ALBERT

Description: Surface albedo, a primary control on the amount of energy available for melt, has considerable spatial heterogeneity across the Greenland ice sheet ablation area. However, the relative importance of distinct surface types on albedo remains unclear. In this study, the causes of mesoscale (102 to 103 m) albedo variability are assessed using high resolution (decimetre-scale) digital imagery and broadband albedo data acquired by a fixed-wing unmanned aerial system. We characterize the reflectance properties and terrain roughness associated with six distinct surface types identified from a 25 km longitudinal transect across the ablating dark region of the Kangerlussuaq sector. Principal component analysis of the fractional area of each surface type versus coincident Moderate Resolution Imaging Spectroradiometer (MODIS) albedo data reveals the relative importance of each surface type. The highest correlation with mesoscale albedo was the fractional area of distributed impurities. Although not the darkest surface type, their extensive coverage meant that they could explain 65 % of the albedo variability across the survey transect including the presence of the dark region. In contrast, the 2 % mean surface water coverage across our survey transect could only explain 12 % of albedo variation and crevasses, only 17 %. Localised cryoconite patches have the lowest albedo signature but comprise less than 1 % of the survey area and do not appear to reduce mesoscale albedo. We anticipate further reduction in ablation area albedo under future warming as localized areas of distributed impurities, supraglacial water and crevassing increase in extent and conclude that current bare ice area albedo models may advance significantly by representing the evolution of the surface types identified in this study.

Description: Determining the concentration and composition of dissolved organic carbon (DOC) in glacial ecosystems is important for assessments of in situ microbial activity and contributions to wider biogeochemical cycles. Nonetheless, there is limited knowledge of the abundance and character of DOC in basal ice and the subglacial environment and a lack of quantitative data on low-molecular-weight (LMW) DOC components, which are believed to be highly bioavailable to microorganisms. We investigated the abundance and composition of DOC in basal ice via a molecular-level DOC analysis. Spectrofluorometry and a novel ion chromatographic method, which has been little utilized in glacial science for LMW-DOC determinations, were employed to identify and quantify the major LMW fractions (free amino acids, carbohydrates, and carboxylic acids) in basal ice from four glaciers, each with a different type of overridden material (i.e. the pre-entrainment sedimentary type such as lacustrine material or palaeosols). Basal ice from Joyce Glacier (Antarctica) was unique in that 98 % of the LMW-DOC was derived from the extremely diverse free amino acid (FAA) pool, comprising 14 FAAs. LMW-DOC concentrations in basal ice were dependent on the bioavailability of the overridden organic carbon (OC), which in turn was influenced by the type of overridden material. Mean LMW-DOC concentrations in basal ice from Russell Glacier (Greenland), Finsterwalderbreen (Svalbard), and Engabreen (Norway) were low (0–417 nM C), attributed to the relatively refractory nature of the OC in the overridden palaeosols and bedrock. In contrast, mean LMW-DOC concentrations were an order of magnitude higher (4430 nM C) in basal ice from Joyce Glacier, a reflection of the high bioavailability of the overridden lacustrine material (〉 17 % of the sediment OC comprised extractable carbohydrates, a proxy for bioavailable OC). We find that the overridden material may act as a direct (via abiotic leaching) and indirect (via microbial cycling) source of DOC to the subglacial environment and provides a range of LMW-DOC compounds that may stimulate microbial activity in wet subglacial sediments.