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  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 36 (1990), S. 797-800 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 43 (1997), S. 1947-1954 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Recent experimental validation of theoretical and numerical predictions regarding scalar variance decay in a pipe have revealed that the traditional plug-flow reactor picture of pipe flow omits key physical mechanisms. In particular, the far-field decay exhibits a power law rather than exponential decay. These observations are examined by performing a set of experiments where the manner in which the scalar constituents are introduced into the pipe is varied. Significant differences are noted in the behavior of the variance decay until the very far field is reached, where an invariant power-law form emerges.
    Additional Material: 14 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 38 (1992), S. 723-732 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Pressure relief venting of a runway reaction with gas generation is examined in terms of the overall system response and the associated venting requirement. This article presents an exact formulation as well as an approximate analytical approach. The latter is shown to be particularly useful in vent-sizing applications. Using an aqueous hydrogen peroxide decomposition example, the analytical results are demonstrated to agree well with the exact numerical results over a wide range of overpressure. In addition, the analytical result is shown to reduce to the correct limit for a pure vapor system and offers a useful vent-sizing equation for a pure-gassy system.
    Additional Material: 9 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 166-177 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A membrane-assisted solvent extraction (MASX) system coupled to a membrane-assisted distillation stripping (MADS) system for use in decontaminating ground-water is evaluated. Volatile organic compounds (VOCs) in the groundwater are extracted in the MASX unit using a sunflower oil solvent. In the MADS unit, VOCs are stripped from the sunflower oil, which is recycled to the MASX unit. Thermodynamic data for the sunflower oil-water-VOCs system were measured. The results were used along with published membrane mass-transfer data to design MASX and MADS modules.
    Additional Material: 8 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 35 (1989), S. 1527-1534 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The mass transfer analysis of the oxygen transfer performance of diffused air or subsurface mechanical aeration systems has progressed very little over the past 20 years. The recently-developed ASCE Standard method for determination of the oxygen mass transfer performance of diffused or subsurface aeration systems is based on a greatly over-simplified mass transfer model. Although the ASCE Standard can be used to empirically evaluate point performance conditions, it does not provide a meaningful representation of the actual mass transfer process and is not capable of accurately assessing or predicting performance under changing operating or environmental conditions. A new oxygen mass transfer model has been developed which is a fundamentally more rigorous description of the actual mass transfer process in diffused aeration systems. This model can be confidently used to predict aerator performance under changing operating and environmental conditions. The model is easily adapted to numerical computer solution for routine aeration systems performance evaluation as well as process design.
    Additional Material: 4 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 1 (1955), S. 20-27 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A study was made of the mutual solubility of ethylene with various polar and nonpolar relatively high-molecular-weight organic compounds at temperatures 1° and 10° C. respectively above the critical temperature of ethylene and at pressures up to 1,500 Ib./sq.in.abs. For many compounds Henry's law was found to be applicable for the liquid phase up to approximately two thirds of the critical pressure of ethylene. In the critical region the solubility of ethylene was extremely sensitive to small changes in both temperature and pressure. The various types of phase behavior encountered were classified according to the nonideality involved. The results of this investigation indicate that a gas near its critical conditions is often capable of dissolving relatively nonvolatile materials in sufficient concentrations to warrant consideration of a separation process using such a gas as the extracting medium, namely fluid-liquid extraction.
    Additional Material: 22 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 24 (1978), S. 1000-1010 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Correlations producing thermodynamic property tables employ the concepts of scaling with increasing frequency in the vapor-liquid critical region. One of the important concepts is that the vapor pressure equation should provide infinite curvature and finite slope ψc at the critical point. The vapor pressure critical exponent θ describes the divergent curvature in a power law expression.This paper provides an extensive study of θ. We have determined an optimal value of θ by two general approaches: a curve fit method (CFM) which employs least-squares analyses, and a numerical derivative method (NDM). The CFM is interpolative but requires a vapor pressure equation, while the NDM is extrapolative but is independent of the vapor pressure equation.The vapor pressure equations, which satisfy scaling concepts most closely, exhibit a very flat minima for the CFM. As a result, the values of θ which provide reasonable correlations vary over an appreciable range (depending upon the compound, form of the equation, and the temperature range). The NDM did not present any particular difficulties. Our overall weighted average for θ is 0.199 with a standard deviation of 0.052, while the overall numerical average was 0.225 with a standard deviation of 0.045; the final recommended value of θ is 0.22 ± 0.04.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Process Safety Progress 12 (1993), S. 83-91 
    ISSN: 1066-8527
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Of all the analytical tools available to the process safety professional, perhaps the most critical are those used to identify and analyze process hazards. Such tools have been collectively referred to as “Hazard Evaluation Procedures” by the Center for Chemical Process Safety (CCPS) and as techniques for “Process Hazard Analysis” (PHA) by the Occupational, Safety and Health Administration (OSHA).One of the best known PHA tools, the Hazard and Operability or HAZOP study, emerged over two decades ago in ICI, U.K., and its use has since spread over six continents. In 1979, ARCO Chemical piloted its first HAZOP and since then, HAZOPs have become the backbone of the company's Process Hazards Review procedure.Repeated use of the HAZOP technique since 1979 has resulted in an affirmation that to be “successful”, much more was needed than simply executing the HAZOP technique. Success is dependent upon the preparation and planning effort that precedes the HAZOP, and the follow-up activity that ensures implementation of study findings. Unlike the study technique, little information was available in 1979 on how to design the framework, or management system, that was needed to support the use of this tool.The purpose of this paper is shift focus from executing the HAZOP technique to that framework, by presenting insights that have accumulated from using the technique in ARCO Chemical, especially during the period 1979 through 1986. These were the formative years, during which the company's advancement on the learning curve was most noticeable. These were the years that convinced the company that successful HAZOP studies do not just happen; success comes from building the right management system. Success must be defined and assured at each step in a Process Hazards Review procedure, of which executing the HAZOP technique is only one.
    Additional Material: 7 Tab.
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  • 9
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Process Safety Progress 15 (1996), S. 66-73 
    ISSN: 1066-8527
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Pressure relief sizing for refrigeration equipment is considered in this paper. In particular the ASHRAE fire sizing formula [2] is critically examined and comparisons are made with methods employed in other engineering institutes. The traditional sizing approach based on vapor relief is re-exmained in light of the recent findings from the DIERS (Design Institute for Emergency Relief Systems) work [11]. The occurrence of two-phase discharges during relief may result in significant overpresurization of the refrigeration equipment. The purpose of this paper is to suggest a methodology adequate for most designs and which has been verified with available experimental data.
    Additional Material: 6 Ill.
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  • 10
    ISSN: 0044-8249
    Keywords: Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 2 Ill.
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