ISSN:
0021-8995
Keywords:
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
,
Physics
Notes:
The polymerization of N-vinylcaprolactam in toluene, dioxane, chlorobenzene, dimethylformamide, and ethylene carbonate with various peroxides, perbenzoates and azobisisobutyronitrile as initiators at 60-80°C, was studied. Under these conditions azobisisobutyronitrile and tert-butyl perbenzoate have satisfactory activity as initiators. Under these conditions N-vinylcaprolactam polymerization in homogeneous solution is first order towards the monomer and 0.5 order towards the initiators.
Additional Material:
5 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/app.1969.070130101
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