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  • Inorganic Chemistry  (4,779)
  • Lunar and Planetary Science and Exploration
  • Wiley-Blackwell  (4,779)
  • 1
    Electronic Resource
    Electronic Resource
    Electrochemical synthesis of Nickel(II) Complexes of schiff bases: The crystal structure of 2,2′-bipyridine bis{2-[(phenyl)iminomethyl]pyrrolato}nickel(II) (1992)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 612 (1992), S. 83-88 
    Details
    ISSN: 0044-2313
    Keywords: Electrochemical synthesis ; nickel(II) complexes of Schiff bases ; 2,2′ bipyridine bis 2-(phenyl)-iminomethyl pyrrolato nickel(II) ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Elektrochemische Synthese von Nickel(II)-Komplexen mit Schiffschen Basen: Kristallstruktur von 2,2′-Bipyridin-bis{2-[(phenyl)iminomethyl]pyrrolato}nickel(II)Die elektrochemische Oxidation von anodischem Nickel in einer Acetonitril-Lösung mit einer aus H-pyrrole-2-carbaldehyd abgeleiteten Schiffschen Base, einem substituierten Anilin und einem Stickstoff-Liganden (1,10-Phenanthroline (phen), 2,2′-Bipyridin (bipy) oder Pyridin (py)) liefert die gemischten Komplexe NiL2 · phen, NiL2 · bipy bzw. NiL2 · (py)2. Die Kristallstruktur von 2,2′-Bipyridin bis{2-[(phenyl)iminomethyl]-pyrrolato}nickel(II) wurde röntgenographisch bestimmt. Der. Komplex kristallisiert triklin in der Raumgruppe P1, mit den Gitterkonstanten a = 12,316(1), b = 13,169(4), c = 17,251(3) Å, α = 82,67(3)°, β = 83,66(1)°, γ = 87,34(2)°, Z = 4; besteht aus monomeren Molekülen mit der zentralen NiN6-Einheit mit verzerrt oktaedrischer Geometrie.
    Notes: The electrochemical oxidation of anodic nickel in acetonitrile solution containing both (a) a Schiff base HL derived from H-pyrrole-2-carbaldehyde and a substituted aniline, and (b) a nitrogen ligand (1, 10-phenanthroline (phen), 2,2′-bipyridine (bipy) or pyridine (py)) yielded the mixed complexes NiL2 · phen, NiL2 · bipy and NiL2 · (py)2. The crystal structure of 2,2′-bipyridine bis{2-[(phenyl)iminomethyl]pyrrolato}nickel(II) was determined by X ray diffraction. Crystals are triclinic space group P1, with four molecules in the unit cell of dimensions a = 12.316(1), b = 13.169(4), c = 17.251(3) Å, α = 82.67(3)°, β = 83.66(1)° and γ = 87.34(2)°, and consist of monomeric molecules in which the central NiN6 unit has a distorted octahedral geometry.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19926120114
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  • 2
    Electronic Resource
    Electronic Resource
    Preparation and electrical and magnetic properties of Sr2-xNaxCuO3 (0 ≤ x ≤ 1) solid solutionsDedicated to Professor Rudolf Hoppe on his 70th Birthday (1992)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 616 (1992), S. 201-207 
    Details
    ISSN: 0044-2313
    Keywords: Mixed-valence copper(II,III) oxide ; solid solutions ; semiconducting behavior ; electronic structure ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Präparation sowie elektrische und magnetische Eigenschaften der festen Lösungen Sr2-xNaxCuO3 (0 ≤ x ≤ 1)Die festen Lösungen Sr2-xNaxCuO3 (0 ≤ x ≤ 1) mit Kupfer(II,III)-oxid wurden durch Feststoffreaktionen in Sauerstoffatmosphäre dargestellt. Alle diese festen Lösungen haben die Struktur von Sr2CuO3 (Raumgruppe Immm). Elektrische Leitfähigkeits- und EMK-Messungen zeigen Halbleiterverhalten im gesamten Bereich der Zusammensetzung. Die Elektronenstruktur des Sr2CuO3 wird mit der des La2CuO4 auf Basis eines ionisch-kovalenten Modells verglichen. Die Interpretation des Transportverhaltens deutet auf kleine Polaronen. Magnetische Suszeptibilitäts- und EPR-Messungen zeigen, daß die antiferromagnetische Ordnung des Sr2CuO3 abnimmt mit zunehmendem x. Die magnetischen Wechselwirkungen sind jedoch noch stark bei einer Kupferionen- Konzentration von x = 0,8.
