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  • 1
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Cell Biochemistry and Function 2 (1984), S. 23-25 
    ISSN: 0263-6484
    Keywords: Blood ; fatty acids ; platelet ; membrane ; myeloproliferative disorders ; Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Medicine
    Notes: The fatty acid composition of platelet membranes has been analysed in patients with thrombocytosis due to myeloproliferative disorders, who had not taken any drugs. A significant increase in palmitic and oleic acid, together with a decrease in stearic, linoleic and arachidonic acids was observed. The fatty acid pattern of platelet membranes was also analysed in patients during treatment with ASA (acetylsalicylic acid). ASA ingestion completely normalizes the platelet content of palmitic acid and partially that of stearic and arachidonic acid, whereas it has no effect on the level of linoleic acid and raises that of oleic acid. The altered pattern of fatty acids observed in patients may interfere with platelet function by decreasing membrane fluidity. Treatment of patients with ASA seems to act on platelet membranes by partially normalizing the fatty acid composition.
    Additional Material: 2 Tab.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 124 (1991), S. 63-67 
    ISSN: 0009-2940
    Keywords: Dinuclear gold complex ; Silyl complex ; Gold-gold interaction ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Transition-Metal Silyl Complexes, 361).  -  On the Question of Gold-Gold Interactions in Ph2P[CH2]t(2)PPh2-Bridged Dinuclear Gold Silyl ComplexesDinuclear silyl gold complexes of the type dppm(AuSiR3)2 (1) or dppe(AuSiR3)2 (2) are prepared by the reaction of dppm-(AuCl)2 or dppe(AuCl)2 with two equivalents of LiSi(aryl)3 or LiSi(SiMe3)3 The complex dppe[AuSi(SiMe3)3]2 (2 c) exhibits crystallographic inversion symmetry, and therefore the distance between both gold atoms is a maximum. In dppm-(AuSiPh3)2 (1b) a gold-gold interaction between both gold atoms is observed [Au  -  Au 316.80(3) pm].
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 124 (1991), S. 743-751 
    ISSN: 0009-2940
    Keywords: Stannyl complexes ; Hydride complexes ; Three-center bonds ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Transition-Metal Stannyl Complexes, 3. - Metal, Hydrogen, Tin Three-Center Bonding in Group VI Hydrido Stannyl ComplexesThe hydrido stannyl complex (π-1,3,5-Me3C6H3)(CO)2Cr(H)-SnPh3 (1) is prepared by photochemical reaction of (π-1,3,5-Me3C6H3)(CO)3Cr with HSnPh3. The 119SnHCr coupling constant (327.6 Hz) and an X-ray structure analysis [Sn - H 202(4), Cr - H 159(4), Cr - Sn 270.16(6) pm] show that the Sn - H bond is coordinated in an η2 fashion. The complexes (CO)4(R3P)-W(H)SnPh3 (R3P=Ph3P, MePh2P) (2) and (CO)3(dppe)M(H)-SnR3 (M=Cr, SnR3=SnPh3; M=Mo, SnR3=SnMe3, SnPh3; M=W, SnR3=SnMe3, SnPh2Me, SnPh3) (4 - 6) are obtained either by thermal reaction of (CO)4(R3P)W(THF) or (CO)3(dppe)ML (L=THF, acetone) with HSiR3, or by photochemical reaction of (CO)4(dppe)M with HSnPh3. Reaction of (CO)4(Ph3P)W(THF) with HSnMe3 yields (CO)4(Ph3P)W(Sn-Me3)2 (3). The Sn,M,H coupling constants in the complexes 2 and (CO)3(dppe)M(H)SnR3 (M=Cr, Mo) are in the range of 250 - 315 Hz and therefore these complexes seem to contain an η2-coordinated stannane. Contrary to this, the SnWH coupling constants in (CO)3(dppe)W(H)SnR3 are considerably lower (70 - 90 Hz), suggesting complete oxidative addition of the H - Sn bond. The complexes (CO)3(dppe)M(H)SnPh3 decompose in benzene solution at room temperature to give, inter alia, hexaphenyldistannane. Ph6Sn2 · 2 C6H6 crystallizes in the space group \documentclass{article}\pagestyle{empty}\begin{document}$ R\bar 3 $\end{document} (Z=1); in the crystal lattice the benzene molecules are perpendicular to the three-fold axis of symmetry of the distannane molecule.
    Additional Material: 2 Ill.
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  • 4
    ISSN: 0009-2940
    Keywords: Gold complex, dinuclear / Silyl complex / Gold - gold interaction ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Transition-Metal Silyl Complexes, 34. - A Dinuclear Gold Silyl Complex with Gold- Gold Interaction Between an (R3P)2Au and an (R′3,Si)ClAu UnitPh2MeP-Au-Cl reacts with Ph2MeP-Au-SiPh3 to form the dinuclear complex (Ph2MeP)2Au2(Cl)SiPh3, which is in equilibrium with its starting compounds. An X-ray structure analysis reveals that it consists of a (Ph2MeP)2Au and a (Ph3Si)ClAu unit, which are held together by Au-Au interaction [298.07(4) Pm]. The approximately linear AuL2 units are orthogonal to each other.
