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  • Homogeneous catalysis  (2)
  • 053-2; 057-1; 087-1; 162-983; 165-1002; 172-1060; 175-1078C; 175-1084; 293; 311; 3664N/S; 63F/NL; 90b; 94-609; Agadir Canyon; ALIENOR; ALTITUDE; AMADEUS; Amazon Fan; AMOCINT, IMAGES XVII; Angola Basin; ARK-X/2; Atlantic; Atlantic Ocean; Atlantic sediment cores; Azores; BC; Benguela Current, South Atlantic Ocean; Blake-Bahama Outer Ridge, North Atlantic Ocean; Box corer; CALYPSO; Calypso Corer; Calypso square corer; Calypso Square Core System; CASQ; CASQS; Cayman Rise, Caribbean Sea; CD159; CD159-10; CD159-17; CEPAG; CH22KW31; CH69-K09; Charles Darwin; CHO288-54; Comment; COMPCORE; Composite Core; consistent dating; Continental Slope Northeast Brazil; Core; CORE; Corner Rise; DAPC2; Denmark Strait; De Soto Canyon; DRILL; Drilling/drill rig; East Atlantic; ENAM9321; ENAM93-21; Event label; EW9209-1JPC; Faeroes Bank; Falkland Plateau, Southern Falkland Plateau (same site as GC526); Faroe Islands margin; Florida Strait; French Guiana; GC; GC528 CORE_NO 528; GeoB1023-5; GeoB1515-1; GeoB16202-2; GeoB16206-1; GeoB16224-1; GeoB1711; GeoB1711-4; GeoB1720-2; GeoB3202-1; GeoB3910-2; GeoB4240-2; GeoB5546-2; GeoB6201-5; GeoB7920-2; GeoB9508-5; GeoB9526-5; GEOFAR; GEOSCIENCES, MARMARCORE; GGC; GGC5; Giant gravity corer; GIK12392-1; GIK15669-1; GIK23415-9; GL1090; GL-1090; Glomar Challenger; Gravity corer; Gravity corer (Kiel type); GS07-150-17/1GC-A; Iceland; IMAGES I; IMAGES IX - PAGE; IMAGES V; IMAGES XV - Pachiderme; James Clark Ross; Joides Resolution; JOPSII-8; JR20110128; JR244; JR244-GC528; KAL; Kasten corer; KF13; KF16; KL; KM31; KN_USA; KN159-5; KN166-2; Knorr; KNR140; KNR140-2-51GGC; KNR140-51GGC; KNR159-5; KNR159-5-36GGC; KNR159-5-42JPC; KNR166-2; KNR166-2-26; KNR166-2-26JPC; KNR166-2-29; KNR166-2-29JPC; KNR166-2-31; KNR166-2-31JPC; KNR166-2-73; KNR166-2-73GGC; KNR197-10; KNR197-10-GGC17; KNR31GPC5; last 40 ky; LATITUDE; Leg162; Leg165; Leg172; Leg175; Leg94; Le Noroit; Le Suroît; LONGITUDE; M12392-1; M16/2; M17/2; M20/2; M25; M34/4; M35/1; M35003-4; M37/1; M39/1; M39/1_08-3; M39008-3; M42/4b; M46/2; M53; M53_169; M53/1; M6/6; M65/1; Marge Ibérique; Maria S. Merian; Marion Dufresne (1995); MD01-2461; MD022575; MD02-2575; MD02-2588; MD02-2588Q; MD02-2592; MD02-2594; MD03-2697; MD03-2698; MD03-2705; MD03-2707; MD04-2805CQ; MD04-2805Q; MD04-2845; MD07-3076; MD07-3076Q; MD08-3167; MD08-3180; MD08-3227G; MD09-3246; MD09-3256; MD09-3256Q; MD101; MD114; MD123; MD127; MD128; MD134; MD140; MD141; MD159; MD16-3511; MD16-3511Q; MD168; MD173; MD952002; MD95-2002; MD952006; MD95-2006; MD952010; MD95-2010; MD952014; MD95-2014; MD952037; MD95-2037; MD952039; MD95-2039; MD952040; MD95-2040; MD952041; MD95-2041; MD952042; MD95-2042; MD99-2281; MD99-2284; MD99-2331; MD99-2334; Meriadzec; Meteor (1964); Meteor (1986); Method comment; MSM20/3; N. Shetland channel; NA87-22; Namibia continental slope; Newfoundland margin; North Atlantic; North Atlantic/FLANK; North East Atlantic; Northeast Brasilian Margin; Norwegian Sea; OCE205-103GGC; OCE205-2-100GGC; OCE205-2-100GGGC; OCE205-2-103GGC; OCE326-GGC5; off Rio Paraiba do Sul; off West Africa; PALEOCINAT; PALEOCINAT II; PC; Persistent Identifier; PICABIA; Piston corer; Piston corer (BGR type); Polarstern; Porto Seamount; PRIVILEGE; PS2644-5; PS31; PS31/160-5; RAPiD-10-1P; RAPiD-17-5P; Reference/source; RETRO-2; REYKJANES-RÜCKEN; S94-2-KS04; SL; SO82; SO82_5-2; Sonne; South Atlantic; South Atlantic Ocean; Southern Ocean; South of Iceland; SU81-18; SU90-08; SU90-24; SU92; SU92-03; SWAF; Tagus-Sado canyon system; TNO57-21; Uniform resource locator/link to graphic; V29; V29-202; Vema; Victor Hensen; Vigo; Voring Plateau; western South Atlantic  (1)
