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  • 1
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Cell Biochemistry and Function 2 (1984), S. 23-25 
    ISSN: 0263-6484
    Keywords: Blood ; fatty acids ; platelet ; membrane ; myeloproliferative disorders ; Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Medicine
    Notes: The fatty acid composition of platelet membranes has been analysed in patients with thrombocytosis due to myeloproliferative disorders, who had not taken any drugs. A significant increase in palmitic and oleic acid, together with a decrease in stearic, linoleic and arachidonic acids was observed. The fatty acid pattern of platelet membranes was also analysed in patients during treatment with ASA (acetylsalicylic acid). ASA ingestion completely normalizes the platelet content of palmitic acid and partially that of stearic and arachidonic acid, whereas it has no effect on the level of linoleic acid and raises that of oleic acid. The altered pattern of fatty acids observed in patients may interfere with platelet function by decreasing membrane fluidity. Treatment of patients with ASA seems to act on platelet membranes by partially normalizing the fatty acid composition.
    Additional Material: 2 Tab.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 124 (1991), S. 63-67 
    ISSN: 0009-2940
    Keywords: Dinuclear gold complex ; Silyl complex ; Gold-gold interaction ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Transition-Metal Silyl Complexes, 361).  -  On the Question of Gold-Gold Interactions in Ph2P[CH2]t(2)PPh2-Bridged Dinuclear Gold Silyl ComplexesDinuclear silyl gold complexes of the type dppm(AuSiR3)2 (1) or dppe(AuSiR3)2 (2) are prepared by the reaction of dppm-(AuCl)2 or dppe(AuCl)2 with two equivalents of LiSi(aryl)3 or LiSi(SiMe3)3 The complex dppe[AuSi(SiMe3)3]2 (2 c) exhibits crystallographic inversion symmetry, and therefore the distance between both gold atoms is a maximum. In dppm-(AuSiPh3)2 (1b) a gold-gold interaction between both gold atoms is observed [Au  -  Au 316.80(3) pm].
    Additional Material: 3 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 124 (1991), S. 743-751 
    ISSN: 0009-2940
    Keywords: Stannyl complexes ; Hydride complexes ; Three-center bonds ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Transition-Metal Stannyl Complexes, 3. - Metal, Hydrogen, Tin Three-Center Bonding in Group VI Hydrido Stannyl ComplexesThe hydrido stannyl complex (π-1,3,5-Me3C6H3)(CO)2Cr(H)-SnPh3 (1) is prepared by photochemical reaction of (π-1,3,5-Me3C6H3)(CO)3Cr with HSnPh3. The 119SnHCr coupling constant (327.6 Hz) and an X-ray structure analysis [Sn - H 202(4), Cr - H 159(4), Cr - Sn 270.16(6) pm] show that the Sn - H bond is coordinated in an η2 fashion. The complexes (CO)4(R3P)-W(H)SnPh3 (R3P=Ph3P, MePh2P) (2) and (CO)3(dppe)M(H)-SnR3 (M=Cr, SnR3=SnPh3; M=Mo, SnR3=SnMe3, SnPh3; M=W, SnR3=SnMe3, SnPh2Me, SnPh3) (4 - 6) are obtained either by thermal reaction of (CO)4(R3P)W(THF) or (CO)3(dppe)ML (L=THF, acetone) with HSiR3, or by photochemical reaction of (CO)4(dppe)M with HSnPh3. Reaction of (CO)4(Ph3P)W(THF) with HSnMe3 yields (CO)4(Ph3P)W(Sn-Me3)2 (3). The Sn,M,H coupling constants in the complexes 2 and (CO)3(dppe)M(H)SnR3 (M=Cr, Mo) are in the range of 250 - 315 Hz and therefore these complexes seem to contain an η2-coordinated stannane. Contrary to this, the SnWH coupling constants in (CO)3(dppe)W(H)SnR3 are considerably lower (70 - 90 Hz), suggesting complete oxidative addition of the H - Sn bond. The complexes (CO)3(dppe)M(H)SnPh3 decompose in benzene solution at room temperature to give, inter alia, hexaphenyldistannane. Ph6Sn2 · 2 C6H6 crystallizes in the space group \documentclass{article}\pagestyle{empty}\begin{document}$ R\bar 3 $\end{document} (Z=1); in the crystal lattice the benzene molecules are perpendicular to the three-fold axis of symmetry of the distannane molecule.
    Additional Material: 2 Ill.
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  • 4
    ISSN: 0009-2940
    Keywords: Gold complex, dinuclear / Silyl complex / Gold - gold interaction ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Transition-Metal Silyl Complexes, 34. - A Dinuclear Gold Silyl Complex with Gold- Gold Interaction Between an (R3P)2Au and an (R′3,Si)ClAu UnitPh2MeP-Au-Cl reacts with Ph2MeP-Au-SiPh3 to form the dinuclear complex (Ph2MeP)2Au2(Cl)SiPh3, which is in equilibrium with its starting compounds. An X-ray structure analysis reveals that it consists of a (Ph2MeP)2Au and a (Ph3Si)ClAu unit, which are held together by Au-Au interaction [298.07(4) Pm]. The approximately linear AuL2 units are orthogonal to each other.