    Notes: Mixed-valence copper(II/III) oxide solid solutions Sr2-xNaxCuO3 (0 ≤ x ≤ 1) have been prepared by solid-state reactions in oxygen atmosphere. All solid solutions exhibit the structure of Sr2CuO3 (S.G. Immm). Electrical conductivity and thermoelectric power measurements show a semiconducting behavior in the whole composition range. The electronic structure of Sr2CuO3 is compared with that of La2CuO4 on the basis of an iono-covalent model. Interpretation of transport properties suggests the formation of small polarons. Magnetic susceptibility and EPR measurements show that the antiferromagnetic ordering of Sr2CuO3 tends to vanish as x increases, however magnetic interactions are still strong for a concentration of Cu2+ ions corresponding to x = 0.8.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19926161033
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  • 3
    Electronic Resource
    Electronic Resource
    Hydrogen Bonding and Conformational Analysis of Chelate-Stabilized Alkoxopalladium(II) Complexes Derived from Amino Alcohol Ligands (1997)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 130 (1997), S. 35-44 
    Details
    ISSN: 0009-2940
    Keywords: Alkoxopalladium(II) ; Conformational analysis ; Hydrogen bonding ; Two-dimensional and cage structures ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The reaction of palladium acetate with two equivalents of di- and triethanolamines RN(CH2CH2OH)2 in the presence of a base affords the new chelate-stabilized alkoxo Pd(II) complexes [Pd(OCH2CH2N(R)CH2CH2OH)2] [R = Me (1), Et (2), n-Bu (3), benzyl (4) or CH2CH2OH (5)]. These N,O-ligated complexes are isolated in high yield as yellow, crystalline solids and are thermally stable despite the presence of several β-hydrogen atoms in the ligand system. Both complexes possess a square-planar palladium coordination geometry with the two oxygen atoms positioned mutually trans. The most notable difference in the molecular structures is that 1 forms a two dimensional network of intermolecular O-H≡O hydrogen bonds, whereas 5 forms intramolecular O-H⃛O hydrogen bonds, which cage the palladium center. In solution 1-4 exist as a diastereoisomeric mixture (a racemic enantiomeric pair SNSN, RNRN and a mesomeric form RNSN) in a 1:1 molar ratio, and this ratio is independent of temperature in nonalcoholic solvents, When complexes 1-4 are dissolved in protic solvents (e.g. MeOH) the diastereomeric excess is temperature-dependent due to an exchange process between the meso diastereoisomer and the (racemic) enantiomeric pair. Thermodynamic parameters for this process in a mixture of MeOH-toluene have been determined with NMR and show this process to be influenced by the steric nature of the alkyl substituent (R) on nitrogen. A conformational analysis based on 1H-NMR coupling constants within the N,O-chelate ring of complexes 1-4 provides details on the solution structure of the ring in both diastereoisomers.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19971300106
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  • 4
    Electronic Resource
    Electronic Resource
    Subsite-Specific Reactions of a Cyclotriveratrylene [4Fe-4S] Cluster Complex (1997)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 130 (1997), S. 1151-1157 
    Details
    ISSN: 0009-2940
    Keywords: Iron-sulfur clusters ; S ligands ; Cyclotriveratrylene ; Subsite-specific reactions ; Electrochemistry ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Ligand exchange reactions are carried out exclusively at the unique iron site of a subsite-differentiated cyclotriveratrylene [4Fe-4S] cluster complex. The effect of a variety of thiolate, phenolate, bidentate, and bridging ligands on the redox potential of the subsite-differentiated [4Fe-4S] cluster complex is studied and compared with the effects of such ligands on an [Fe4S4C14]2- cluster. The redox potential can be modulated within the range of -1.60 to -1.80 V (vs. Fc0/+) by varying the ligand. The introduction of an electron releasing substituent shifts the redox potential to more negative values, whereas an electron withdrawing substituent has the opposite effect. A linear relationship exists between the number of substituted sites and the reduction potential of the cluster.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19971300819
