ALBERT

Description: The Antarctic ice sheet extent in the Weddell Sea embayment (WSE) during the Last Glacial Maximum (LGM; ca. 19–25 calibrated kiloyears before present, ka cal BP) and its subsequent retreat from the shelf are poorly constrained, with two conflicting scenarios being discussed. Today, the modern Brunt Ice Shelf, the last remaining ice shelf in the northeastern WSE, is only pinned at a single location and recent crevasse development may lead to its rapid disintegration in the near future. We investigated the seafloor morphology on the northeastern WSE shelf and discuss its implications, in combination with marine geological records, to create reconstructions of the past behaviour of this sector of the East Antarctic Ice Sheet (EAIS), including ice–seafloor interactions. Our data show that an ice stream flowed through Stancomb-Wills Trough and acted as the main conduit for EAIS drainage during the LGM in this sector. Post-LGM ice stream retreat occurred stepwise, with at least three documented grounding-line still-stands, and the trough had become free of grounded ice by ∼10.5 ka cal BP. In contrast, slow-flowing ice once covered the shelf in Brunt Basin and extended westwards toward McDonald Bank. During a later time period, only floating ice was present within Brunt Basin, but large “ice slabs” enclosed within the ice shelf occasionally ran aground at the eastern side of McDonald Bank, forming 10 unusual ramp-shaped seabed features. These ramps are the result of temporary ice shelf grounding events buttressing the ice further upstream. To the west of this area, Halley Trough very likely was free of grounded ice during the LGM, representing a potential refuge for benthic shelf fauna at this time.

Description: Baffin Bay is a semi-enclosed basin connecting the Arctic Ocean and the western North Atlantic, thus making out a significant pathway for heat exchange. Here we reconstruct the alternating advection of relatively warmer and saline Atlantic waters versus the incursion of colder Arctic water masses entering Baffin Bay through the multiple gateways in the Canadian Arctic Archipelago and the Nares Strait during the Holocene. We carried out benthic foraminiferal assemblage analyses, X-ray fluorescence scanning, and radiocarbon dating of a 738 cm long marine sediment core retrieved from eastern Baffin Bay near Upernavik, Greenland (Core AMD14-204C; 987 m water depth). Results reveal that eastern Baffin Bay was subjected to several oceanographic changes during the last 9.2 kyr. Waning deglacial conditions with enhanced meltwater influxes and an extensive sea-ice cover prevailed in eastern Baffin Bay from 9.2 to 7.9 ka. A transition towards bottom water amelioration is recorded at 7.9 ka by increased advection of Atlantic water masses, encompassing the Holocene Thermal Maximum. A cold period with growing sea-ice cover at 6.7 ka interrupts the overall warm subsurface water conditions, promoted by a weaker northward flow of Atlantic waters. The onset of the neoglaciation at ca. 2.9 ka is marked by an abrupt transition towards a benthic fauna dominated by agglutinated species, likely in part explained by a reduction of the influx of Atlantic Water, allowing an increased influx of the cold, corrosive Baffin Bay Deep Water originating from the Arctic Ocean to enter Baffin Bay through the Nares Strait. These cold subsurface water conditions persisted throughout the Late Holocene, only interrupted by short-lived warmings superimposed on this cooling trend.

Description: Centennial- and millennial-scale variability of Southern Ocean temperature over the Holocene is poorly known, due to both short instrumental records and sparsely distributed high-resolution temperature reconstructions, with evidence for past temperature variations in the region coming mainly from ice core records. Here we present a high-resolution (∼60 year), diatom-based sea surface temperature (SST) reconstruction from the western Indian sector of the Southern Ocean that spans the interval 14.2 to 1.0 ka (calibrated kiloyears before present). During the late deglaciation, the new SST record shows cool temperatures at 14.2–12.9 ka and gradual warming between 12.9 and 11.6 ka in phase with atmospheric temperature evolution. This supports the evolution of the Southern Ocean SST during the deglaciation being linked with a complex combination of processes and drivers associated with reorganisations of atmospheric and oceanic circulation patterns. Specifically, we suggest that Southern Ocean surface warming coincided, within the dating uncertainties, with the reconstructed slowdown of the Atlantic Meridional Overturning Circulation (AMOC), rising atmospheric CO2 levels, changes in the southern westerly winds and enhanced upwelling. During the Holocene the record shows warm and stable temperatures from 11.6 to 8.7 ka followed by a slight cooling and greater variability from 8.7 to 1 ka, with a quasi-periodic variability of 200–260 years identified by spectral analysis. We suggest that the increased variability during the mid- to late Holocene reflects the establishment of centennial variability in SST connected with changes in the high-latitude atmospheric circulation and Southern Ocean convection.