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  • 5
    Publication Date: 2017-04-04
    Description: Field geology, well data and seismic imaging have illuminated the upper crustal structure of the Southern Apennines. However, lack of control of the deep structure allows viable competing thin-skin and thick-skin models of the orogen. In thin-skin models the detachment decouples a stack of rootless nappes from the basement. In thick-skin models, basement is involved in the most recent phase of thrusting. To examine the deep crustal structure, we use the teleseismic recordings from the CAT/SCAN array, deployed in southern Italy from Dec. 2003-Oct. 2005. We use receiver functions processed into a Common Conversion Point stack to generate images of the crust. We image three main westward-dipping seismic-velocity discontinuities where P-to-S conversions occur. They correspond to velocity jumps at the Moho, the upper-lower crust boundary and sedimentary interfaces resulting from the contrast between clastic and carbonate strata with basement. The CCP image matches features from both thin-skin and thick skin model. The lateral continuity of the converters favors thin skin, but consistent interpretation across the image favors the thick skin. Overall, the results provide a better fit to the thick-skin interpretation. This suggests a change in structural style as the collision with Apulia halted motion. This model also implies considerably less Plio-Pleistocene shortening across the Apennines and a SE motion of the Calabrian Arc subparallel to the southern Apennines rather than a radial expansion of the Arc.
    Description: Published
    Description: AGU General Assembly, S. Francisco
    Description: 3.3. Geodinamica e struttura dell'interno della Terra
    Description: open
    Keywords: Continental Crust ; Suduction zone processes ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Oral presentation
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  • 6
    Publication Date: 2017-04-04
    Description: We analyze the seismicity of a small sector of the Northern Apennines merging data from the Italian seismic bulletin with original data collected by temporary seismic networks. Our attention is focused on the region enclosed between the Apenninic watershed and the Adriatic Sea. This portion of belt is interested by the occurrence of diffuse crustal seismicity and small-to-moderate earthquakes. In this paper we study the five small sequences with mainshock having Mw 〈 4.7 that in the past 15 years hit the area. Our interest is addressed to better understand the relationship between these events and the regional seismotectonic setting in terms of seismicity distribution and stress field. Two regions with different behavior in the seismic release can be distinguished: (i) along the watershed where seismicity is clustered at shallow depths (〈 15 km) and where strong earthquakes occurred in the past, (ii) an eastern portion where the seismicity is distributed across all of the crustal volume, locally reaching depths down to 30 km. The focal mechanism of the seismic sequences shows mainly normal fault kinematics coherent with the regional stress field. Detailed stress field analysis suggests a rotation of the principal stress axis moving from the axial part of the chain toward the Adriatic Sea to the east.
    Description: Published
    Description: 136-144
    Description: 1.1. TTC - Monitoraggio sismico del territorio nazionale
    Description: 3.2. Tettonica attiva
    Description: JCR Journal
    Description: reserved
    Keywords: Northern Apennines ; Stress field ; Focal mechanisms ; Seismicity ; 04. Solid Earth::04.06. Seismology::04.06.01. Earthquake faults: properties and evolution ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 7
    Publication Date: 2017-04-04
    Description: Global crustal model, from gravity studies, imaged a thick crust (〉40 km) under Eastern Antartic craton (EAC). This global trend ends abruptly west of the Transantarctic Mountains (TAM), which border EAC along its western margins. There, the crust raises up to about 20 km. While this model points out the difference between EAC and the Ross sea crustal structures, its intrinsic spatial resolution gives little help to solve some regional geophysical issues, like the TAM orogenesis and the formation and nature of the Wilkes Basin. In this study, teleseismic Receiver Functions (RFs) are used to image the S-velocity crustal structure in finer details. We computed RFs from teleseismic events recorded during three different austral summer compaigns: BackTAM, WIBEM and WISE. Broadband seismic stations were deployed along a transect which spans from the coast of Northern Victoria land (NVL) to the far interior of the EAC plateau. The transect, almost perpendicular to the regional TAM axis, came across four different geological/geophysical settings: the alloctonhous terranes of the NVL, the TAM sector, the Wilkes Basin and the EAC plateau. Each area shows peculiar crustal structures and we propose both finer local S-velocity models and a regional crustal model.
