation Division. S.C.D. acknowledges support from NOAA Grant NA07OAR4310098. T.T. has been supported by grants from NSF and NOAA.
    Keywords: Ocean ; Carbon dioxide ; CO2 sink ; Anthropogenic carbon ; Deep-water
    Repository Name: Woods Hole Open Access Server
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  • 3
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2004. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 109 (2004): C08S11, doi:10.1029/2003JC001831.
    Description: During the two recent GasEx field experiments, direct covariance measurements of air-sea carbon dioxide fluxes were obtained over the open ocean. Concurrently, the National Oceanic and Atmospheric Administration/Coupled-Ocean Atmospheric Response Experiment air-sea gas transfer parameterization was developed to predict gas transfer velocities from measurements of the bulk state of the sea surface and atmosphere. The model output is combined with measurements of the mean air and sea surface carbon dioxide fugacities to provide estimates of the air-sea CO2 flux, and the model is then tuned to the GasEx-1998 data set. Because of differences in the local environment and possibly because of weaknesses in the model, some discrepancies are observed between the predicted fluxes from the GasEx-1998 and GasEx-2001 cases. To provide an estimate of the contribution to the air-sea flux of gas due to wave-breaking processes, the whitecap and bubble parameterizations are removed from the model output. These results show that moderate (approximately 15 m s−1) wind speed breaking wave gas transfer processes account for a fourfold increase in the flux over the modeled interfacial processes.
    Description: This work was supported by the NOAA Office of Global Programs, under the leadership of Dr. Lisa Dilling. WHOI was supported by the National Science Foundation grant OCE-9711218.
    Keywords: Air-sea interaction ; Air-sea flux ; Air-gas transfer
    Repository Name: Woods Hole Open Access Server
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  • 4
    Publication Date: 2022-05-25
    Description: Author Posting. © The Author(s), 2015. This is the author's version of the work. It is posted here for personal use, not for redistribution. The definitive version was published in Annual Review of Marine Science 8 (2016): 185-215, doi:10.1146/annurev-marine-052915-100829.
    Description: The ocean, a central component of Earth’s climate system, is changing. Given the global scope of these changes, highly accurate measurements of physical and biogeochemical properties need to be conducted over the full water column, spanning the ocean basins from coast to coast, and repeated every decade at a minimum, with a ship-based observing system. Since the late 1970s, when the Geochemical Ocean Sections Study (GEOSECS) conducted the first global survey of this kind, the World Ocean Circulation Experiment (WOCE) and Joint Global Ocean Flux Study (JGOFS), and now the Global Ocean Ship-based Hydrographic Investigations Program (GO-SHIP) have collected these “reference standard” data that allow quantification of ocean heat and carbon uptake, and variations in salinity, oxygen, nutrients, and acidity on basin scales. The evolving GO-SHIP measurement suite also provides new global information about dissolved organic carbon, a large bioactive reservoir of carbon.
    Description: Climate Observations Division of the U.S. NOAA Climate Program Office and NOAA Research; Joint Institute for the Study of the Atmosphere and Ocean (JISAO) under NOAA Cooperative Agreement NA10OAR4320148; U.S. National Science Foundation [OCE- 0223869; OCE-0752970; OCE-0825163; OCE-1434000; OCE 0752972; OCE-0752980; OCE-1232962; OCE-1155983; OCE-1436748]; U.S. CLIVAR Project Office; Global Environment and Marine Department, Japan Meteorological Agency; Australian Climate Change Science Program (Australian Department of Environment and CSIRO); U.K. Natural Environment Research Council; European Union’s FP7 grant agreement 264879 (CarboChange); Horizon 2020 grant agreement No 633211; ETH Zurich Switzerland.
    Keywords: Anthropogenic climate change ; Ocean temperature change ; Salinity change ; Ocean carbon cycle ; Ocean oxygen and nutrients ; Ocean chlorofluorocarbons ; Ocean circulation change ; Ocean mixing
    Repository Name: Woods Hole Open Access Server
    Type: Preprint
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  • 5
    Publication Date: 2022-10-26
    Description: © The Author(s), 2019. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Carter, B. R., Feely, R. A., Wanninkhof, R., Kouketsu, S., Sonnerup, R. E., Pardo, P. C., Sabine, C. L., Johnson, G. C., Sloyan, B. M., Murata, A., Mecking, S., Tilbrook, B., Speer, K., Talley, L. D., Millero, F. J., Wijffels, S. E., Macdonald, A. M., Gruber, N., & Bullister, J. L. Pacific anthropogenic carbon between 1991 and 2017. Global Biogeochemical Cycles, 33(5), (2019):597-617, doi:10.1029/2018GB006154.
    Description: We estimate anthropogenic carbon (Canth) accumulation rates in the Pacific Ocean between 1991 and 2017 from 14 hydrographic sections that have been occupied two to four times over the past few decades, with most sections having been recently measured as part of the Global Ocean Ship‐based Hydrographic Investigations Program. The rate of change of Canth is estimated using a new method that combines the extended multiple linear regression method with improvements to address the challenges of analyzing multiple occupations of sections spaced irregularly in time. The Canth accumulation rate over the top 1,500 m of the Pacific increased from 8.8 (±1.1, 1σ) Pg of carbon per decade between 1995 and 2005 to 11.7 (±1.1) PgC per decade between 2005 and 2015. For the entire Pacific, about half of this decadal increase in the accumulation rate is attributable to the increase in atmospheric CO2, while in the South Pacific subtropical gyre this fraction is closer to one fifth. This suggests a substantial enhancement of the accumulation of Canth in the South Pacific by circulation variability and implies that a meaningful portion of the reinvigoration of the global CO2 sink that occurred between ~2000 and ~2010 could be driven by enhanced ocean Canth uptake and advection into this gyre. Our assessment suggests that the accuracy of Canth accumulation rate reconstructions along survey lines is limited by the accuracy of the full suite of hydrographic data and that a continuation of repeated surveys is a critical component of future carbon cycle monitoring.
    Description: The data we use can be accessed at CCHDO website (https://cchdo.ucsd.edu/) and GLODAP website (https://www.glodap.info/). This research would not be possible without the hard work of the scientists and crew aboard the many repeated hydrographic cruises coordinated by GO‐SHIP, which is funded by NSF OCE and NOAA OAR. We thank funding agencies and program managers as follows: U.S., Australian, Japanese national science funding agencies that support data collection, data QA/QC, and data centers. Contributions from B. R. C., R. A. F., and R. W. are supported by the National Oceanic and Atmospheric Administration Global Ocean Monitoring and Observing Program (Data Management and Synthesis Grant: N8R3CEA‐PDM managed by Kathy Tedesco and David Legler). G. C. J. is supported by the Climate Observation Division, Climate Program Office, National Oceanic and Atmospheric Administration (NOAA), U.S. Department of Commerce and NOAA Research (fund reference 100007298), grant (N8R1SE3‐PGC). B. M. S was supported by the Australian Government Department of the Environment and CSIRO through the Australian Climate Change Science Programme and by the National Environmental Science Program. N. G. acknowledges support by ETH Zurich. This is JISAO contribution 2018‐0149 and PMEL contribution 4786. We fondly remember John Bullister as a treasured friend, valued colleague, and dedicated mentor, and we thank him for sharing his days with us. He is and will be dearly missed.
    Keywords: Anthropogenic carbon ; Pacific ; Decadal variability ; EMLR ; Ocean acidification ; Repeat hydrography
    Repository Name: Woods Hole Open Access Server
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