    Additional Material: 1 Ill.
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  • 5
    Publication Date: 2021-07-14
    Description: We report the preliminary results from a project (GAPSS-Geothermal Area Passive Seismic Sources), aimed at testing the resolving capabilities of passive exploration methods on a well-known geothermal area, namely the Larderello-Travale Geothermal Field (LTGF). Located in the western part of Tuscany (Italy), LTGF is the most ancient geothermal power field of the world. GAPSS consisted of up to 20 seismic stations deployed over an area of about 50 x 50 Km. During the first 12 months of measurements, we located more than 2000 earthquakes, with a peak rate of up to 40 shocks/day. Preliminary results from analysis of these signals include: (i) analysis of Shear-Wave-Splitting from local earthquake data, from which we determined the areal distribution of the most anisotropic regions; (ii) local-earthquake travel-time tomography for both P- and S-wave velocities; (iii) telesismic receiver function aimed at determining the high-resolution (〈0.5km) S-velocity structure over the 0-20km depth range, and seismic anisotropy using the decomposition of the angular harmonics of the RF data-set; (iv) S-wave velocity profiling through inversion of the dispersive characteristics of Rayleigh waves from earthquakes recorded at regional distances. After presenting results from these different analyses, we eventually discuss their potential application to the characterisation and exploration of the investigated area.
    Description: Published
    Description: 227-234
    Description: 6T. Sismicità indotta e caratterizzazione sismica dei sistemi naturali
    Description: N/A or not JCR
    Description: restricted
    Keywords: Geothermal field; Local Earthquake Tomography; Shear Wave Splitting; Surface Wave Dispersion; Receiver Functions; Larderello- Travale geothermal field (Italy) ; 04. Solid Earth::04.06. Seismology::04.06.07. Tomography and anisotropy
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 6
    Publication Date: 2017-10-19
    Description: We performed three-dimensional analysis of anisotropic parameters of body waves to develop a 3D self-consistent dynamic model of the syn-convergent extension in the Northern Apennines within the multidisciplinary project RETREAT. Simultaneous extension within the convergent margin can be the consequence of the retreat of the subducting Adriatic plate from the orogenic front, caused by sub-lithosphere mantle processes that seismic anisotropy can help to decipher. We use data recorded by the RETREAT temporary array consisting of 35 stations complemented by data of permanent INGV observatories. Currently, 18-months of data are available from some stations, representing half of the passive experiment duration. We detect many examples of core-refracted shear-wave splitting within the upper mantle, and observe both distinct lateral variations of anisotropic parameters and their dependence on the direction of propagation. In particular, the fast shear-wave polarization changes from slab-perpendicular to slab-parallel along the Apennines chain. There is also a distinct change in the anisotropic signals across the presumed boundary of the Tyrrhenian and Adriatic micro-plates. Variations of the splitting time delays and orientation of the fast shear waves, together with considerations on the geodynamics of the area, seem to exclude simple sub-lithosphere mantle corner flow as the only source of the observed anisotropy. Alternate models include (1) a frozen-in fabric of different lithosphere domains, and (2) complex mantle flow associated with the Plio-Pleisocene uplift and extension of Tuscany.
    Description: Published
    Description: Vienna
    Description: 3.3. Geodinamica e struttura dell'interno della Terra
    Description: open
    Keywords: anisotropy ; SKS shear wave splitting ; Northern Apennines ; 04. Solid Earth::04.06. Seismology::04.06.07. Tomography and anisotropy ; 04. Solid Earth::04.06. Seismology::04.06.09. Waves and wave analysis ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.06. Subduction related processes
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Poster session
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  • 7
    Publication Date: 2017-04-04
    Description: We investigate in detail the crustal layering of the ‘Val di Chiana Basin’ (Northern Apennines, Tuscany, Italy) through receiver functions and seismic anisotropy with hexagonal symmetry. The teleseismic data set is recorded in correspondence of a typical foreland basin resulting by the progressive eastward retreat of a regional-scale subduction zone trapped between two continents. We study the azimuthal variations of the computed and binned receiver functions associated to a harmonic angular analysis to emphasize the presence of the dipping and the anisotropic structures. The resulting S-wave velocity model shows interesting and new results for this area that we discuss in a regional geodynamic contest contributing to the knowledge of the structure of the forearc of the subduction zone. A dipping interface (N192°E strike, 18° dip) has been revealed at about 1.5 km depth, that separates the basin sediments and flysch from the carbonates and evaporites. Moreover, we interpret the two upper-crust anisotropic layers (at about 6 and 17 km depth) as the Hercynian Phyllites and Micaschists, of the Metamorphic Tuscan Basement. At relatively shallow depths, the presence of these metamorphic rocks causes the seismic anisotropy in the upper crust. The presence of shallow anisotropic layers is a new and interesting feature, first revealed in the study area. Beneath the crust–mantle transition (Moho), located about 28 km depth, our analysis reveals a 7-km-thick anisotropic layer.
