ALBERT

All Library Books, journals and Electronic Records Telegrafenberg

feed icon rss

Your email was sent successfully. Check your inbox.

An error occurred while sending the email. Please try again.

Proceed reservation?

Export
  • 1
    Electronic Resource
    Electronic Resource
    [s.l.] : Nature Publishing Group
    Nature 171 (1953), S. 1104-1106 
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] THE structure of polythene film has been investi-X gated by X-ray, optical and polarized infra-red methods. It was found that the polymer chains are oriented differently in the crystalline and the amorphous regions, the respective chain axes being perpendicular to each other. We are unaware of any ...
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 2
    Electronic Resource
    Electronic Resource
    [s.l.] : Nature Publishing Group
    Nature 195 (1962), S. 170-171 
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] (1) Carbon powder of 99-5 per cent purity and mean particle size of 400 A. was incorporated into a commercial feldspathic glaze normally used for covering high-tension insulators. When carbon/glaze mixtures were fired in dry nitrogen or argon, 50-75 per cent of the carbon was lost due to oxidation ...
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 3
    Electronic Resource
    Electronic Resource
    Copenhagen : International Union of Crystallography (IUCr)
    Acta crystallographica 6 (1953), S. 256-259 
    ISSN: 0001-5520
    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
    Topics: Geosciences
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 4
    Electronic Resource
    Electronic Resource
    Copenhagen : International Union of Crystallography (IUCr)
    Acta crystallographica 6 (1953), S. 301-302 
    ISSN: 0001-5520
    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
    Topics: Geosciences
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 5
    Electronic Resource
    Electronic Resource
    [s.l.] : Nature Publishing Group
    Nature 216 (1967), S. 54-56 
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] The tentative explanation1 put forward to explain the small increases in oxidation rates at the higher chromium contents was an extension of a suggestion by Mortimer and Menzies3. The scales on the alloys rich in chromium are thought to consist of nearly pure chromic oxide, while the films formed ...
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 6
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 23 (1972), S. 741-747 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Eindrücke und Schlußfolgerungen der Tagung „Mechanische Eigenschaften und Haftung von Zunderschichten und ihr Einfluß auf die Oxydation von Metallen“Zusammenfassende Übersicht der auf der Tagung gebrachten Vorträge und Diskussionen. Zu den behandelten The- men gehörten die verschiedenen Möglichkeiten der Verformung von wachsenden Oxidschichten zum Ausgleich der Wachstumsspannungen. Die plastische Verformung kann nach verschiedenen Mechanismen erfolgen: Versetzungsgleitung, Versetzungssteigung, spannungsunterstütztes Diffusionskriechen nach Herring-Nabarro, Korngrenzengleitung, mechanische Zwillingsbildung und viskoses Fließen amorpher Oxide. Die Verformung ist abhängig von der Konfiguration des Zunders und dem einwirkenden Spannungssystem; viele Oxidsysteme sind bei hohen Temperaturen ziemlich plastisch, doch spielen Poren, Einschlüsse anderer Phasen u. ä. ebenfalls eine wichtige Rolle. Nach übereinstimmender Ansicht gibt es starke Beweise für eine gewisse plastische Verformung in wachsenden Zunderschichten, wobei bei hohen Temperaturen diffusionskontrolliertes Kriechen in Verbindung mit Korngrenzengleitung bevorzugt sein dürfte. Zu den die Haftung des Zunders beeinflussenden Faktoren gehören elektrostatische Kräfte an der Grenzfläche Metall/Oxid, Unregelmäßigkeiten in der Grenzfläche, Spannung/Dehnung-Wechselwirkungen zwischen Oxid und Metall, Spannungrelaxationen in Metall und Oxid sowie das Vorliegen von Kerbstellen wie Leerräume, Einschlüsse und Poren an der Grenzfläche Metall/Oxid. Die Notwendigkeit der Entwicklung neuer Meßmethoden wird ebenfalls aufgezeigt.
    Notes: Review of the papers presented to the Conference and of discussions. The topics dealt with included the various ways in which growing oxide scales can deform to accommodate their growth stresses. According to that plastic deformation occurs by the following mechanisms: dislocation glide, dislocation climb, Herring-Nabarro stress-assisted diffusion creep, grain-boundary sliding, mechanical twinning and viscous flow of amorphous oxides. The deformation depends on the scale configuration and the stress system; many oxide systems are rather plastic at high temperatures, but pores, defect doping elements and second phase inclusions play important parts, too. It is generally accepted that the evidence for some plastic deformation in growing oxide scales is very strong, the most favoured mechanism at high temperatures being diffusion controlled creep associated with grain boundary sliding. Factors influencing adhesion of scales include electrostatic forces at the metalloxide interface, interface irregularities, stress/strain interactions between oxide and metal, stress relaxation in metal and oxide, and the presence of stress raisers such as voids, second phase particles and pores at the metal/oxide interface. The necessity of developing new measuring methods is pointed out, too.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 7
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Wechselwirkungen Dehnung/Oxidation in Stählen und ModellegierungenDie Spannungen, die in Oxidfilmen auf zahlreichen für die Energieerzeugung wichtigen Werkstoffen entstehen, werden in Verbindung mit den jeweiligen Betriebs-bedingungen erörtert. Zu den betrachteten Themen gehören das Wachsen von Brennelementhülsen, das Abplatzen von Oxiden, die Bildung von mehrschichtigen Oxiden während der Innenkorrosion von Kesseln und er Sprödbruch von nicht-rostenden austenitischen Stählen. Die bei thermischer Wechselbeanspruchung entstehenden Spannungen werden eingehend betrachtet und die zur Rißbildung im film erforderlichen Temperaturänderungen erörtert und mit dem beobachteten Abplatzverhalten verglichen.
