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  • 1
    Electronic Resource
    Electronic Resource
    Ethylaluminium Dichloride Induced Reactions of Acetals with Unsaturated Carboxylic Esters: Synthesis of Homoallyl Ethers (1996)
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 1996 (1996), S. 1851-1854 
    Details
    ISSN: 0947-3440
    Keywords: Homoallyl ethers ; Acetals ; Unsaturated fatty esters ; Addition reactions ; Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The ethylaluminium dichloride induced reactions of methyl 10-undecenoate (1) with dimethyl acetals of formaldehyde 2a, acetaldehyde 2b, isobutyraldehyde 2c, and pivaldehyde 2d gave the corresponding homoallyl ethers 3a, 3b, 3c, and 3d in yields of 48-70%. The products were obtained as mixtures of the (E) and (Z) stereoisomers. With formaldehyde dimethyl acetal (2a), methyl oleate (6), and methyl petroselinate (11) gave the corresponding regioisomeric (E)-configured homoallyl ethers 7/8 and 12/13.
    Additional Material: 1 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/jlac.199619961119
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