    Description: Published
    Description: 545-556
    Description: 3.3. Geodinamica e struttura dell'interno della Terra
    Description: JCR Journal
    Description: reserved
    Keywords: Seismic anisotopy ; Computational Seismology ; Wave propagation ; Subduction zone process ; Crustal structure ; Europe ; 04. Solid Earth::04.06. Seismology::04.06.07. Tomography and anisotropy
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 8
    Publication Date: 2017-04-04
    Description: The main goal of this study is to increase the understanding of the physical mechanisms behind the ongoing seismic activity in the Pollino area and its influence on the seismic hazard of the Apennines-Calabrian arc boundary region. The study area, near the Pollino massif, is located at the northernmost edge of the Calabrian Arc, which is the last oceanic subduction segment along the Africa-Eurasian plate. The subduction results from the sinking of the Ionian oceanic plate beneath the Calabrian Arc-Southern Tyrrhenian Sea and is part of the fragmented tectonic boundary between two macro-plates: Africa and Eurasia. The subduction geometry is well-documented by several seismological studies (i.e. Chiarabba et al., 2005), and the lithospheric structure of the area is quietly well known (i.e. Totaro et al., 2014 and Piana Agostinetti and Amato, 2009) Despite the slow N-S convergence between these major plates, the Southern Tyrrhenian Sea is a large basin characterized by E-W extensional tectonic. Since Late Miocene, the Calabrian Arc slab experienced rapid rollback, moving E to SE at a rate of 5-6 cm/yr, which is by far higher than the ~1-2 cm/yr rate of convergence between Africa and Europa (Faccenna et al., 2004). However, during late Pleistocene, rollback and subduction have slowed and is likely proceeding at less than 1 cm/yr (D’Agostino and Selvaggi., 2004). Geodetic measurements show that the Pollino Range is subject to NE-SW anti-apenninic extension. In the region the strain rate field shows a continuous belt of extensional deformation that follows the ridge of the Southern Apennines and extends in the Pollino region. The extension rate appears to decrease from the Southern Apennines to the Calabria- Lucania border region (D’Agostino et al., 2013). This finding indeed reveals that the Pollino region is deforming and accumulating tectonic strain which results in a complex system of normal active faults striking sub-parallel to the Apennines. Two principal normal faults are present in the Italian Database of the Individual Seismogenic Sources DISS version 3.1.1 (DISS Working Group, 2010) in the Pollino area: the Pollino (P) fault and the “Rimendiello-Mormanno” (RM) fault system. The RM fault is an active seismogenic structure it strikes about NNW-SSE and dips toward NE; it has hosted in its northernmost part a M 5.0 earthquake on 9th September 1998. The P fault has similar strike but dips toward SW: it shows no recent seismicity and is hence one of the most prominent seismic gaps in the Italian historical seismic catalogue (Rovida et al., 2011). Paleoseismic studies have shown that the P fault was active in the last ten thousand years and is capable to produce events with magnitude above 6.0. The DISS database reports as debated source also the Piana Perretti fault (Brozzetti et al., 2009). A detailed structural map of the area interested by the seismic sequence shows three fault systems (Brozzetti et al., 2013) consisting of several aligned fault segments that have been active during the Late Pleistocene and are reasonably presently active. The first fault system strikes NW-SE and dips toward SW (including the Piana Perretti fault at the NE edge of the Mercure Basin), the second one has similar strike and NE dip, while the third one strikes about E-W. Earthquakes reported in the historical catalogues for this area are not very strong. Few earthquakes with magnitude probably less than 6 affected the area, including the Mw=5.6 “Mercure” event in 1998 (Brozzetti et al., 2009). The Parametric Catalogue of Italian earthquakes (CPTI11, Rovida et al., 2011), shows very well the lack of strong earthquakes in the region: there is a clear evidence of large earthquakes in the Campania-Basilicata area (M~7.0) and several strong earthquakes in the Sila region and in the whole Calabrian territory. According to the seismic classification of the national territory, the area affected by the 2010-2014 seismic activity have a relatively higher probability to be shaken by a strong acceleration (Gruppo di Lavoro MPS, 2004). Most of the seismic events occurred in areas where the peak ground acceleration having 10% chance of being exceeded in next 50 years is between the values of 0.225 g and 0.275 g.
    Description: Published
    Description: Bologna
    Description: 2T. Tettonica attiva
    Description: 3T. Pericolosità sismica e contributo alla definizione del rischio
    Description: 5T. Sorveglianza sismica e operatività post-terremoto
    Description: 1IT. Reti di monitoraggio e Osservazioni
    Description: open
    Keywords: Seimic Swarm, Pollino, active faults, Vp/Vs Seismic tomography, seismic anisotropy, temporary seismic network ; 04. Solid Earth::04.04. Geology::04.04.01. Earthquake geology and paleoseismology ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.04. Geology::04.04.11. Instruments and techniques ; 04. Solid Earth::04.06. Seismology::04.06.01. Earthquake faults: properties and evolution ; 04. Solid Earth::04.06. Seismology::04.06.07. Tomography and anisotropy ; 04. Solid Earth::04.06. Seismology::04.06.09. Waves and wave analysis ; 04. Solid Earth::04.07. Tectonophysics::04.07.05. Stress ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Oral presentation
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