ISSN:
0947-3440
Keywords:
Homoallyl ethers
;
Acetals
;
Unsaturated fatty esters
;
Addition reactions
;
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The ethylaluminium dichloride induced reactions of methyl 10-undecenoate (1) with dimethyl acetals of formaldehyde 2a, acetaldehyde 2b, isobutyraldehyde 2c, and pivaldehyde 2d gave the corresponding homoallyl ethers 3a, 3b, 3c, and 3d in yields of 48-70%. The products were obtained as mixtures of the (E) and (Z) stereoisomers. With formaldehyde dimethyl acetal (2a), methyl oleate (6), and methyl petroselinate (11) gave the corresponding regioisomeric (E)-configured homoallyl ethers 7/8 and 12/13.
Additional Material:
1 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/jlac.199619961119
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