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  • 1
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Cell Biochemistry and Function 2 (1984), S. 23-25 
    ISSN: 0263-6484
    Keywords: Blood ; fatty acids ; platelet ; membrane ; myeloproliferative disorders ; Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Medicine
    Notes: The fatty acid composition of platelet membranes has been analysed in patients with thrombocytosis due to myeloproliferative disorders, who had not taken any drugs. A significant increase in palmitic and oleic acid, together with a decrease in stearic, linoleic and arachidonic acids was observed. The fatty acid pattern of platelet membranes was also analysed in patients during treatment with ASA (acetylsalicylic acid). ASA ingestion completely normalizes the platelet content of palmitic acid and partially that of stearic and arachidonic acid, whereas it has no effect on the level of linoleic acid and raises that of oleic acid. The altered pattern of fatty acids observed in patients may interfere with platelet function by decreasing membrane fluidity. Treatment of patients with ASA seems to act on platelet membranes by partially normalizing the fatty acid composition.
    Additional Material: 2 Tab.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 124 (1991), S. 63-67 
    ISSN: 0009-2940
    Keywords: Dinuclear gold complex ; Silyl complex ; Gold-gold interaction ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Transition-Metal Silyl Complexes, 361).  -  On the Question of Gold-Gold Interactions in Ph2P[CH2]t(2)PPh2-Bridged Dinuclear Gold Silyl ComplexesDinuclear silyl gold complexes of the type dppm(AuSiR3)2 (1) or dppe(AuSiR3)2 (2) are prepared by the reaction of dppm-(AuCl)2 or dppe(AuCl)2 with two equivalents of LiSi(aryl)3 or LiSi(SiMe3)3 The complex dppe[AuSi(SiMe3)3]2 (2 c) exhibits crystallographic inversion symmetry, and therefore the distance between both gold atoms is a maximum. In dppm-(AuSiPh3)2 (1b) a gold-gold interaction between both gold atoms is observed [Au  -  Au 316.80(3) pm].
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 124 (1991), S. 743-751 
    ISSN: 0009-2940
    Keywords: Stannyl complexes ; Hydride complexes ; Three-center bonds ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Transition-Metal Stannyl Complexes, 3. - Metal, Hydrogen, Tin Three-Center Bonding in Group VI Hydrido Stannyl ComplexesThe hydrido stannyl complex (π-1,3,5-Me3C6H3)(CO)2Cr(H)-SnPh3 (1) is prepared by photochemical reaction of (π-1,3,5-Me3C6H3)(CO)3Cr with HSnPh3. The 119SnHCr coupling constant (327.6 Hz) and an X-ray structure analysis [Sn - H 202(4), Cr - H 159(4), Cr - Sn 270.16(6) pm] show that the Sn - H bond is coordinated in an η2 fashion. The complexes (CO)4(R3P)-W(H)SnPh3 (R3P=Ph3P, MePh2P) (2) and (CO)3(dppe)M(H)-SnR3 (M=Cr, SnR3=SnPh3; M=Mo, SnR3=SnMe3, SnPh3; M=W, SnR3=SnMe3, SnPh2Me, SnPh3) (4 - 6) are obtained either by thermal reaction of (CO)4(R3P)W(THF) or (CO)3(dppe)ML (L=THF, acetone) with HSiR3, or by photochemical reaction of (CO)4(dppe)M with HSnPh3. Reaction of (CO)4(Ph3P)W(THF) with HSnMe3 yields (CO)4(Ph3P)W(Sn-Me3)2 (3). The Sn,M,H coupling constants in the complexes 2 and (CO)3(dppe)M(H)SnR3 (M=Cr, Mo) are in the range of 250 - 315 Hz and therefore these complexes seem to contain an η2-coordinated stannane. Contrary to this, the SnWH coupling constants in (CO)3(dppe)W(H)SnR3 are considerably lower (70 - 90 Hz), suggesting complete oxidative addition of the H - Sn bond. The complexes (CO)3(dppe)M(H)SnPh3 decompose in benzene solution at room temperature to give, inter alia, hexaphenyldistannane. Ph6Sn2 · 2 C6H6 crystallizes in the space group \documentclass{article}\pagestyle{empty}\begin{document}$ R\bar 3 $\end{document} (Z=1); in the crystal lattice the benzene molecules are perpendicular to the three-fold axis of symmetry of the distannane molecule.
    Additional Material: 2 Ill.