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  • 1
    ISSN: 0570-0833
    Keywords: homogeneous catalysis ; industrial chemistry ; organometallic chemistry ; polymers ; reagents ; Homogeneous catalysis ; Industrial chemistry ; Organometallic compounds ; Polymers ; Reagents ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Homogeneous catalysis is the success story of organometallic chemistry. Otto Roelen's initial discovery of hydroformylation in 1938 not only entailed large-capacity production plants but was later followed by systematic research into the catalytic chemistry of the ever-growing class of organometallic compounds. Further developments in industrial chemistry towards clean, low-temperature, low-pressure, and economic processes - in feedstock or in the fine chemicals and polymer area - clearly depend on improved catalysts. Molecularly defined, tailor-made structures are the safest prerequisites for chemical selectivity; hence, organometallic compounds with their overwhelming variety of compositions and structures offer the most promising approach. Wilkinson's catalysts [HRh(CO){P(C6H5)3] and [ClRh{P(C6H5)}3}3] are outstanding examples. On the other hand, process technology has to be considered also (for example catalyst-product separation and hear-exchange problems). The following review attempts to critically assess the future trends and present demands in the applied area of orgnometallic catalysis-a “gentle art” that is far from being a mature field.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Angewandte Chemie International Edition in English 33 (1994), S. 2144-2163 
    ISSN: 0570-0833
    Keywords: Roelen, Otto ; History of chemistry ; Homogeneous catalysis ; Hydroformylation ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Otto Roelen discovered the oxo synthesis (hydroformylation) in 1938, and despite all the problems created by the war years he was able to explore successfully the fundamental aspects related to its application up to the point of building the first plant. At the same time he laid the groundwork for industrial utilization of homogeneous organometallic catalysts. Almost simultaneously, his contemporary, Walter Hieber, was investigating the basic chemistry of the same catalysts, but with no knowledge whatsoever of their potential application. Hydroformylation today constitutes one of the most important industrial examples of a homogeneous catalytic process.For corrigendum see DOI:10.1002/anie.199423481
    Additional Material: 15 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Publication Date: 2024-04-25
    Description: Rapid changes in ocean circulation and climate have been observed in marine-sediment and ice cores over the last glacial period and deglaciation, highlighting the non-linear character of the climate system and underlining the possibility of rapid climate shifts in response to anthropogenic greenhouse gas forcing. To date, these rapid changes in climate and ocean circulation are still not fully explained. One obstacle hindering progress in our understanding of the interactions between past ocean circulation and climate changes is the difficulty of accurately dating marine cores. Here, we present a set of 92 marine sediment cores from the Atlantic Ocean for which we have established age-depth models that are consistent with the Greenland GICC05 ice core chronology, and computed the associated dating uncertainties, using a new deposition modeling technique. This is the first set of consistently dated marine sediment cores enabling paleoclimate scientists to evaluate leads/lags between circulation and climate changes over vast regions of the Atlantic Ocean. Moreover, this data set is of direct use in paleoclimate modeling studies.