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  • 5
    Electronic Resource
    Electronic Resource
    Synthese, Eigenschaften und NMR-spektroskopisch Untersuchung von Phenylthiophosphonsäure-bis(trimethylsilylamid) und 1,3-Bis(trimethylsilyl)-2,4-diphenyl-2, 4-dithioxo-1,3,2λ5,4λ5-diazadiphosphetidinProfessor Lothar Kolditz zum 60. Geburtstage gewidmet (1989)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 576 (1989), S. 54-64 
    Details
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Synthesis, Properties, and N.M.R. Investigation of Phenylphosphonothioic Acid Bis-(trimethylsilylamide) and 1,3-Bis(trimethylsilyl)-2,4-diphenyl-2,4-dithioxo-1,3,2λ5,4λ5-diazadiphosphetidineThe reaction of phenylphosphonothioic dichloride PhP(S)Cl2 (1) with hexamethyl-disilazane (HMDSA) yields N,N′-bis(trimethylsilylamide) of phenylphosphonothioic acid PhP(S)(NHSiMe3)2 (2). The thermolysis of 2 leads to the 1,3-bis(trimethylsilyl)-2,4-diphenyl-2,4-dithioxo-1,3,2λ5, 4λ5-diazadiphosphetidine [PhP(S)NSiMe3]2 (3). The structures of the compounds 2 and trans-3 isolated in high purity habe been elucidated by means of mass, IR-, Raman-, and NMR (1H, 31P, 13C, 29Si) spectra. The first hydrolysis products of both compounds have been proved by NMR spectroscopy. Besides the predominantly formed trans-isomer of 3 the corresponding cis-isomer is obtained with 10% yield.
    Notes: Durch Umsetzung von Phenylthiophosphonsäuredichlorid PhP(S)Cl2 (1) mit Hexamethyldisilazan (HMDSA) wurde das Bis(trimethylsilylamid) dieser Säure PhP(S)(NHSiMe3)2 (2) hergestellt und durch thermische Zersetzung von 2 das 1,3-Bis(trimethyl-silyl)-2,4-diphenyl-2,4-dithioxo-1,3,2λ5,4λ5-diazadiphosphetid [PhP(S)NSiMe3]2 (3) erhalten. Mit Hilfe von Massen-, IR-, Raman- und NMR (1H, 31P, 13C, 29Si)-Spektren wurde die Struktur der in hoher Reinheit isolierten Verbindungen 2 und trans-3 aufgeklärt. NMR-spektroskopisch konnten die ersten Hydrolysestufen beider Verbindungen nachgewiesen werden. Neben dem vorwiegend entstehenden trans-Isomer von 3 wird zu etwa 10% das cis-Isomer gebildet.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19895760108
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  • 6
    Electronic Resource
    Electronic Resource
    Zur Stabilität von Doppelchloriden in den Systemen ACI/PrCl3(A = Na—Cs) (1987)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 555 (1987), S. 143-153 
    Details
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Stability of Double Chlorides in the Systems ACl/PrCl3(A = Na—Cs)The pseudobinary systems ACl/PrCl3(A = Na—Cs) were reinvestigated by means of DTA. The following chlorides were found. (Primary detected compounds are underlined.): \documentclass{article}\pagestyle{empty}\begin{document}$ \underline {{\rm Na}_{\rm 2} {\rm Pr}_{\rm 5} {\rm Cl}_{{\rm 18}} } $\end{document} K3PrCl6; K2PrCl5; \documentclass{article}\pagestyle{empty}\begin{document}$ \underline {{\rm Rb}_{\rm 3} {\rm Pr} {\rm Cl}_{{\rm 6}} } $\end{document} Rb2PrCl5, \documentclass{article}\pagestyle{empty}\begin{document}$ \underline {{\rm Rb} {\rm Pr}_{\rm 2} {\rm Cl}_{{\rm 7}} } $\end{document} Cs3PrCl6, \documentclass{article}\pagestyle{empty}\begin{document}$ \underline {{\rm Cs}_{\rm 3} {\rm Pr} {\rm Cl}_{{\rm 5}} } $\end{document}, CsPr2Cl7.Measurements of the solution enthalpies and of the free (Gibbs) enthalpies of formation from ACl and PrCl3 together with the free enthalpies of synproportionation from the adjacent compounds in the phase diagrams with a galvanic cell for solid electrolytes revealed, that only the chlorides A2PrCl5 are stable at ambient temperature. All other compounds are high temperature forms.The crystal structures of the compounds were determined by X-ray analysis on powders; the compounds are isotypic with the analogous double chlorides of La and Ce. Magnetic susceptibilities in the range from 80 - 300 K were measured with a Gouy-balance.