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  • 4
    ISSN: 0009-2940
    Keywords: Gold complex, dinuclear / Silyl complex / Gold - gold interaction ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Transition-Metal Silyl Complexes, 34. - A Dinuclear Gold Silyl Complex with Gold- Gold Interaction Between an (R3P)2Au and an (R′3,Si)ClAu UnitPh2MeP-Au-Cl reacts with Ph2MeP-Au-SiPh3 to form the dinuclear complex (Ph2MeP)2Au2(Cl)SiPh3, which is in equilibrium with its starting compounds. An X-ray structure analysis reveals that it consists of a (Ph2MeP)2Au and a (Ph3Si)ClAu unit, which are held together by Au-Au interaction [298.07(4) Pm]. The approximately linear AuL2 units are orthogonal to each other.
    Additional Material: 1 Ill.
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  • 5
    Publication Date: 2021-06-14
    Description: Southwestern Sicily is an area of infrequent seismic activity; however, some studies carried out in the archaeological Selinunte site suggest that, between the fourth century BC and the early Middle Ages, probably at least two earthquakes strucked this area with enough energy to damage and cause the collapse and kinematics of much of the architecture of Selinunte. Take into account that, in 2008, a noninvasive archaeological prospection and traditional data gathering methods along the Acropolis north fortifications were carried out. Following these first studies, after about 10 years, a new geophysical campaign was carried out. This second campaign benefited from the application of modern technologies for the acquisition and processing of the point cloud data on the northern part of the Acropolis, like terrestrial laser scanning and unmanned aerial vehicle photogrammetry. In this paper, we present the application of these techniques and a strategy for their integration for the 3D modelling of buildings and cultural heritages. We show how the integration of data acquired independently by these two techniques is an added value able to overcome the intrinsic limits of the individual techniques. The application to Selinunte's Acropolis allowed it to highlight and measure with high accuracy fractures, dislocation, inclinations of walls, depressions of some areas and other interesting observations, which may be important starting points for future investigations.
    Description: Published
    Description: 153-165
    Description: 2IT. Laboratori analitici e sperimentali
    Description: JCR Journal
    Keywords: 3D reconstruction ; archaeological survey ; digital elevation model ; Selinunte Archaeological Park ; terrestrial laser scanning ; unmanned aerial vehicle photogrammetry ; 05.04. Instrumentation and techniques of general interest ; 04.02. Exploration geophysics ; 05.02. Data dissemination ; 05.06. Methods
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 6
    Publication Date: 2021-02-23
    Description: Nanotechnology-based materials are currently being tested in the protection of cultural heritage: ethyl silicate or silica nanoparticles dispersed in aqueous colloidal suspensions mixed with titanium dioxide are used as a coating for stone materials. These coatings can play a key role against the degradation of stone materials, due to the deposit of organic matter and other contaminants on the substrate, a phenomenon that produces a greater risk for the monuments in urban areas because of the increasing atmospheric pollution. However, during the application phase, it is important to evaluate the amount of titanium dioxide in the coatings on the substrate, as it can produce a coverage effect on the asset. In this work, we present the hyperspectral data obtained through a field spectroradiometer on samples of different stone materials, which have been prepared in laboratory with an increasing weight percentage of titanium dioxide from 0 to 8 wt%. The data showed spectral signatures dependent on the content of titanium dioxide in the wavelength range 350–400 nm. Afterwards, blind tests were performed on other samples in order to evaluate the reliability of these measurements in detecting the unknown weight percentage of titanium dioxide. Moreover, an investigation was also performed on a test application of nanoparticle coatings on a stone statue located in a coastal town in Calabria (southern Italy). The results showed that the surveys can be useful for verifying the phase of application of the coating on cultural heritage structures; however, they could also be used to check the state of the coated stone directly exposed over time to atmospheric, biological and chemical agents.
