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  • 1
    Electronic Resource
    Electronic Resource
    Radical initiated homo- and copolymerization of N,N,N′N′-tetra(2-hydroxypropyl)ethylene diamine methacrylate (1990)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 28 (1990), S. 949-953 
    Details
    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pola.1990.080280421
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  • 2
    Electronic Resource
    Electronic Resource
    Alkyl cyanoacrylates as space filling bone adhesives (1992)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Biomaterials 3 (1992), S. 207-210 
    Details
    ISSN: 1045-4861
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine , Technology
    Notes: Higher chained alkyl cyanoacrylates have potential to function efficiently as space filling, hydrophobic, viscoelastic, biocompatible, and rapidly polymerizing bone adhesives. Hence they may be useful in applications where a void has to be filled, such as replacement of the intervertebral disc. To assess their applicability as space filling material in such an pplication, three alkyl cyanoacrylates; methoxyethyl cyanoacrylate, isobutyl cyanoacrylate, and isoamyl cyanoacrylate have been evaluated in this study. The bonding strength of these cyanoacrylates to bone in a space filling situation have been measured. The results indicate the bond strength of isoamyl cyanoacrylate (0.13 MPa) to be significantly (p 〈 0.05) lower compared with methoxyethyl cyanoacrylate (0.33 MPa) and isobutyl cyanoacrylate (0.37 MPa). There was no significant difference in the bond strengths of isobutyl cyanoacrylate and methoxyethyl cyanoacrylate.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/jab.770030307
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  • 3
    Electronic Resource
    Electronic Resource
    Graft copolymerization of collagen with N, N, N′, N′-tetra (2-hydroxypropyl) ethylene diamine methacrylate by use of potassium persulfate as an initiator (1990)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 40 (1990), S. 1541-1545 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Graft copolymerization of collagen with N,N,N′,N′-tetra (2-hydroxypropyl) ethylene diamine methacrylate (THPEDM) was carried out in an aqueous medium using potassium persulfate as the radical initiator. Collagen-g-poly(THPEDM) was characterized by the percent yield and the copper chloride test. The percentage of grafting was determined as functions of concentration of monomer, concentration initiator, reaction time, and temperature.
    Additional Material: 3 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1990.070400911
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  • 4
    Electronic Resource
    Electronic Resource
    The use of analytic surfaces for the design of centrifugal impellers by computer graphicsThis paper is Crown copyright and is reproduced with the permission of the Controller, Her Majesty's Stationery Office. (1973)
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 7 (1973), S. 137-154 
    Details
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: This paper shows how analytic surfaces can be used to define the vanes of an impeller of a centrifugal compressor. The analysis has been given of a cubic-linear patch for representing three-dimensional geometries. An example has shown how this type of patch can be successfully used to model the geometry of centrifugal or mixed flow impellers having 'swept back vanes at the outlet.The analysis has been programmed for the Atlas computer at the Computer Aided Design Centre (CADC), Cambridge and set up in such a way that the designer can examine systematically a range of impeller shapes.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/nme.1620070205
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  • 5
    Electronic Resource
    Electronic Resource
    The crystal structure of polycaproamide: Nylon 6 (1955)
    Hoboken, NJ : Wiley-Blackwell
    Journal of Polymer Science 17 (1955), S. 159-177 
    Details
    ISSN: 0022-3832
