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  • 1
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Highly split, visible light emissions at room temperature were observed in the range from 335 to 650 nm in silicon-rich oxide films deposited in the plasma phase of a mixture of silane and oxygen. The mechanism of the light emissions is classified into two categories. The photoluminescence bands at both 365 and 469 nm are related to the intrinsic defects of the E′ center and the neutral oxygen vacancy, respectively. However, the relatively sharp peaks at 403 and 535 nm are correlated with the development of polycrystalline core of Si-enriched parts. © 1996 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Journal of Chromatography A 641 (1993), S. 319-327 
    ISSN: 0021-9673
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    s.l. ; Stafa-Zurich, Switzerland
    Key engineering materials Vol. 257-258 (Feb. 2004), p. 383-388 
    ISSN: 1013-9826
    Source: Scientific.Net: Materials Science & Technology / Trans Tech Publications Archiv 1984-2008
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Journal of inclusion phenomena and macrocyclic chemistry 5 (1987), S. 483-490 
    ISSN: 1573-1111
    Keywords: N-hexylammonium ; montmorillonite ; catalytic decomposition reaction ; intercalate ; layer charge
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract It was found that the variation in the thermally evolved gases obtained by decomposition ofn-hexylammonium layered aluminosilicates is mainly due to the difference between octahedral and tetrahedral coordination of aluminium in the lattice and also to the contribution of the excess negative layer charges. ESCA, TG-DSC, GC and MS results indicate that the layer charge originated from the octahedral substitution induces only desintercalation ofn-hexylamine around 250–360°C, whereas that from the tetrahedral substitution induces the catalytic decomposition reaction involving the cleavage of C−N and C−C bonds at 350–450°C with the evolution of ammonia, ethylene, pentene and hexene. It is therefore concluded that the former reaction step is a simple desintercalation, but for the latter one a Brönsted acid catalytic mechanism is proposed.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Springer
    Journal of radioanalytical and nuclear chemistry 227 (1998), S. 75-80 
    ISSN: 1588-2780
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract In order to determine the operating condition of an uranium chlorination process with U3O8-C-Cl2 system, the experimental conditions have been evaluated preliminarily by the thermochemical analysis and experimentally confirmed in this study. The dry-type chlorination of U3O8 occurs as irreversible and exothermic reaction and produces many kinds of chloride compounds such as UCl3, UCl4, UCl5 and UCl6 in the air and humidity controlled argon environment. Taking account of Gibbs free energy and vapor pressure for various chloride compounds, the proper temperature range of chlorination appears to be 863 to 953 K in aspects of increasing reaction rate and the yield of nonvolatile product. In the course of the experimental confirmation the powder of U3O8 is perfectly converted into uranium chlorides within 4 hours above 863K, and then the maximum fraction of uranium chloride remaining in the reactor is about 30% of total conversion mass.
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  • 6
    Electronic Resource
    Electronic Resource
    Springer
    Journal of radioanalytical and nuclear chemistry 209 (1996), S. 217-223 
    ISSN: 1588-2780
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract A study on the precipitation of uranium by oxalic acid was carried out in a multicomponent solution. The precipitation method is usually applied to the treatment of radioactive waste and the recovery of uranium from a uranium-scrap contaminated with impurities. In these cases, the problem is how to increase the precipitation yield of target element and to prevent impurities from coprecipitation. The multicomponent solution in the present experiment was prepared by dissolving U, Nd, Cs and Sr in nitric acid. The effects of concentrations of oxalic acid and ascorbic acid on the precipitation yield and purity of uranium were observed. As results of the study, the maximum precipitation yield of uranium is revealed to be about 96.5% and the relative precipitation ratio of Nd, Cs and Sr versus uranium are discussed at the condition of the maximum precipitation yield of uranium, respectively.
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  • 7
    Electronic Resource
    Electronic Resource
    Springer
    Journal of radioanalytical and nuclear chemistry 209 (1996), S. 113-122 
    ISSN: 1588-2780
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract In order to obtain the exact information of atomic number density in UO2(NO3)2 · 6H2O−HNO3−H2O ternary mixture, the theoretical estimation of excess volume which is one of excess properties of non-ideal solution is discussed in this study. The calculation model based on the Stokes-Robinson application of the Brunauer-Emmett-Teller (BET) adsorption isotherm and activity equations of water nitric acid, and uranyl nitrate hexahydrate (UNH) which were used to calculate distribution coefficients in a solvent extraction system has one adjustable parameter and two BET constants. The BET constants have been determined by asymptotic method on the BET adsorption isotherm as a function of water activity in the ternary system. As results of the study, the observed volume of mixture agrees with the volume predicted by the simulation within a maximum relative deviation of 0.78% and the excess volume is also estimated as a function of total molality.