    Description: Published
    Description: AGU General Assembly, S. Francisco
    Description: 3.3. Geodinamica e struttura dell'interno della Terra
    Description: open
    Keywords: Antarctica ; Receiver Functions ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Poster session
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  • 8
    Publication Date: 2017-04-04
    Description: The main goal of this study is to increase the understanding of the physical mechanisms behind the ongoing seismic activity in the Pollino area and its influence on the seismic hazard of the Apennines-Calabrian arc boundary region. The study area, near the Pollino massif, is located at the northernmost edge of the Calabrian Arc, which is the last oceanic subduction segment along the Africa-Eurasian plate. The subduction results from the sinking of the Ionian oceanic plate beneath the Calabrian Arc-Southern Tyrrhenian Sea and is part of the fragmented tectonic boundary between two macro-plates: Africa and Eurasia. The subduction geometry is well-documented by several seismological studies (i.e. Chiarabba et al., 2005), and the lithospheric structure of the area is quietly well known (i.e. Totaro et al., 2014 and Piana Agostinetti and Amato, 2009) Despite the slow N-S convergence between these major plates, the Southern Tyrrhenian Sea is a large basin characterized by E-W extensional tectonic. Since Late Miocene, the Calabrian Arc slab experienced rapid rollback, moving E to SE at a rate of 5-6 cm/yr, which is by far higher than the ~1-2 cm/yr rate of convergence between Africa and Europa (Faccenna et al., 2004). However, during late Pleistocene, rollback and subduction have slowed and is likely proceeding at less than 1 cm/yr (D’Agostino and Selvaggi., 2004). Geodetic measurements show that the Pollino Range is subject to NE-SW anti-apenninic extension. In the region the strain rate field shows a continuous belt of extensional deformation that follows the ridge of the Southern Apennines and extends in the Pollino region. The extension rate appears to decrease from the Southern Apennines to the Calabria- Lucania border region (D’Agostino et al., 2013). This finding indeed reveals that the Pollino region is deforming and accumulating tectonic strain which results in a complex system of normal active faults striking sub-parallel to the Apennines. Two principal normal faults are present in the Italian Database of the Individual Seismogenic Sources DISS version 3.1.1 (DISS Working Group, 2010) in the Pollino area: the Pollino (P) fault and the “Rimendiello-Mormanno” (RM) fault system. The RM fault is an active seismogenic structure it strikes about NNW-SSE and dips toward NE; it has hosted in its northernmost part a M 5.0 earthquake on 9th September 1998. The P fault has similar strike but dips toward SW: it shows no recent seismicity and is hence one of the most prominent seismic gaps in the Italian historical seismic catalogue (Rovida et al., 2011). Paleoseismic studies have shown that the P fault was active in the last ten thousand years and is capable to produce events with magnitude above 6.0. The DISS database reports as debated source also the Piana Perretti fault (Brozzetti et al., 2009). A detailed structural map of the area interested by the seismic sequence shows three fault systems (Brozzetti et al., 2013) consisting of several aligned fault segments that have been active during the Late Pleistocene and are reasonably presently active. The first fault system strikes NW-SE and dips toward SW (including the Piana Perretti fault at the NE edge of the Mercure Basin), the second one has similar strike and NE dip, while the third one strikes about E-W. Earthquakes reported in the historical catalogues for this area are not very strong. Few earthquakes with magnitude probably less than 6 affected the area, including the Mw=5.6 “Mercure” event in 1998 (Brozzetti et al., 2009). The Parametric Catalogue of Italian earthquakes (CPTI11, Rovida et al., 2011), shows very well the lack of strong earthquakes in the region: there is a clear evidence of large earthquakes in the Campania-Basilicata area (M~7.0) and several strong earthquakes in the Sila region and in the whole Calabrian territory. According to the seismic classification of the national territory, the area affected by the 2010-2014 seismic activity have a relatively higher probability to be shaken by a strong acceleration (Gruppo di Lavoro MPS, 2004). Most of the seismic events occurred in areas where the peak ground acceleration having 10% chance of being exceeded in next 50 years is between the values of 0.225 g and 0.275 g.
    Description: Published
    Description: Bologna
    Description: 2T. Tettonica attiva
    Description: 3T. Pericolosità sismica e contributo alla definizione del rischio
    Description: 5T. Sorveglianza sismica e operatività post-terremoto
    Description: 1IT. Reti di monitoraggio e Osservazioni
    Description: open
    Keywords: Seimic Swarm, Pollino, active faults, Vp/Vs Seismic tomography, seismic anisotropy, temporary seismic network ; 04. Solid Earth::04.04. Geology::04.04.01. Earthquake geology and paleoseismology ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.04. Geology::04.04.11. Instruments and techniques ; 04. Solid Earth::04.06. Seismology::04.06.01. Earthquake faults: properties and evolution ; 04. Solid Earth::04.06. Seismology::04.06.07. Tomography and anisotropy ; 04. Solid Earth::04.06. Seismology::04.06.09. Waves and wave analysis ; 04. Solid Earth::04.07. Tectonophysics::04.07.05. Stress ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Oral presentation
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