    Notes: Die pseudobinären Systeme ACl/PrCl3(A = Na—Cs) wurden mittels DTA neu untersucht. Folgende Verbindungen wurden gefunden (erstmalig nachgewiesene Verbindungen sind unterstrichen) \documentclass{article}\pagestyle{empty}\begin{document}$ \underline {{\rm Na}_{\rm 2} {\rm Pr}_{\rm 5} {\rm Cl}_{{\rm 18}} } $\end{document} K3PrCl6; K2PrCl5; \documentclass{article}\pagestyle{empty}\begin{document}$ \underline {{\rm Rb}_{\rm 3} {\rm Pr} {\rm Cl}_{{\rm 6}} } $\end{document} Rb2PrCl5, \documentclass{article}\pagestyle{empty}\begin{document}$ \underline {{\rm Rb} {\rm Pr}_{\rm 2} {\rm Cl}_{{\rm 7}} } $\end{document} Cs3PrCl6, \documentclass{article}\pagestyle{empty}\begin{document}$ \underline {{\rm Cs}_{\rm 3} {\rm Pr} {\rm Cl}_{{\rm 5}} } $\end{document}, CsPr2Cl7. Messungen der Lösungsenthalpien, der freien Enthalpien für die Bildung aus ACl und den PrCl3-reicheren Nachbarverbindungen mittels einer galvanischen Zelle für feste Elektrolyte sowie die Berechnung der freien Enthalpien für die Synproportionierung aus den Nachbarverbindungen im Zustandsdiagramm ergaben, daß nur die Chloride A2PrCl5 bei Raumtemperatur stabil sind; alle anderen sind Hochtemperaturphasen. Strukturuntersuchungen an Kristallpulvern ergaben Isotypie mit den entsprechenden La- und Ce-Verbindungen. Magnetische Suszeptibilitäten nach der Gouy-Methode im Bereich 80 - 300 K zeigen die erwarteten Werte.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19875551215
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  • 7
    Electronic Resource
    Electronic Resource
    Eine Methode zur ldentifizierung von Gitter-Leerstellen in Zeolithen (1988)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 564 (1988), S. 72-80 
    Details
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: A Method for the Identification of T-Atom Vacancies in the Lattices of ZeolitesSilanol groups in the lattices of zeolites can be silylated with trimethylchlorosilane and the products can be characterized by means of 29Si (CP) MAS NMR. T-atom vacancies are indicated by the formation of silylation products with three or four siloxy-linkages under mild reaction conditions as this requires the presence of three or silanol groups in favourable geometrical arrangements.
    Notes: Am Beispiel der Zeolithe ZSM-5 und Y wird gezeigt, wie amn Gitter-Leer-stellen in Zeolithen identifizieren kann. Terminale Hydroxylgruppen, die auch Gitter-Leerstellen umgeben, werden dabei mit Trimethylchlorsilan (TCS) silyliert und die Produkte mit 29Si-(CP)-MAS-NMR untersucht. Die Anwesenheit von Gitter-Leerstellen wird angezeigt durch die Bildung von Silylierungsprodukten mit drei oder vier Siloxybindungen, die Insertion des TCS zwischen drei beziehungsweise vier terminalen Hydroxylgruppen im Zeolithgitter unter sehr milden Reaktions bedingungen entstehen.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19885640109
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  • 8
    Electronic Resource
    Electronic Resource
    Investigations of CsCl, K2SO4, and K2CrO4 as high temperature calibrants for differential scanning calorimetryProfessor Hans-Heinz Emons zum 60. Geburtstage am 1. Juni 1990 gewidmet (1990)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 586 (1990), S. 166-174 
    Details
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Untersuchungen von CsCl, K2SO4 und K2CrO4 als Hochtemperatur-Eichsubstanzen für die Differential Scanning CalorimetrieDie Auswahl von Bezugssubstanzen mit Daten von Standardqualität ist wichtig für sinnvolle Messungen mit der DSC. In der vorliegenden Arbeit werden die Ergebnisse der kritischen Bestimmung der Daten für solche Materialien mitgeteilt. Neue Untersuchungen werden für die drei Salzsysteme CsCl, K2SO4 und K2CrO4 als Standardreferenzsubstanzen für die Hochtemperatur-DSC vorgenommen und mitgeteilt. Die Untersuchungen werden auf Bi und KNO3, zwei voraussichtliche Materialien für Messungen bei niedrigen Temperaturen, ausgedehnt und hier ebenfalls mitgeteilt.