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  • 8
    Electronic Resource
    Electronic Resource
    Springer
    Journal of radioanalytical and nuclear chemistry 243 (2000), S. 639-643 
    ISSN: 1588-2780
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract In order to determine the operating conditions of an electrolyzer to recover lithium metal from molten salt wastes composed of LiCl, Li2O, Cs2O, and SrO, electrolytic reduction experiments have been carried out in a single compartment electrochemical reactor with a mono-polar connection. All the combinative experiments were conducted in an argon atmospheric glove box, and each applied potential-current value was synchronously measured and analyzed in aspects of the preferentially recovering probability of lithium in mixed phases. The effect of the electrode surface area on the current was also observed. Based on our experimental results compared with electrochemical thermodynamic evaluation, it is revealed that Li2O can be preferentially reduced to lithium by controlled LiCl concentration and applied potential.
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  • 9
    Electronic Resource
    Electronic Resource
    Springer
    Journal of radioanalytical and nuclear chemistry 240 (1999), S. 815-821 
    ISSN: 1588-2780
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract In order to determine the operating conditions of an uranium reduction process with U3O8-Li-LiCl system, the operating conditions have been evaluated in thermodynamic aspects and the results were experimentally confirmed in this study. All the reduction experiments were conducted in an argon atmospheric glove box, and the resultant degree of reduction was determined by analyzing the product using XRD and TGA. In the results of this study, a reduction yield greater than 95% is achieved within about 3 hours of reaction. The effects of the added quantity of Li and LiCl to the reduction yield of U3O8 and the preferential removal of several metal oxides accompanying U3O8 in the course of reduction were discussed. For a greater reduction of U3O8, an additional 20% of Li is required when compared to the stoichiometric composition. The proper composition of LiCl is about 75% based on the weight of U3O8 charged.
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  • 10
    ISSN: 0044-2313
    Keywords: Mixed-valence copper(II,III) oxide ; solid solutions ; semiconducting behavior ; electronic structure ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Präparation sowie elektrische und magnetische Eigenschaften der festen Lösungen Sr2-xNaxCuO3 (0 ≤ x ≤ 1)Die festen Lösungen Sr2-xNaxCuO3 (0 ≤ x ≤ 1) mit Kupfer(II,III)-oxid wurden durch Feststoffreaktionen in Sauerstoffatmosphäre dargestellt. Alle diese festen Lösungen haben die Struktur von Sr2CuO3 (Raumgruppe Immm). Elektrische Leitfähigkeits- und EMK-Messungen zeigen Halbleiterverhalten im gesamten Bereich der Zusammensetzung. Die Elektronenstruktur des Sr2CuO3 wird mit der des La2CuO4 auf Basis eines ionisch-kovalenten Modells verglichen. Die Interpretation des Transportverhaltens deutet auf kleine Polaronen. Magnetische Suszeptibilitäts- und EPR-Messungen zeigen, daß die antiferromagnetische Ordnung des Sr2CuO3 abnimmt mit zunehmendem x. Die magnetischen Wechselwirkungen sind jedoch noch stark bei einer Kupferionen- Konzentration von x = 0,8.
    Notes: Mixed-valence copper(II/III) oxide solid solutions Sr2-xNaxCuO3 (0 ≤ x ≤ 1) have been prepared by solid-state reactions in oxygen atmosphere. All solid solutions exhibit the structure of Sr2CuO3 (S.G. Immm). Electrical conductivity and thermoelectric power measurements show a semiconducting behavior in the whole composition range. The electronic structure of Sr2CuO3 is compared with that of La2CuO4 on the basis of an iono-covalent model. Interpretation of transport properties suggests the formation of small polarons. Magnetic susceptibility and EPR measurements show that the antiferromagnetic ordering of Sr2CuO3 tends to vanish as x increases, however magnetic interactions are still strong for a concentration of Cu2+ ions corresponding to x = 0.8.
    Additional Material: 10 Ill.
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