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  • 1
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 31 (1988), S. 889-893 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 7 (1963), S. 15-26 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Acid hydrolyses of untreated cotton (scoured) and cottons treated in slack with three swelling agents were carried out for different periods. It was found that treatment with swelling agents decreases crystallinity and fiber strength and increases reactivity of cellulose. Such treatments also improve the strength-fluidity relation of the fibers. Swelling treatment with sodium hydroxide (NaOH) or ethylenediamine (EDA) improves strength uniformity along the fiber length. Both mild and drastic hydrolyses increase crystallinity of the untreated and the treated cottons. Crystallinity figures obtained by x-ray diffraction technique are different from those obtained by iodine sorption method. Treatment of acid-hydrolyzed cotton fibers with sodium hydroxide improves fiber strength considerably. When acid-hydrolyzed cotton is swollen with zinc chloride solution, crystallinity (x-ray) drops down to as low as 36%.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 2000 (2000), S. 1959-1964 
    ISSN: 1434-193X
    Keywords: C-C coupling ; Palladium ; Silanes ; Catalysts ; Allylsilanes ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: ---One of the main problems of the Heck reaction using acyclic substrates which lead to Pd intermediates with β- and β′-hydrogens is the lack of selectivity in the formation of the double bond as the last step of the catalytic cycle. The use of allylsilanes as the alkene moiety permits control of the elimination step. Thus, the Pd0-catalysed reaction of 1a-c and 2 leads exclusively to the corresponding bicyclic compounds 11a-c. In contrast, reaction of 7 yields a mixture of 12a, (E)-12b and (Z)-12b.
    Additional Material: 1 Tab.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 33 (1995), S. 197-201 
    ISSN: 0887-624X
    Keywords: anthryl methyl vinyl ketone ; polymer ; photolysis ; drug delivery ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The photolysis of copolymers of anthrylmethyl vinyl ketone (AMVK) with styrene and methyl methacrylate has been studied, both in solution and in the solid phase. Quantum yields of the order of 0.01 were observed in both cases for release of the major product, methyl anthracene (MA). Photolysis of an aqueous emulsion of a styrene-AMVK copolymer showed similar yields of MA. The results indicate the possibility of using the Norrish type I process as a means of releasing drugs or other biologically active compounds from polymeric matrices. © 1995 John Wiley & Sons, Inc.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Publication Date: 2019-07-13
    Description: NASA is developing the Unmanned Aircraft System Traffic Management research platform to safely integrate small unmanned aircraft operations in large-scale at low-altitudes. As a part of this effort, small unmanned aircraft system off-nominal operational situations data collection process has been developed to take lessons learned and to reinforce operational compliance. In this paper, descriptions of variables used for digital data collection and an online report form for collection of observational data from the operators (contextual data) are provided. They are used to collect off-nominal data from the Unmanned Aircraft System Traffic Management National Campaign in 2017. The digital data show that 2 out of 118 campaign operations (1.7%) encountered loss of navigation. Since the campaign aircraft used Global Positioning System for navigation, it is likely that unobstructed view of the sky at the campaign locations contributed to this small number. Also, 4 out of 47 operations (8.5%) encountered loss of communications. A relatively short distance between ground control system and aircraft, ranging from 2300 feet to 4200 feet, likely contributed to this small number. There was no data to identify the loss of communications condition, aircraft received signal strength, for the remaining 71 operations suggesting that some operators may not be monitoring unmanned aircraft communications system performance or monitoring it with different parameters. For the contextual data, due to the low number of total reports during the campaign, no significant trends emerged. This is an initial attempt to collect contextual data from small unmanned aircraft operators about off-nominal situations, and changes will be made to the future data collection to improve the amount and quality of the information.