Description: We measured the radioactive carbon isotope 14C (radiocarbon) in various fractions of the carbonaceous aerosol sampled between February 2011 and March 2012 at the Cesar Observatory in the Netherlands. Based on the radiocarbon content in total carbon (TC), organic carbon (OC), water-insoluble organic carbon (WIOC), and elemental carbon (EC), we estimated the contribution of major sources to the carbonaceous aerosol. The main source categories were fossil fuel combustion, biomass burning, and other contemporary carbon, which is mainly biogenic secondary organic aerosol material (SOA). A clear seasonal variation is seen in EC from biomass burning (ECbb), with lowest values in summer and highest values in winter, but ECbb is a minor fraction of EC in all seasons. WIOC from contemporary sources is highly correlated with ECbb, indicating that biomass burning is a dominant source of contemporary WIOC. This suggests that most biogenic SOA is water soluble and that water-insoluble carbon stems mainly from primary sources. Seasonal variations in other carbon fractions are less clear and hardly distinguishable from variations related to air mass history. Air masses originating from the ocean sector presumably contain little carbonaceous aerosol from outside the Netherlands, and during these conditions measured carbon concentrations reflect regional sources. In these situations absolute TC concentrations are usually rather low, around 1.5 µg m−3, and ECbb is always very low ( ∼  0.05 µg m−3), even in winter, indicating that biomass burning is not a strong source of carbonaceous aerosol in the Netherlands. In continental air masses, which usually arrive from the east or south and have spent several days over land, TC concentrations are on average by a factor of 3.5 higher. ECbb increases more strongly than TC to 0.2 µg m−3. Fossil EC and fossil WIOC, which are indicative of primary emissions, show a more moderate increase by a factor of 2.5 on average. An interesting case is fossil water-soluble organic carbon (WSOC, calculated as OC-WIOC), which can be regarded as a proxy for SOA from fossil precursors. Fossil WSOC has low concentrations when regional sources are sampled and increases by more than a factor of 5 in continental air masses. A longer residence time of air masses over land seems to result in increased SOA concentrations from fossil origin.

Description: A large number of radiometers are traceable to the World Standard Group (WSG) for shortwave radiation and the interim World Infrared Standard Group (WISG) for longwave radiation, hosted by the Physikalisch-Meteorologisches Observatorium Davos/World Radiation Centre (PMOD/WRC, Davos, Switzerland). The WSG and WISG have recently been found to over- and underestimate radiation values, respectively (Fehlmann et al., 2012; Gröbner et al., 2014), although research is still ongoing. In view of a possible revision of the reference scales of both standard groups, this study discusses the methods involved and the implications on existing archives of radiation time series, such as the Baseline Surface Radiation Network (BSRN). Based on PMOD/WRC calibration archives and BSRN data archives, the downward longwave radiation (DLR) time series over the 2006–2015 period were analysed at four stations (polar and mid-latitude locations). DLR was found to increase by up to 3.5 and 5.4 W m−2 for all-sky and clear-sky conditions, respectively, after applying a WISG reference scale correction and a minor correction for the dependence of pyrgeometer sensitivity on atmospheric integrated water vapour content. Similar increases in DLR may be expected at other BSRN stations. Based on our analysis, a number of recommendations are made for future studies.

Description: Late-glacial palaeoclimate reconstructions from deep-sea sediment archives provide valuable insight into past rapid changes in ocean chemistry, but only a small proportion of the ocean floor is suitable for such reconstructions using the existing state-of-the-art using the age-depth approach. We employ ultra-small radiocarbon (14C) dating on single microscopic foraminifera to demonstrate that the longstanding age-depth method conceals large age uncertainty caused by post-depositional sediment mixing, meaning that existing studies may underestimate total geochronological error. To overcome these problems, we use dual 14C and stable isotope (δ18O and δ13C) analysis on single microscopic foraminifera to produce a palaeoclimate time series independent of the age-depth paradigm. This new and novel method will address large geographical gaps in late-glacial benthic palaeoceanographic reconstructions by opening up vast areas of previously disregarded deep-sea archives, leading to improved understanding of the global interaction between oceans and climate.

