ALBERT

Description: Three years of greenhouse gases measurements, obtained using a gas chromatograph (GC) system located at the Puy de Dôme station at 1465 m a.s.l. in Central France are presented. The GC system was installed in 2010 at Puy de Dôme and was designed for automatic and accurate semi-continuous measurements of atmospheric carbon dioxide, methane, nitrous oxide and sulfur hexafluoride mole fractions. We present in detail the instrumental set up and the calibration strategy, which together allow the GC to reach repeatabilities of 0.1 μmol mol−1, 1.2, 0.3 nmol mol−1 and 0.06 pmol mol−1 for CO2, CH4, N2O and SF6, respectively. Comparisons of the atmospheric time series with those obtained using other instruments shown that the GC system meets the World Meteorological Organization recommendations. The analysis of the three-year atmospheric time series revealed how the planetary boundary layer height drives the mole fractions observed at a mountain site such as Puy de Dôme where air masses alternate between the planetary boundary layer and the free troposphere. Accurate long-lived greenhouse gases measurements collocated with 222Rn measurements as an atmospheric tracer, allowed us to determine the CO2, CH4 and N2O emissions in the catchment area of the station. The derived CO2 surface flux revealed a clear seasonal cycle with net uptake by plant assimilation in the spring and net emission caused by the biosphere and burning of fossil fuel during the remainder of the year. We calculated a mean annual CO2 flux of 1150 t(CO2) km−2. The derived CH4 and N2O emissions in the station catchment area were 5.6 t(CH4) km−2 yr−1 and 1.5 t(N2O) km−2 yr−1, respectively. Our derived annual CH4 flux is in agreement with the national French inventory, whereas our derived N2O flux is five times larger than the same inventory.

Description: This study presents two methods for estimating methane emissions from a waste water treatment plant (WWTP) along with results from a measurement campaign at a WWTP in Valence, France. These methods, chamber measurements and tracer release, rely on Fourier Transform Infrared (FTIR) spectroscopy and Cavity Ring Down Spectroscopy (CRDS) instruments. We show that the tracer release method is suitable to quantify facility- and some process-scale emissions, while the chamber measurements, provide insight into individual process emissions. Uncertainties for the two methods are described and discussed. Applying the methods to CH4 emissions of the WWTP, we confirm that the open basins are not a major source of CH4 on the WWTP (about 10% of the total emissions), but that the pretreatment and sludge treatment are the main emitters. Overall, the waste water treatment plant represents a small part (about 1.5%) of the methane emissions of the city of Valence and its surroundings, which is lower than the national inventories.

Description: This study compares actual evapotranspiration (ETa) measurements by a set of six weighable lysimeters, ETa estimates obtained with the eddy covariance (EC) method, and evapotranspiration calculated with the full-form Penman–Monteith equation (ETPM) for the Rollesbroich site in the Eifel (western Germany). The comparison of ETa measured by EC (including correction of the energy balance deficit) and by lysimeters is rarely reported in the literature and allows more insight into the performance of both methods. An evaluation of ETa for the two methods for the year 2012 shows a good agreement with a total difference of 3.8% (19 mm) between the ETa estimates. The highest agreement and smallest relative differences (〈 8%) on a monthly basis between both methods are found in summer. ETa was close to ETPM, indicating that ET was energy limited and not limited by water availability. ETa differences between lysimeter and EC were mainly related to differences in grass height caused by harvest and the EC footprint. The lysimeter data were also used to estimate precipitation amounts in combination with a filter algorithm for the high-precision lysimeters recently introduced by Peters et al. (2014). The estimated precipitation amounts from the lysimeter data differ significantly from precipitation amounts recorded with a standard rain gauge at the Rollesbroich test site. For the complete year 2012 the lysimeter records show a 16 % higher precipitation amount than the tipping bucket. After a correction of the tipping bucket measurements by the method of Richter (1995) this amount was reduced to 3%. With the help of an on-site camera the precipitation measurements of the lysimeters were analyzed in more detail. It was found that the lysimeters record more precipitation than the tipping bucket, in part related to the detection of rime and dew, which contribute 17% to the yearly difference between both methods. In addition, fog and drizzle explain an additional 5.5% of the total difference. Larger differences are also recorded for snow and sleet situations. During snowfall, the tipping bucket device underestimated precipitation severely, and these situations contributed also 7.9% to the total difference. However, 36% of the total yearly difference was associated with snow cover without apparent snowfall, and under these conditions snow bridges and snow drift seem to explain the strong overestimation of precipitation by the lysimeter. The remaining precipitation difference (about 33%) could not be explained and did not show a clear relation to wind speed. The variation of the individual lysimeters devices compared to the lysimeter mean are small, showing variations up to 3% for precipitation and 8% for evapotranspiration.

Description: Representation of atmospheric transport is a major source of error in the estimation of greenhouse gas sources and sinks by inverse modelling. Here we assess the impact on trace gas mole fractions of the new physical parameterizations recently implemented in the atmospheric global climate model LMDz to improve vertical diffusion, mesoscale mixing by thermal plumes in the planetary boundary layer (PBL), and deep convection in the troposphere. At the same time, the horizontal and vertical resolution of the model used in the inverse system has been increased. The aim of this paper is to evaluate the impact of these developments on the representation of trace gas transport and chemistry, and to anticipate the implications for inversions of greenhouse gas emissions using such an updated model. Comparison of a one-dimensional version of LMDz with large eddy simulations shows that the thermal scheme simulates shallow convective tracer transport in the PBL over land very efficiently, and much better than previous versions of the model. This result is confirmed in three-dimensional simulations, by a much improved reproduction of the radon-222 diurnal cycle. However, the enhanced dynamics of tracer concentrations induces a stronger sensitivity of the new LMDz configuration to external meteorological forcings. At larger scales, the inter-hemispheric exchange is slightly slower when using the new version of the model, bringing them closer to observations. The increase in the vertical resolution (from 19 to 39 layers) significantly improves the representation of stratosphere/troposphere exchange. Furthermore, changes in atmospheric thermodynamic variables, such as temperature, due to changes in the PBL mixing modify chemical reaction rates, which perturb chemical equilibriums of reactive trace gases. One implication of LMDz model developments for future inversions of greenhouse gas emissions is the ability of the updated system to assimilate a larger amount of high-frequency data sampled at high-variability stations. Others implications are discussed at the end of the paper.