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  • Springer  (29)
  • 2000-2004  (13)
  • 1990-1994  (9)
  • 1975-1979  (7)
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  • 1
    ISSN: 1572-9028
    Schlagwort(e): hydrogenation of aromatic nitro compounds ; Raney nickel ; vanadium promoter ; modified catalysts ; aryl hydroxylamine ; chloronitrobenzene
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract The effect of vanadium promotion of Raney nickel on aryl hydroxylamine accumulation in the catalytic hydrogenation of electron deficient aromatic nitro compounds was investigated. High accumulation of 70–80% was observed with unmodified Raney nickel. Vanadium promoters were able to modulate the accumulation and depending on the modifier used, an increase (up to 86%) or a decrease (down to 11%) was found. Higher rates were obtained in the former (up to a factor 1.3), lower ones in the latter case (down to a factor 0.1) compared to the unmodified system. Supported or unsupported NH4VO3 was usually the most efficient modifier for obtaining low accumulation and reasonable rates, but the optimum concentration and modification procedure had to be determined for every substrate separately. In cases of low accumulation, the vanadium promoters worked as disproportionation catalysts. Dehalogenation was not significantly influenced by the presence of promoters: in all cases dehalogenation took only place after both the nitro arene and aryl hydroxylamine compound had been consumed completely.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 2
    Digitale Medien
    Digitale Medien
    Springer
    The European physical journal 18 (2000), S. 233-240 
    ISSN: 1434-6036
    Schlagwort(e): PACS. 75.30.Vn Colossal magnetoresistance - 78.70.Dm X-ray absorption spectra - 75.25.+z Spin arrangements in magnetically ordered materials (including neutron and spin-polarized electron studies, synchrotron-source x-ray scattering, etc.)
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract: X-ray absorption spectroscopy (XAS) and soft-X-ray magnetic circular dichroism (SXMCD) at the Mn L2,3-, Cr L2,3- and O-K edges of Sm0.5Ca0.5Mn1-xCrxO3 ( ) bulk polycrystalline samples have been performed at T=20 K below the ferromagnetic Curie temperature. We show the existence of a magnetic sublattice on each of the probed cations. Considering an electronically phase-separated system, results are compared with magnetization and resistivity measurements and a tentative correlation with magnetoresistance properties on such doped compounds is discussed.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 3
    Digitale Medien
    Digitale Medien
    Springer
    Computing 18 (1977), S. 281-293 
    ISSN: 1436-5057
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Informatik
    Beschreibung / Inhaltsverzeichnis: Zusammenfassung Die vorliegende Arbeit analysiert die Erfahrungen, die bei der Durchführung formaler Korrektheitsbeweise an schon exsiterenden Programmen gemacht wurden. Mit Hilfe der Hoareschen Methode der Programmverfikation wurde der von an Emden angegebene Quicksort Algorithmus als richtig bewiesen. Dafür was es jedoch notwendig, eine Reihe von Veränderungen an dem Algorithmus vorzunehmen, um ihn an das Beweisverfahren und die existierenden Axiome anzupassen. Die gegenseitige Einflußnahme der Veränderungen und des Beweisverfahrens werden analysiert und Schlüse über die Verwendbarkeit des Hoareschen Verifikationsverfahrens für existierende Programme werden gezogen.
    Notizen: Abstract Using the Quicksort Algortihm, given by van Emden, an analysis is made how Hoare's method of program verification can be applied to already existing programs. Changes to these programs become necessary to adopt them to the proving method and to the existing axioms. The interdependencies between these changes and the verification method are discussed and conclusions are draw about the applicability of Hoare's Methods for proving already existing programs.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 4
    Digitale Medien
    Digitale Medien
    Springer
    Monatshefte für Chemie 131 (2000), S. 1335-1343 
    ISSN: 1434-4475
    Schlagwort(e): Keywords. Homogeneous catalysis; Enantioselective hydrogenation; Heterocyclic arenes; Rh diphosphine complexes.