    Notes: Strain/oxidation interactions in steels and model alloys The strains generated in oxide films on a number of materials of interest to the power generation industry are considered in relation to their operating conditions. Topics discussed the growth of nuclear canning alloys, oxide spalling, the formation of multilayer oxides during internal boiler corrosion and low ductility failures in austenitic stainless steels. The strains induced during thermal cycling are considered in detail and the temperature changes required to cause film craking are estimated and compared with observed spalling behaviour.
    Additional Material: 15 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 8
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 21 (1970), S. 917-924 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Transporteigenschaften und Defektstruktur des auf FeCr-Legierungen entstehenden Oxids (Fe, Cr2)O3Die Schutzeigenschaften einer auf einem Metall entstehenden Zunderschicht sind eng verbunden mit der Art des Stofftransports durch das Oxid. In der vorliegenden Arbeit wird das Oxydations- verhalten der binären FeCr-Legierungen behandelt, welche die Grundlage zahlreicher technisch wichtiger Werkstoffe sind; gleichzeitig wird versucht, eine Beziehung zwischen Oxydationsverhalten einerseits und Defektstruktur und Transporteigenschaften der Oxide vom Typ (Fe, Cr)2O3, andererseits herzustellen. Die über dieses System vorhandenen Informationen be- schränken sich im wesentlichen auf die Endprodukte, nämlich Cr2O3 und Fe2O3. Das Chromoxid ist ein Oxid vom p-Typ rnit Kationenunterschuß, so daß der Kationentransport überwiegt. Das Eisenoxid hingegen ist ein Oxid vom n-Typ und enthält wahrscheinlich Eisen auf Zwischengitterplätzen sowie Sauerstoffleerstellen; die Transportgeschwindigkeiten für diese beiden Spezies sind vergleichbar, doch die Defektstruktur und die Eigenschaften der beiden Oxide sind bisher nur teilweise bekannt. Neue Messungen unter Verwendung von thermogravimetrischen, elektrischen und Hochtemperatur-Verformungstechniken zur Ermittlung der genannten Eigenschaften werden kurz beschrieben.Elektrische Messungen stützen die Hypothese, wonach bestimmte feste Lösungen von Cr2O3-Fe2O3 durch niedrigere Defektkonzentrationen und niedrigere Ionentransportgeschwindigkeiten als die reinen Oxide gekennzeichnet sind. Es gibt Anzeichen dafür, daß die auf einer binären Legierung mit etwa 20% Chrom entstehenden Zunderschichten etwa die Zusammensetzung haben, welche für niedrige Oxydationsgeschwindigkeiten erforderlich ist. Kurz eingegangen wird auf die mögliche Erweiterung der Theorie für die Bildung won stöchiometrisch zusammengesetzten Zunderschichten zum Schutz won ternären und noch komplexeren Legierungen.
    Notes: The protective properties of a scale forming on a metal are intimately relat-ed to the way in which matter is transported through the oxide. This report re-views the oxidation behaviour the bi-nary iron-chromium alloys which form the basis of many technologically important materials and attempts to relate it to the defect structure and transport properties of (Fe, Cr)2O3 oxides. Existing information on this system is mainly restricted to the end members, Cr2O3 and Fe2O3. The former is a cation deficient, p-type oxide and cation transport dominates. Fe2O3 is n-type, probably containing iron interstitials and oxygen vacancies, with comparable transport rates for both species, but the defect structure and properties of both oxides have been only partly characterized. New measurements by thermogravimetric, electrical and high temperature deformation techniques of these properties are briefly described.Electrical measurements support the hypothesis that certain solid solutions of Cr2O3-Fe2O3have lower defect concentrations and ionic transport rates than the pure oxides. There is evidence that scales of about the required composition form on the binary alloy containing about 20% Cr and are responsible for its low oxidation rate. Possible extensions of the theory to the design of highly stoichiometric scales for the protection of tornary and more complex alloys are briefly mentioned.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 9
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    Journal of Polymer Science 17 (1955), S. 159-177 
    ISSN: 0022-3832
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The crystal structure of nylon 6 (—NH (CH2)5CO—)p has been determined by interpretation of the x-ray diffraction patterns given by drawn, rolled fibers. The determination was part of a program to investigate the relation between structure and physical properties, in particular melting point. Nylon 6 melts 50°C. lower than its isomer nylon 66 (—NH (CH2)6NH·CO (CH2)4CO—)p; it had been suggested that this was due to deficient hydrogen-bond formation in nylon 6 crystallites. The unit cell contains eight chemical units (—NH (CH2)5CO—) and is monoclinic with a = 9.56 A., b = 17.24 A., c = 8.01 A., and β = 671/2°. Calculated density = 1.23. Observed density for a drawn monofilament = 1.16. The structure consists of planar chains of CH2 groups and amide groups tilted 7° from the (001) plane. Alternate chains in this plane are oppositely directed, an arrangement which allows all hydrogen bonds to be made perfectly. The hydrogen-bonded sheets of atoms are packed in an “up-and-down” staggered configuration along the c-axis. Distances between atoms in neighboring molecules are all normal van der Waals contact distances. It appears, from a general survey of polyamide melting points published elsewhere, that the determining factor is the number of CH2 groups between the amide “anchor points” - polymers with odd numbers of CH2 groups melt lower than those with even numbers. The present work shows that the odd number of CH2 groups in this polymer does not lead to deficient hydrogenbond formation, and that the lower melting point of nylon 6 as compared with nylon 66 must be ascribed to some other cause, possibly connected with the propagation of vibrations along odd-numbered chain segments.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 10
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    Journal of Polymer Science 42 (1960), S. 274-274 
    ISSN: 0022-3832
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
Close ⊗
This website uses cookies and the analysis tool Matomo. More information can be found here...