Publication Date:
1999-12-01
Description:
The structural evolution of LiMn2O4spinel was followed from 320 K down to 10 K. The structural transformation, recently studied down to 230 K [Rodriguez-Carvajal, Rousse, Masquelier & Hervieu (1998).Phys. Rev. Lett.81, 4660–4663], takes place near room temperature with a significant hysteresis: the high-temperature cubic phase transforms to a superstructure orthorhombic cell. The present study indicates that the nuclear structure is stable down to 10 K, while neutron diffraction patterns below 80 K show the rise of a magnetic ordering in the spinel phase. From Mn—O bond-length analysis of the MnO6octahedra, a temperature-independent charge ordering in the structure can be deduced.
Print ISSN:
0021-8898
Electronic ISSN:
1600-5767
Topics:
Geosciences
,
Physics
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