    Description: Published
    Description: id 92
    Description: 2IT. Laboratori analitici e sperimentali
    Description: JCR Journal
    Keywords: protective coatings ; nanoparticle films ; titanium dioxide ; stone surface conservation ; spectroradiometric data ; hyperspectral signatures ; cultural heritage protection ; 05.04. Instrumentation and techniques of general interest ; 05.06. Methods ; 05.08. Risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 7
    Publication Date: 2020-05-19
    Description: Both assessment and mitigation of seismic vulnerability connected to cultural heritages monitoring are non-trivial issues, based on the knowledge of structural and environmental factors potential impacting the cultural heritage. A holistic approach could be suitable to provide an effective monitoring of cultural heritages within their surroundings at different spatial and temporal scales. On the one hand, the analysis about geometrical and structural properties of monuments is important to assess their state of conservation, their response to external stresses as well as anomalies related to natural and/or anthropogenic phenomena (e.g. the aging of materials, seismic stresses, vibrational modes). On the other hand, the investigation of the surrounding area is relevant to assess environmental properties and natural phenomena (e.g. landslides, earthquakes, subsidence, seismic response) as well as their related impacts on the monuments. Within such a framework, a multi-disciplinary system has been developed and here presented for the monitoring of cultural heritages for seismic vulnerability assessment and mitigation purposes*. It merges geophysical investigations and modeling, in situ measurements and multi-platforms remote sensing sensors for the non-destructive and non-invasive multi-scales monitoring of historic buildings in a seismic-prone area. In detail, the system provides: a) the long-term and the regional-scale analysis of buildings’ environment through the integration of seismogenic analysis, airborne magnetic surveys, space-borne Synthetic Aperture Radar (SAR) and multi-spectral sensors. They allow describing the sub-surface fault systems, the surface deformation processes and the land use mapping of the regional-scale area on an annual temporal span; b) the short-term and the basin-scale analysis of building’s neighborhood through geological setting and geotechnical surveys, airborne Light Detection And Radar (LiDAR) and ground-based SAR sensors. They enable assessing the site seismic effects, the built-up structural features and the surface deformation processes of the local-scale area on a monthly temporal span; c) the real- to near-real-time and building scale analysis of the heritage through proximal remotely sensing tools (e.g. terrestrial laser scanning, infrared thermal cameras and real aperture radar), combined with ambient vibration tests. They allow analyzing geometric, structural and material properties / anomalies of buildings as well as the state of conservation of structures on a real-time temporal span. The proposed approach is: Specific (it targets the cultural heritages monitoring for seismic mitigation purposes); Measurable (it provides synthetic descriptors or maps able to quantify structural and the environmental properties / anomalies / trends); Action-oriented (it provides information to plan consolidation and restoration actions for prevention activity); Relevant (it allows achieving consolidated results for cultural heritage monitoring); Time-related (it specifies when the results can be achieved). Meaningful results, obtained for the Saint Augustine Complex (XVI century) located in the historic center of the Calabrian chief town of Cosenza, are presented in terms of a web-based Geographic Information System (GIS) platform and a 3-dimensional (3D) visual software for the monitoring of environmental/urban landscapes and buildings. These tools represent the added-value products of the proposed SMART system, which allow integrating and combining multi-sensors analyses in order to support end-users involved into a cultural heritage monitoring.
    Description: Copernicus Meetings
    Description: Published
    Description: Vienna | Austria | 17–22 April 2016
    Description: 5T. Sismologia, geofisica e geologia per l'ingegneria sismica
    Keywords: seismic vulnerability ; cultural heritages monitoring ; multi-disciplinary system ; SMART system ; 05.04. Instrumentation and techniques of general interest
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Conference paper
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  • 8
    Publication Date: 2023-11-20
    Description: The study aims to analyse the vibrations induced by traffic on the Villa Farnesina in Rome. The ancient building was designed and erected by the architect Baldassarre Peruzzi and the walls, vaults and lodges were decorated with frescoes attributable to Raphael and other relevant Italian Renaissance painters. Villa Farnesina is located near the Lungotevere road, therefore it suffers the dangerous effects due to the urban traffic even with heavy vehicles passing, so much so that in the early seventies an anti-vibration paving was built. A six-month geophysical monitoring made it possible to analyse the propagation of the waves on the building, characterizing the vibration due to the current traffic level. The results show the vibration levels recorded on the different floors of the building.