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The crystal structure of nylon 6 (—NH (CH2)5CO—)p has been determined by interpretation of the x-ray diffraction patterns given by drawn, rolled fibers. The determination was part of a program to investigate the relation between structure and physical properties, in particular melting point. Nylon 6 melts 50°C. lower than its isomer nylon 66 (—NH (CH2)6NH·CO (CH2)4CO—)p; it had been suggested that this was due to deficient hydrogen-bond formation in nylon 6 crystallites. The unit cell contains eight chemical units (—NH (CH2)5CO—) and is monoclinic with a = 9.56 A., b = 17.24 A., c = 8.01 A., and β = 671/2°. Calculated density = 1.23. Observed density for a drawn monofilament = 1.16. The structure consists of planar chains of CH2 groups and amide groups tilted 7° from the (001) plane. Alternate chains in this plane are oppositely directed, an arrangement which allows all hydrogen bonds to be made perfectly. The hydrogen-bonded sheets of atoms are packed in an “up-and-down” staggered configuration along the c-axis. Distances between atoms in neighboring molecules are all normal van der Waals contact distances. It appears, from a general survey of polyamide melting points published elsewhere, that the determining factor is the number of CH2 groups between the amide “anchor points” - polymers with odd numbers of CH2 groups melt lower than those with even numbers. The present work shows that the odd number of CH2 groups in this polymer does not lead to deficient hydrogenbond formation, and that the lower melting point of nylon 6 as compared with nylon 66 must be ascribed to some other cause, possibly connected with the propagation of vibrations along odd-numbered chain segments.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1955.120178401
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  • 6
    Electronic Resource
    Electronic Resource
    Complete 1H and 13C assignments of ractopamine hydrochloride using 2D and selective 1D NMR methods (1993)
    Chichester : Wiley-Blackwell
    Organic Magnetic Resonance 31 (1993), S. 283-286 
    Details
    ISSN: 0749-1581
    Keywords: Ractopamine ; Long-range selective proton decoupling ; NMR assignments ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The 1H and 13C NMR resonances for ractopamine hydrochloride have been assigned. H,H-COSY and H,C-COSY were used to assign the aliphatic moiety of the molecule and to correlate protons and carbons on the same ring system. Long-range selective proton decoupling (LSPD) experiments were used to assign quaternary carbons and to distinguish the two ring systems.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/mrc.1260310314
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  • 7
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    Latest Pleistocene and Holocene behaviour of Franklin Glacier, Mt. Waddington area, British Columbia Coast Mountains, Canada (2015)
    Sage
    In: Holocene
    Details
    Publication Date: 2015-04-09
    Description: Franklin Glacier is an 18-km-long valley glacier that originates in a broad icefield below the west face of Mt. Waddington in the central British Columbia Coast Mountains, Canada. Radiocarbon-dated wood samples from the proximal faces of lateral moraines flanking Franklin Glacier show that the glacier expanded at least nine times since 13,000 cal. yr BP. A probable Younger Dryas advance of Franklin Glacier at 12,910–12,690 cal. yr BP followed the late glacial retreat and down wasting of the Cordilleran Ice Sheet from ca. 16,000 to 12,900 cal. yr BP. During the succeeding early Holocene warm period, Franklin Glacier appears to have retreated significantly, leaving no record of glacial expansion until the mid-Holocene when it repeatedly advanced at 6360–6280, 5470–5280 and 4770–4580 cal. yr BP. Down wasting of the glacier surface after ca. 4770–4580 cal. yr BP was followed by intervals of expansion at 4260–4080, 3210–3020 and 2620–2380 cal. yr BP. Following ice expansion at ca. 2620–2380 cal. yr BP into trees over 224 years in age, there is no record of the glacier activity until 1570–1480 cal. yr BP when Franklin Glacier thickened and advanced into young subalpine fir trees. During the ‘Little Ice Age’, advances at 800–680, 610–560 and 570–510 cal. yr BP preceded a mid-19th to early 20th century advance that saw Franklin Glacier attain its maximum Holocene extent. The dendroglaciological record at Franklin Glacier is among the most comprehensive recovered from the British Columbia Coast Mountains and showcases the complexity of mid- to late Holocene glacier expansion in the region.