    Notes: The selection of reference materials having calibration quality data sets is essential to meaningful measurements with DSC. In the present work the results of critical evaluations of the data sets for such materials are reported. New studies for three salt systems, CsCl, K2SO4, and K2CrO4 as calibrants for high temperature DSC, were undertaken, and are reported. The studies were extended to include Bi and KNO3, two prospective candidate materials for measurements at lower temperatures, and these results are also reported herewith.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19905860122
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  • 9
    Electronic Resource
    Electronic Resource
    New A0.50A′0.50F3 Ferroelastic Phases with VF3 Structure (A, A′ = Al, Ti, Cr, In, Tl) (1988)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 557 (1988), S. 225-233 
    Details
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Neue ferroelastische A0,50A′0,50F3-Phasen mit VF3-Struktur (A, A′ = Al, Ti, Cr, In, Tl)Ein Phasenübergang wurde in InF3 und mehreren A0,50A′0,50F3-Phasen (A, A′ = Al, Ti, Cr, In, Tl) mittels Mikro-DTA, Mikrocalorimetrie und Röntgen-Diffraktion beobachtet. Die thermische Abhängigkeit der spontanen Verzerrung wurde bestimmt. Dieser Übergang ist von ferroelastischem Prototyp. Die Curie-Temperatur von A0,50A′0,50F3 liegt zwischen den Werten, die früher für die entsprechenden binären Trifluoride mitgeteilt wurden.
    Notes: A phase transition has been detected in InF3 and in several A0.50A′0.50F3 phases (A, A′ = Al, Ti, Cr, In, Tl) by micro-DTA, microcalorimetry, and X-ray diffraction. The thermal dependence of the spontaneous strain has been determined. This transition is of ferroelastic-prototype nature. The Curie temperature for the A0.50A′0.50F3 composition is intermediate to those previously reported for the related binary trifluorides.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19885570124
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  • 10
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    Electronic Resource
    Electrochemical synthesis of metal complexes of schiff bases: The crystal structure of bis{2-[(4-methylphenyl)iminomethyl]pyrrolato}copper(II) (1992)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 615 (1992), S. 155-160 
    Details
    ISSN: 0044-2313
    Keywords: Electrochemical synthesis ; Schiff bases metal complexes ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Elektrochemische Synthese von Metall(II)-Komplexen mit Schiffschen Basen: Kristallstruktur von Bis{2-[(4-methylphenyl)iminomethyl]pyrrolato}kupfer(II)Die elektrochemische Oxidation von anodischem Metall (Nickel, Kupfer, Zink, Cadmium) in einer Acetonitril-Lösung mit einer aus H-pyrrol-2-carbaldehyd abgeleiteten Schiffschen Base eines substitutierten Anilins (HL) liefert die gemischten Komplexe ML2. Die Kristallstruktur von Bis{2-[(4-methylphenyl)iminomethyl]pyrrolato}kupfer(II) wurde röntgenographisch bestimmt. Der Komplex kristallisiert monoklin in der Raumgruppe P21/n, a = 9,356(2), b = 16,697(2), c = 14,145(2) A, β = 108,47(2)°, Z = 4, und er besteht aus monomeren Molekülen, von denen die zentrale CuN4-Einheit eine verzerrt-tetraedrische Geometrie besitzt mit einem Diederwinkel der Flächen von 25,8(3)°. Die IR, 1H-NMR und UV-VIS Spektren werden im Zusammenhang mit der Struktur diskutiert.
    Notes: The electrochemical oxidation of anodic nickel, copper, zinc or cadmium in acetonitrile solutions of Schiff bases (HL) derived from H-pyrrole-2-carbaldehyde and substituted anilines gives compounds of general formula ML2. The crystal structure of bis{2-[(4-methylphenyl)iminomethyl]pyrrolato}copper(II) has been determined by X-ray diffraction. The compound crystallizes in the monoclinic space group P21/n with a = 9.356(2), b = 16.697(2), c = 14.145(2) Å and β = 108.47(2)°. The crystal structure consists of monomeric molecules in which the central CuN4 unit has distorted square-planar geometry with a dihedral angle of 25.8(3)° between the coordination planes. The IR, 1H NMR and UV-visible spectra of the complexes are discussed and related to the structure.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19926150931
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