    Description: Published
    Description: International Conference on Metrology for Archaeology and Cultural Heritage (MetroArchaeo 2021) 20-22 October 2021, Milan, Italy
    Description: 7A. Geofisica per il monitoraggio ambientale
    Description: 7SR AMBIENTE – Servizi e ricerca per la società
    Keywords: Cultural Heritage ; Traffic-induced vibrations ; Villa Farnesina ; 05.04. Instrumentation and techniques of general interest ; 05.06. Methods
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Conference paper
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  • 9
    Publication Date: 2022-11-21
    Description: A multidisciplinary approach is often the only way to assess the state of the cultural heritage, thus involving different specialist expertise and techniques. The paper shows the paired use of terrestrial laser scanning (TLS) and geophysical monitoring (GM) to detect past effects and analyse the actual vibration levels induced by traffic on cultural heritage. The case study is the Villa Farnesina, one of the most important Renaissance buildings commissioned by the banker Agostino Chigi. The Villa contains frescoes attributed to Raphael and other famous 16th century artists, and it is located a few meters from the Lungotevere, which is one of the busiest roads in the historic centre of Rome. Testimonies report the damages caused by the construction of the embankment of the Tiber River, as well as by the traffic in the second half of the 20th century, so much so as to require requalification of the road artery. The TLS survey allows for detecting cracks and deteriorations of the frescoes, although these were subjected to restoration activities over the time, whereas the (GM) allows analysing actual vibrations induced by traffic at the different floors and outside the Villa. Although the measured vibration limits, as velocity peaks in defined frequency ranges, are below the thresholds established by international codes, the importance of the wall paintings and their already-shown susceptibility to damage suggest keeping the building under constant monitoring.
    Description: Published
    Description: 5818
    Description: 7A. Geofisica per il monitoraggio ambientale
    Description: 7SR AMBIENTE – Servizi e ricerca per la società
    Description: 2IT. Laboratori analitici e sperimentali
    Description: JCR Journal
    Keywords: terrestrial laser scanning ; geophysical monitoring ; cultural heritage ; traffic-induced vibrations ; Raphael’s frescoes ; Villa Farnesina ; Lodge of Galatea ; 05.04. Instrumentation and techniques of general interest ; 04.02. Exploration geophysics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 10
    Publication Date: 2022-12-13
    Description: Da venerdì 4 novembre a domenica 6 novembre 2022, si è tenuta una esercitazione nazionale denominata “Exe Sisma dello Stretto 2022” in un'area del territorio della Regione Calabria e della Regione Sicilia caratterizzata da una elevatissima pericolosità sismica. L’esercitazione è stata indetta e coordinata dal Dipartimento della Protezione Civile e aveva l’obiettivo di verificare la risposta operativa a un evento sismico significativo del Servizio Nazionale della Protezione Civile, di cui anche l’Istituto Nazionale di Geofisica e Vulcanologia fa parte. Durante le tre giornate, l’INGV ha avuto modo di testare tutte le procedure che l’Istituto ha codificato a partire da quelle del “Protocollo di Ente per le emergenze sismiche e da maremoto”. Dopo che INGV ha dato l’avvio all’intera esercitazione simulando il terremoto di magnitudo MW 6.2 (ML 6.0) alle ore 09:00 UTC in provincia di Reggio Calabria (5 km a SW dal comune di Laganadi), e ha, quindi, inviato il messaggio per il potenziale maremoto con un livello di allerta arancione; inoltre, il Presidente INGV ha prontamente convocato l’Unità di Crisi e attivato tutti Gruppi Operativi. Questi ultimi, nell’ambito dello scenario esercitativo, hanno verificato che i flussi di comunicazione interna e tutte le attività necessarie in emergenza sismica, presenti nei relativi protocolli operativi, risultassero rispettati. L’obiettivo primario dell’esercitazione è stato quindi quello di validare le attività previste e di aggiornare il personale afferente ai Gruppi Operativi stessi. Tra di essi, SISMIKO, che rappresenta il GO dedicato al coordinamento delle reti sismiche mobili INGV in emergenza, nelle settimane precedenti l’esercitazione ha predisposto tutte le attività che intendeva testare, descrivendole brevemente nel Documento d’impianto INGV e con maggior dettaglio in quello del Gruppo Operativo. A pochi giorni dalla chiusura dell’esercitazione, un terremoto di magnitudo ML 5.7 (MW 5.5) registrato alle ore 06:07 UTC del 09 novembre 2022 ha spostato l’attenzione dalla simulazione alla realtà.
    Description: Istituto Nazionale di Geofisica e Vulcanologia
    Description: Published
    Description: 4T. Sismicità dell'Italia
    Description: 2SR TERREMOTI - Gestione delle emergenze sismiche e da maremoto
    Description: 1IT. Reti di monitoraggio e sorveglianza
    Description: 4IT. Banche dati
    Keywords: SISMIKO ; Esercitazione ; Exercise ; Rischio Sismico Seismic risk ; Seismic risk ; 05.04. Instrumentation and techniques of general interest
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: report
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