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Summary.  The first case of an enantioselective hydrogenation of monosubstituted pyridines and furans with homogeneous rhodium diphosphine catalysts with low but significant enantioselectivities and catalyst activities is reported. Best enantioselectivities (ees of 24–27%) were obtained for the hydrogenation of 2- and 3-pyridine carboxylic acid ethyl ester and 2-furan carboxylic acid with catalysts prepared in situ from [Rh(nbd)2]BF4 and the chiral ligands diop, binap, or ferrocenyl diphosphines of the josiphos type. Turnover numbers (ton) were in the order of 10–20, turnover frequencies (tof) usually 1–2 h−1. Diphosphines giving 6- or 7-ring chelates led to higher ees than 1,2-diphosphines; otherwise, no clear correlation between ligand properties and catalytic performance was found. In some experiments black precipitates were observed at the end of the reaction, indicating the decomposition of the homogeneous catalysts for certain ligand/metal/substrate combinations.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 5
    Digitale Medien
    Digitale Medien
    Springer
    Policy sciences 8 (1977), S. 111-124 
    ISSN: 1573-0891
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Politikwissenschaft , Wirtschaftswissenschaften
    Notizen: Abstract It is argued that “successful” social science requires the development of a social ethic or sense of research responsibility. An examination of impediments to ethical reflection in sociology suggests that an individualistic orientation is ineffective in coping with the unintended consequences of social research. Such consequences can be particularly harmful in the sociology of science where policy research and governmental support for its production often entails an “indiscriminate advocacy of knowledge.” Such advocacy raises anew questions of the power of scientific knowledge, the definition of client-professional relationships, and the collection of data which may not only violate the intent of individuals and groups supplying information, but may undermine the credibility of sociology itself.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 6
    Digitale Medien
    Digitale Medien
    Springer
    Communications in mathematical physics 139 (1991), S. 103-139 
    ISSN: 1432-0916
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Mathematik , Physik
    Notizen: Abstract We study the options for boundary conditions at the conical singularity for quantum mechanics on a two-dimensional cone with deficit angle ≦ 2π and for classical and quantum scalar fields propagating with a translationally invariant dynamics in the 1+3 dimensional spacetime around an idealized straight infinitely long, infinitesimally thin cosmic string. The key to our analysis is the observation that minus-the-Laplacian on a cone possesses a one-parameter family of selfadjoint extensions. These may be labeled by a parameterR with the dimensions of length—taking values in [0, ∞). ForR=0, the extension is positive. WhenR≠0 there is a bound state. Each of our problems has a range of possible dynamical evolutions corresponding to a range of allowedR-values. They correspond to either finite, forR=0, or logarithmically divergent, forR≠0, boundary conditions at zero radius. Non-zeroR-values are a satisfactory replacement for the (mathematically ill-defined) notion of δ-function potentials at the cone's apex. We discuss the relevance of the various idealized dynamics to quantum mechanics on a cone with a rounded-off centre and field theory around a “true” string of finite thickness. Provided one is interested in effects at sufficiently large length scales, the “true” dynamics will depend on the details of the interaction of the wave function with the cone's centre (/field with the string etc.) only through a single parameterR (its “scattering length”) and will be well-approximated by the dynamics for the corresponding idealized problem with the sameR-value. This turns out to be zero if the interaction with the centre is purely gravitational and minimally coupled, but non-zero values can be important to model nongravitational (or non-minimally coupled) interactions. Especially, we point out the relevance of non-zeroR-values to electromagnetic waves around superconducting strings. We also briefly speculate on the relevance of theR-parameter in the application of quantum mechanics on cones to 1+2 dimensional quantum gravity with massive scalars.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 7
    Digitale Medien
    Digitale Medien
    Springer
    Communications in mathematical physics 148 (1992), S. 553-600 
    ISSN: 1432-0916
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Mathematik , Physik