    Print ISSN: 0959-6836
    Electronic ISSN: 1477-0911
    Topics: Geography , Geosciences
    Published by Sage
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  • 8
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    Mid-Holocene glacier expansion between 7500 and 4000 cal. yr BP in the British Columbia Coast Mountains, Canada (2012)
    Sage
    In: Holocene
    Details
    Publication Date: 2012-08-21
    Description: The mid-Holocene behaviour of five glaciers in the British Columbia Coast Mountains was reconstructed from radiocarbon ages and stratigraphic analysis. Subfossil wood evidence at Canoe, Fyles, Jacobsen, Tchaikazan and Icemaker glaciers suggests these glaciers were expanding into standing forests prior to 6630, 4900 and 4200 cal. yr BP. Stratigraphically constrained woody detritus at Fyles Glacier records the progradational history of a Gilbert-type delta forming in response to glacial expansion between 7020 and 5470 cal. yr BP. This research provides the first evidence for mid-Holocene glacial expansion in the central and northern British Columbia Coast Mountains. Proxy records describing mid-Holocene climates in the British Columbia Coast Mountains indicate a trend towards slightly cooler and possibly wetter conditions than present. Glacial expansion occurring between 7500 and 4000 cal. yr BP has regional correlatives, suggesting coherent broad-scale climate forcing mechanisms influenced glacial mass balance at this time.
    Print ISSN: 0959-6836
    Electronic ISSN: 1477-0911
    Topics: Geography , Geosciences
    Published by Sage
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  • 9
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    Dendroglaciological reconstruction of late-Holocene glacier activity at White and South Flat glaciers, Boundary Range, northern British Columbia Coast Mountains, Canada (2012)
    Sage
    In: Holocene
    Details
    Publication Date: 2012-08-21
    Description: Holocene glacier activity in the northern British Columbia Coast Mountains, Canada, is described following investigations in the recently deglaciated forefields of White and South Flat glaciers spilling from the Cambria Icefield. Glacially overridden stumps and detrital wood was radiocarbon and dendrochronologically dated to describe an advance between ad 250 and 650. Expansion and thickening of White Glacier by ad 765 resulted in creation of an ice-dammed lake in South Flat valley that persisted until ad 1080. Following this the lake drained, before refilling in the early ‘Little Ice Age’ prior to ad 1300. Shortly thereafter White and South Flat glaciers became confluent and flowed over the valley side toward White Lake. The characteristics of the site and the preservation of 1500 yr old deposits indicate that the two glaciers remained confluent throughout the remainder of the ‘Little Ice Age’, only separating following terminal retreat early in the 20th century. The late-Holocene glacial history of White and South Flat glaciers appears synchronous with those of other glaciers in northern portion of Pacific Northwest.
    Print ISSN: 0959-6836
    Electronic ISSN: 1477-0911
    Topics: Geography , Geosciences
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  • 10
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    Dendroglaciological investigations of mid- to late-Holocene glacial activity in the Mt. Waddington area, British Columbia Coast Mountains, Canada (2012)
    Sage
    In: Holocene
    Details
    Publication Date: 2012-12-21
    Description: Dendroglaciological investigations near Mt. Waddington in the central British Columbia Coast Mountains provide an enhanced perspective of Holocene glacial activity. Field investigations at Confederation, Franklin, and Jambeau glaciers led to the discovery of subfossil wood mats encased in glacial deposits and glacially sheared stumps buried beneath till. Radiocarbon-dated wood collected from valley-bottom and lateral moraine sites at Confederation Glacier suggest that an early-Holocene advance occurred at c . 5665 cal. yr BP, followed by succeeding intervals of glacier expansion at c . 3700 and 3500 cal. yr BP. At Jambeau Glacier detrital wood mats buried close to the contemporary lateral moraine crests document glacier expansion at c . 3000 cal. yr BP. Detrital subfossil wood buried in lateral moraines at the confluence of Confederation and Franklin glaciers records distinct episodes of ‘Little Ice Age’ glacier expansion as early as c . 1212 cal. yr ad , and suggests the glacier surface continued to thicken until at least c . 1330–1410 cal. yr ad. An interval of downwasting and retreat followed, before late ‘Little Ice Age’ advances such as those at Jambeau Glacier were overwhelming valley-bottom forests by c . 1740 cal. yr ad. With the exception of the previously unrecognized advance of Confederation Glacier at c . 3700 cal. yr BP, our dendroglaciological findings corroborate the emerging record of Holocene glacier activity in the British Columbia Coast Mountains.
    Print ISSN: 0959-6836
    Electronic ISSN: 1477-0911
    Topics: Geography , Geosciences
    Published by Sage
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