    Keywords: 053-2; 057-1; 087-1; 162-983; 165-1002; 172-1060; 175-1078C; 175-1084; 293; 311; 3664N/S; 63F/NL; 90b; 94-609; Agadir Canyon; ALIENOR; ALTITUDE; AMADEUS; Amazon Fan; AMOCINT, IMAGES XVII; Angola Basin; ARK-X/2; Atlantic; Atlantic Ocean; Atlantic sediment cores; Azores; BC; Benguela Current, South Atlantic Ocean; Blake-Bahama Outer Ridge, North Atlantic Ocean; Box corer; CALYPSO; Calypso Corer; Calypso square corer; Calypso Square Core System; CASQ; CASQS; Cayman Rise, Caribbean Sea; CD159; CD159-10; CD159-17; CEPAG; CH22KW31; CH69-K09; Charles Darwin; CHO288-54; Comment; COMPCORE; Composite Core; consistent dating; Continental Slope Northeast Brazil; Core; CORE; Corner Rise; DAPC2; Denmark Strait; De Soto Canyon; DRILL; Drilling/drill rig; East Atlantic; ENAM9321; ENAM93-21; Event label; EW9209-1JPC; Faeroes Bank; Falkland Plateau, Southern Falkland Plateau (same site as GC526); Faroe Islands margin; Florida Strait; French Guiana; GC; GC528 CORE_NO 528; GeoB1023-5; GeoB1515-1; GeoB16202-2; GeoB16206-1; GeoB16224-1; GeoB1711; GeoB1711-4; GeoB1720-2; GeoB3202-1; GeoB3910-2; GeoB4240-2; GeoB5546-2; GeoB6201-5; GeoB7920-2; GeoB9508-5; GeoB9526-5; GEOFAR; GEOSCIENCES, MARMARCORE; GGC; GGC5; Giant gravity corer; GIK12392-1; GIK15669-1; GIK23415-9; GL1090; GL-1090; Glomar Challenger; Gravity corer; Gravity corer (Kiel type); GS07-150-17/1GC-A; Iceland; IMAGES I; IMAGES IX - PAGE; IMAGES V; IMAGES XV - Pachiderme; James Clark Ross; Joides Resolution; JOPSII-8; JR20110128; JR244; JR244-GC528; KAL; Kasten corer; KF13; KF16; KL; KM31; KN_USA; KN159-5; KN166-2; Knorr; KNR140; KNR140-2-51GGC; KNR140-51GGC; KNR159-5; KNR159-5-36GGC; KNR159-5-42JPC; KNR166-2; KNR166-2-26; KNR166-2-26JPC; KNR166-2-29; KNR166-2-29JPC; KNR166-2-31; KNR166-2-31JPC; KNR166-2-73; KNR166-2-73GGC; KNR197-10; KNR197-10-GGC17; KNR31GPC5; last 40 ky; LATITUDE; Leg162; Leg165; Leg172; Leg175; Leg94; Le Noroit; Le Suroît; LONGITUDE; M12392-1; M16/2; M17/2; M20/2; M25; M34/4; M35/1; M35003-4; M37/1; M39/1; M39/1_08-3; M39008-3; M42/4b; M46/2; M53; M53_169; M53/1; M6/6; M65/1; Marge Ibérique; Maria S. Merian; Marion Dufresne (1995); MD01-2461; MD022575; MD02-2575; MD02-2588; MD02-2588Q; MD02-2592; MD02-2594; MD03-2697; MD03-2698; MD03-2705; MD03-2707; MD04-2805CQ; MD04-2805Q; MD04-2845; MD07-3076; MD07-3076Q; MD08-3167; MD08-3180; MD08-3227G; MD09-3246; MD09-3256; MD09-3256Q; MD101; MD114; MD123; MD127; MD128; MD134; MD140; MD141; MD159; MD16-3511; MD16-3511Q; MD168; MD173; MD952002; MD95-2002; MD952006; MD95-2006; MD952010; MD95-2010; MD952014; MD95-2014; MD952037; MD95-2037; MD952039; MD95-2039; MD952040; MD95-2040; MD952041; MD95-2041; MD952042; MD95-2042; MD99-2281; MD99-2284; MD99-2331; MD99-2334; Meriadzec; Meteor (1964); Meteor (1986); Method comment; MSM20/3; N. Shetland channel; NA87-22; Namibia continental slope; Newfoundland margin; North Atlantic; North Atlantic/FLANK; North East Atlantic; Northeast Brasilian Margin; Norwegian Sea; OCE205-103GGC; OCE205-2-100GGC; OCE205-2-100GGGC; OCE205-2-103GGC; OCE326-GGC5; off Rio Paraiba do Sul; off West Africa; PALEOCINAT; PALEOCINAT II; PC; Persistent Identifier; PICABIA; Piston corer; Piston corer (BGR type); Polarstern; Porto Seamount; PRIVILEGE; PS2644-5; PS31; PS31/160-5; RAPiD-10-1P; RAPiD-17-5P; Reference/source; RETRO-2; REYKJANES-RÜCKEN; S94-2-KS04; SL; SO82; SO82_5-2; Sonne; South Atlantic; South Atlantic Ocean; Southern Ocean; South of Iceland; SU81-18; SU90-08; SU90-24; SU92; SU92-03; SWAF; Tagus-Sado canyon system; TNO57-21; Uniform resource locator/link to graphic; V29; V29-202; Vema; Victor Hensen; Vigo; Voring Plateau; western South Atlantic
    Type: Dataset
    Format: text/tab-separated-values, 563 data points
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