    Notizen: Abstract We show that the non-relativistic quantum mechanics of particles with spin coupled to an electromagnetic field has a naturalU(1)×SU(2) gauge invariance. Ward identities reflecting this gauge invariance combined with an assumption of incompressibility of a system of such particles in an appropriate external field and for suitable values of the particle density permit us to determine the form of the effective action of the system as a functional of small fluctuations in the electromagnetic field, in the large-distance-, adiabatic limit. In this limit, the action is found to have a universal form. We present explicit results for two-dimensional, incompressible electron fluids and apply them to derive the equations of linear response theory, describing a variety of generalized Hall effects. Sum rules for the Hall conductivities, magnetic susceptibilities and other quantities of physical interest are found.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 8
    Digitale Medien
    Digitale Medien
    Springer
    Planta 188 (1992), S. 155-163 
    ISSN: 1432-2048
    Schlagwort(e): Bradyrhizobium ; Electron microscopy ; Glycine (root nodules) ; High-pressure freezing ; Ultrastructure
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie
    Notizen: Abstract High-pressure freezing of chemically untreated nodules of soybean (Glycine max (L.) Merr.), in sharp contrast to chemical fixation and prefixation, appears to preserve the ultrastructure close to the native state. This is supported by the observation that the peribacteroid membrane of high-pressure-frozen samples is tightly wrapped around the bacteroids, a finding that is fully consistent with the current views on the physiology of oxygen and metabolite transport between plant cytosol and bacteroids. In soybean root nodules, the plant tissue and the enclosed bacteria are so dissimilar that conventional aldehyde-fixation procedures are unable to preserve the overall native ultrastructure. This was demonstrated by high-pressure freezing of nodules that had been pre-fixed in glutaraldehyde at various buffer molalities: no buffer strength tested preserved all ultrastructural aspects that could be seen after high-pressure freezing of chemically untreated nodules.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 9
    Digitale Medien
    Digitale Medien
    Springer
    Water, air & soil pollution 68 (1993), S. 291-305 
    ISSN: 1573-2932
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Energietechnik
    Notizen: Abstract Transport of volatile hydrocarbons in soils is largely controlled by interactions of vapours with the liquid and solid phase. Sorption on solids of gaseous or dissolved compounds may be important. Since the contact time between a chemical and a specific sorption site can be rather short, kinetic or mass-transfer resistance effects may be relevant. An existing mathematical model describing advection and diffusion in the gas phase and diffusional transport from the gaseous phase into an intra-aggregate water phase is modified to include linear kinetic sorption on gas-solid and water-solid interfaces. The model accounts for kinetic mass transfer between all three phases in a soil. The solution of the Laplace-transformed equations is inverted numerically. We performed transient column experiments with 1,1,2-Trichloroethane, Trichloroethylene, and Tetrachloroethylene using air-dry solid and water-saturated porous glass beads. The breakthrough curves were calculated based on independently estimated parameters. The model calculations agree well with experimental data. The different transport behaviour of the three compounds in our system primarily depends on Henry's constants.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 10
    Digitale Medien
    Digitale Medien
    Springer
    The journal of membrane biology 38 (1978), S. 51-72 
    ISSN: 1432-1424
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie , Chemie und Pharmazie
    Notizen: Summary The effects of calcium ionophores on cellular calcium metabolism were studied in cultured kidney cells, in cells freshly isolated from rat kidney, and in liver and kidney slices. In isolated cells, these ionophores decreased the total cellular Ca content and the mitochondrial Ca.45Ca efflux from prelabelled cells was also stimulated even in the absence of extracellular Ca. In slices, the ionophore A23187 increased the total slice Ca and the uptake of45Ca. However, the mitochondria isolated from these slices treated with the ionophore had a lower total Ca and a depressed relative radioactivity. These results suggest that the increased cytosolic Ca produced by Ca ionophores may be due to mobilization of intracellular Ca stores rather than to a net shift of Ca from the extracellular fluids to the cell.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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