    Keywords: Air Transportation and Safety
    Type: ARC-E-DAA-TN57430 , Aviation Forum 2018; Jun 25, 2018 - Jun 29, 2018; Atlanta, GA; United States
    Format: application/pdf
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  • 6
    Publication Date: 2019-09-13
    Description: No abstract available
    Keywords: Air Transportation and Safety
    Type: ARC-E-DAA-TN73054-2 , Digital Avionics Systems Conference (DASC); Sep 08, 2019 - Sep 12, 2019; San Diego, CA; United States
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  • 7
    Publication Date: 2019-07-13
    Description: No abstract available
    Keywords: Air Transportation and Safety
    Type: ARC-E-DAA-TN33796 , Unmanned Aircraft Systems (UAS) Traffic Management (UTM) Weather Workshop; Jul 19, 2016 - Jul 21, 2016; Moffett Field, CA; United States
    Format: application/pdf
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  • 8
    Publication Date: 2019-11-08
    Description: NASA has been researching prototype technologies for an Unmanned Aircraft System (UAS) Traffic Management (UTM) system to facilitate enabling of safe and efficient civilian low-altitude airspace and UAS operations, in a series of Technical Capability Levels (TCL) activities that are increasingly complex. In TCL1, completed in 2015, visual line-of-sight operations such as agriculture, firefighting and infrastructure monitoring were addressed with a focus on geofencing and operations scheduling. Technologies and requirements needed for beyond visual line-of-sight (BVLOS) operations in sparsely populated areas were examined in TCL2 in 2016, and those for operations over moderately populated areas in TCL3 in 2017 and 2018. TCL4 will build on the earlier TCLs and focus on technologies and requirements for operations in higher-density urban areas for tasks such as news gathering, package delivery and for managing large-scale contingencies. This paper describes a communications test conducted in TCL3 and discusses insights gained from the test. In the test, operators were directed to equip UAS with redundant Command and Control (C2) communications systems, send a maneuver command to Unmanned Aircraft (UA) via the primary system, then verify execution of the sent command. This exercise was repeated with each redundant system. The test was designed to assess effectiveness of redundant C2 systems in maintaining operational control of UA. Several UAS were configured with varying arrangements to achieve redundancy, including two identical radio modems using the same frequency band, WiFi and Long-Term Evolution (LTE) cellular modems, etc. From the test, digital data such as time maneuver command sent, time maneuver verified, etc., were collected. Descriptions of methods to detect loss of C2 communications and contingency steps for such event were collected and assessed. The final paper will include a detailed analysis of the collected data leading to the following insights. First, effectiveness of redundant C2 systems depends on several factors, such as operational environment and communications service availability. For example, use of two identical point-to-point radio to connect operator and UA on the same frequency band can be effective in mitigating radio malfunction when operating in an environment where possibility of Radio Frequency (RF) interference is low, such as over open plains. However, the same arrangement may not be effective where high level of RF transmissions in broad spectrum ranges can be expected, such as over or near urban areas. For redundant systems that consist of external communications services, such as cellular and satellite communications network, redundancy is maintained only in the areas where more than one services are available. Therefore, UAS operators should have the means to plan for and monitor the performance of external communications services they are relying on to control UA. Second, communications performance needs, such as the minimum data transfer rate and the maximum tolerable latency, should be assessed to reflect the potential hazard that can come from loss of UA control. For example, UA operations over desolate area pose less hazard to people than operations over densely populated area and performance need for the former would be less than the latter.
    Keywords: Air Transportation and Safety
    Type: ARC-E-DAA-TN73288 , Digital Avionics Systems Conference (DASC); Sep 08, 2019 - Sep 12, 2019; San Diego, CA; United States
    Format: application/pdf
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  • 9
    Publication Date: 2019-07-13
    Description: NASA is developing the Unmanned Aircraft System Traffic Management research platform to safely integrate small unmanned aircraft operations in large-scale at low-altitudes. As a part of this effort, small unmanned aircraft system off-nominal operational situations data collection process has been developed to take lessons learned and to reinforce operational compliance. In this paper, descriptions of variables used for digital data collection and an online report form for collection of observational data from the operators (contextual data) are provided. They are used to collect off-nominal data from the Unmanned Aircraft System Traffic Management National Campaign in 2017. The digital data show that 2 out of 118 campaign operations (1.7%) encountered loss of navigation. Since the campaign aircraft used Global Positioning System for navigation, it is likely that unobstructed view of the sky at the campaign locations contributed to this small number. Also, 4 out of 47 operations (8.5%) encountered loss of communications. A relatively short distance between ground control system and aircraft, ranging from 2300 feet to 4200 feet, likely contributed to this small number. There was no data to identify the loss of communications condition, aircraft received signal strength, for the remaining 71 operations suggesting that some operators may not be monitoring unmanned aircraft communications system performance or monitoring it with different parameters. For the contextual data, due to the low number of total reports during the campaign, no significant trends emerged. This is an initial attempt to collect contextual data from small unmanned aircraft operators about off-nominal situations, and changes will be made to the future data collection to improve the amount and quality of the information.
    Keywords: Air Transportation and Safety
    Type: ARC-E-DAA-TN56071 , AIAA Aviation Forum 2018; Jun 25, 2018 - Jun 29, 2018; Atlanta, GA; United States
    Format: application/pdf
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  • 10
    Publication Date: 2019-09-13
    Description: The goal of the Unmanned Aircraft System (UAS) Traffic Management (UTM) effort at NASA is to enable access to low-altitude airspace for small UAS. This goal is being achieved partly through partnerships that NASA has developed with the FAA, other government agencies, the UAS stakeholder community, and the designated FAA UAS Test Sites. This paper reports the technical and operational capabilities demonstrated during the UTM flight demonstration, March 6 through May 30, 2018. The demonstration featured geographically diverse operations, involving FAA UAS Test Sites in Alaska, Nevada, New York, North Dakota, Texas and Virginia. The demonstration leveraged the contributions of 30 partner organizations serving as UAS service suppliers, UAS operators, and/or providers of sensors, surveillance, connectivity, and management roles. Utilizing the UTM architecture developed at NASA, the demonstration explored 11 use cases for small UAS operations to highlight UTM capabilities at what NASA calls Technical Capability Level (TCL) 3. TCL 3 is characterized by multiple small UAS safely operating in moderately populated areas and beyond the visual line of sight of their operators. The TCL 3 flights demonstrated the basic feasibility of such operations in the UTM environment, including USS exchanges; communication, navigation and surveillance functions; sense and avoid capabilities; and technologies and procedures to enable them.
    Keywords: Air Transportation and Safety
    Type: ARC-E-DAA-TN73054-1 , Digital Avionics Systems Conference (DASC); Sep 08, 2019 - Sep 12, 2019; San Diego, CA; United States
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