Description: Particulate matter was collected at an urban site in Göteborg (Sweden) in February/March 2005 and in June/July 2006. Additional samples were collected at a rural site for the winter period. Elemental carbon (EC), organic carbon (OC), water-insoluble OC (WINSOC), and water-soluble OC (WSOC) were analyzed for 14C in order to distinguish fossil from non-fossil emissions. As wood burning is the single major source of non-fossil EC, its contribution can be quantified directly. For non-fossil OC, the wood burning fraction was determined independently by levoglucosan and 14C analysis and combined using Latin-hypercube sampling (LHS). For the winter period, the relative contribution of EC from wood burning to the total EC was 〉3 times higher at the rural site compared to the urban site, whereas the absolute concentrations of EC from wood burning were comparable at both sites. Thus, the urban site is substantially more influenced by fossil EC emissions. For summer, biogenic emissions dominated OC concentrations most likely due to secondary organic aerosol (SOA) formation. During both seasons, a more pronounced fossil signal was observed for Göteborg than has previously been reported for Zurich, Switzerland. Analysis of air mass origin using back trajectories suggests that the fossil impact was larger when local sources dominated, whereas long-range transport caused an enhanced non-fossil signal. In comparison to other European locations, concentrations of levoglucosan and other monosaccharide anhydrides were low for the urban and the rural site in the area of Göteborg during winter. The comparison of summer and winter results provides insight into the annual cycle of anthropogenic vs. biogenic contributions to the atmospheric aerosol.

Description: Residential wood combustion has only recently been recognized as a major contributor to air pollution in Switzerland and in other European countries. A source apportionment method using the aethalometer light absorption parameters was applied to five winter campaigns at three sites in Switzerland: a village with high wood combustion activity in winter, an urban background site and a highway site. The particulate mass from traffic (PMtraffic) and wood burning (PMwb) emissions obtained with this model compared fairly well with results from the 14C source apportionment method. PMwb from the model was also compared to well known wood smoke markers such as anhydrosugars (levoglucosan and mannosan) and fine mode potassium, as well as to a marker recently suggested from the Aerodyne aerosol mass spectrometer (mass fragment m/z 60). Additionally the anhydrosugars were compared to the 14C results and were shown to be comparable to literature values from wood burning emission studies using different types of wood (hardwood, softwood). The levoglucosan to PMwb ratios varied much more strongly between the different campaigns (4–13%) compared to mannosan to PMwb with a range of 1–1.5%. Possible uncertainty aspects for the various methods and markers are discussed.

Description: Particulate matter was collected at an urban site in Göteborg (Sweden) in February/March 2005 and in June/July 2006. Additional samples were collected at a rural site for the winter period. Total carbon (TC) concentrations were 2.1–3.6 μg m−3, 1.8–1.9 μg m−3, and 2.2–3.0 μg m−3 for urban/winter, rural/winter, and urban/summer conditions, respectively. Elemental carbon (EC), organic carbon (OC), water-insoluble OC (WINSOC), and water-soluble OC (WSOC) were analyzed for 14C in order to distinguish fossil from non-fossil emissions. As wood burning is the single major source of non-fossil EC, its contribution can be quantified directly. For non-fossil OC, the wood-burning fraction was determined independently by levoglucosan and 14C analysis and combined using Latin-hypercube sampling (LHS). For the winter period, the relative contribution of EC from wood burning to the total EC was 〉3 times higher at the rural site compared to the urban site, whereas the absolute concentrations of EC from wood burning were elevated only moderately at the rural compared to the urban site. Thus, the urban site is substantially more influenced by fossil EC emissions. For summer, biogenic emissions dominated OC concentrations most likely due to secondary organic aerosol (SOA) formation. During both seasons, a more pronounced fossil signal was observed for Göteborg than has previously been reported for Zurich, Switzerland. Analysis of air mass origin using back trajectories suggests that the fossil impact was larger when local sources dominated, whereas long-range transport caused an enhanced non-fossil signal. In comparison to other European locations, concentrations of levoglucosan and other monosaccharide anhydrides were low for the urban and the rural site in the area of Göteborg during winter.

Description: Dual carbon isotope analysis of marine aerosol samples has been performed for the first time demonstrating a potential in organic matter apportionment between three principal sources: marine, terrestrial (non-fossil) and fossil fuel due to unique isotopic signatures. The results presented here, utilising combinations of dual carbon isotope analysis, provides conclusive evidence of a dominant biogenic organic fraction to organic aerosol over biologically active oceans. In particular, the NE Atlantic, which is also subjected to notable anthropogenic influences via pollution transport processes, was found to contain 80 % organic aerosol matter of biogenic origin directly linked to plankton emissions. The remaining carbonaceous aerosol was of terrestrial origin. By contrast, for polluted air advected out from Europe into the NE Atlantic, the source apportionment is 30 % marine biogenic, 40 % fossil fuel, and 30 % continental non-fossil fuel. The dominant marine organic aerosol source in the atmosphere has significant implications for climate change feedback processes.