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  • 05. General::05.02. Data dissemination::05.02.01. Geochemical data  (1)
  • Larix
  • calculation
  • Comparability
  • DYANA
  • 1
    Publication Date: 2021-06-16
    Description: The Campi Flegrei caldera collapsed 39 ka in the Neapolitan area (southern Italy) after the Campanian Ignimbrite eruption. This eruption, recognized as the largest and the most cataclysmic volcanic event in the Mediterranean area over the past 200 ka, extruded not less than 300 km3 of trachytic magma. Controversy exists over the timescales required to assemble a such large volume of silicic melt and thus whether large magmatic reservoirs can actually persist below active volcanic systems over prolonged periods of time. Uranium-series analyses have been performed on Campanian Ignimbrite whole-rocks, glass matrixes and separated minerals, and the obtained results have been interpreted in combination with data on Sr, Nd, Pb isotopes from literature. The compositionally most evolved sample which is most radiogenic with respect to Sr isotopes records a reference age of 71 ka. By contrast, U-Th internal isochrones of the three compositionally least evolved samples give identical initial Th isotope ratios and yield consistent ages predating the eruption by up to 6.4 ka. The highest Pb and Nd isotopic ratios and 230Th/232Th activity ratios together with the oldest reference age of the most evolved samples suggest the existence of a resident magma body possibly related to a magmatic system that is known to have fed earlier magmatic activity in the Campi Flegrei area. Conversely, the younger age of the least evolved and least radiogenic magma dates the crystallization/differentiation event of a chemically and isotopically new magma batch entering the reservoir of the resident magma some few thousand years before the cataclysmic eruption. Therefore, the time preceding this large caldera-forming eruption during which the large volume of Campanian Ignimbrite magma assembled and mixed is 6.4 ± 2.1 ka.
    Description: This study benefited from the financial support of the 5th Framework Programme of the European Union within the ERUPT project.
    Description: Published
    Description: 217-228
    Description: 3.5. Geologia e storia dei vulcani ed evoluzione dei magmi
    Description: JCR Journal
    Description: restricted
    Keywords: U-Th isotopes ; Campanian Ignimbrite ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 2
    ISSN: 1432-0517
    Keywords: Key words Trace elements ; Water ; Intercomparison ; Comparability ; Traceability
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract  The sixth round of the International Measurement Evaluation Programme (IMEP) is presented. The programme offers reference values, established by primary methods of measurement, against which participating laboratories can evaluate their performance. The degree of comparability is thus established against the most objective references available at present. In IMEP-6, reference values for total concentrations of 14 trace elements in a synthetic and a natural water were established mainly by isotope dilution mass spectrometry (IDMS). For the majority of the measurands, results traceable to the international system of units (SI) and having expanded uncertainties, U (k=2), of 2% could be established. Measurements results from 165 field laboratories in 29 countries are evaluated and presented as descriptive (regional, national and intercontinental) pictures of the participants' self-declared degree of experience, status of accreditation, performance (including target values for uncertainty set by authorities) and instrumental methods used. The participants' use of certified reference materials and calibrants has been documented, and some comments on this matter are raised. The results and characteristics for IMEP-6 are compared with those of IMEP-3 (1991–1993) and discussed in view of the forthcoming IMEP-9 (1998).
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 1573-5001
    Keywords: AIDS ; DYANA ; HIV-1 ; NMR structure ; ribonuclease H ; RNA-DNA hybrid ; torsion angle dynamics
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Chemistry and Pharmacology
    Notes: Abstract A high-quality NMR solution structure of the chimeric hybrid duplex r(gcaguggc)⋅r(gcca)d(CTGC) was determined using the program DYANA with its recently implemented new module FOUND, which performs exhaustive conformational grid searches for dinucleotides. To ensure conservative data interpretation, the use of 1H-1H lower distance limit constraints was avoided. The duplex comprises the tRNA–DNA junction formed during the initiation of HIV-1 reverse transcription. It forms an A-type double helix that exhibits distinct structural deviations from a standard A-conformation. In particular, the minor groove is remarkably narrow, and its width decreases from about 7.5 Å in the RNA/RNA stem to about 4.5 Å in the RNA/DNA segment. This is unexpected, since minor groove widths for A-RNA and RNA/DNA hybrid duplexes of ∼11 Å and ∼8.5 Å, respectively, were previously reported. The present, new structure supports that reverse transcriptase-associated RNaseH specificity is related primarily to conformational adaptability of the nucleic acid in 'induced-fit'-type interactions, rather than the minor groove width of a predominantly static nucleic acid duplex.
    Type of Medium: Electronic Resource
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