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  • Polymer and Materials Science  (7)
  • 1960-1964  (7)
  • 1
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 6 (1962), S. S68 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 7 (1963), S. 1691-1695 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Comparisons were made of changes in molecular weight and in tensile strength of regenerated cellulose after exposure to 40% KOH at 90°C., for varying lengths of time. In the absence of air, both parameters decreased in a fairly consistent manner. In the presence of air, an initial steeper drop was followed by an irregular up-and-down pattern. The theory is advanced that the increase in tensile strength was caused by increased crystallinity.
    Additional Material: 3 Ill.
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  • 3
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The composition of crosslinked polyester-urethanes has been varied by adjusting the ratio of ester to urethane groups. The crosslinking density of these materials has been varied by changes in the polyester functionality. The polyester-urethanes have been subjected to solvent extraction, wherein it was found that at high crosslinking densities, the solubility of the polymers is unaffected by the ester-urethane ratio. At low crosslinking densities, solubility increases slightly with increasing urethane concentration. The solubility was also found to increase with decreasing crosslinking density. Data obtained from isothermal heat aging and thermogravimetric analysis, both carried out in air and in inert atmosphere, indicate that thermal stability increases with increasing ester/urethane ratio and is independent of crosslinking density where the ester/urethane ratio is held constant. In addition, data obtained from heat aging and thermogravimetric analysis have indicated that decomposition of the samples occurs as rapidly in inert atmosphere as in air, indicating that the decomposition occurs chiefly by a nonoxidative mechanism.
    Additional Material: 6 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 8 (1964), S. 673-685 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The corrosion of steel by nitrile elastomer oil seals prompted a laboratory study of the corrosivity of numerous compounding ingredients and nitrile polymers. Groups of materials studied in this investigation were plasticizers, antioxidants, black fillers, nonblack fillers, curing systems, and base polymers. A corrosion test procedure utilizing a benchtype corrosion chamber was developed, and a corrosion rating system was established. All materials were rated according to their corrosivity under conditions of 100% R. H., and 100°F. for 96 hr. From these data it was possible to formulate several noncorrosive seal compounds without the use of corrosion inhibitors.
    Additional Material: 3 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    Journal of Polymer Science 48 (1960), S. 301-308 
    ISSN: 0022-3832
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The degradation of deoxyribonucleic acid (DNA) by irradiation of its aqueous solutions with ionizing radiations in the presence of oxygen has been discussed in terms of the reactions of free radicals (produced by the radiolytic decomposition of the water) with the different molecular entities of the macromolecule. It has been found that attack of the radicals on the purine and pyrimidine bases is a major effect of the irradiation, and it has been estimated that about 80% of the OH radicals attack the base components. In the presence of oxygen an important radiation-induced reaction is the formation of peroxidic compounds from the pyrimidines. Breakage of the strands in the DNA helix is apparently due mainly to an attack of the radiation-produced radicals on the sugar moieties which leads to a splitting of the phosphate ester linkages along the chains. The extent of attack which leads to breakage of internucleotide bonds, leading to the production of phosphomonoester groups, has been determined directly: the number of endgroups formed on irradiation with 200 k.v. x-rays corresponds to a yield of G ⋍ 0.5 (endgroups/100 e.v.). Rupture of hydrogen bonds within the helix is a consequence of chemical changes in the polynucleotide chains; several hydrogen bonds can be broken following a single chemical event. The hyperchromic effect which is observed in the action of the radiations on nucleic acids in solutions has been investigated in some detail. It has been concluded that this effect is caused, in general, by environmental changes of the chromophoric groups of the purine and pyrimidine bases of the DNA, and is due to the change of the nature of the hydrogen bonding of the bases within the intact helix, where the bases of one strand are bonded to the bases of the complementary strand, to hydrogen bonding with water molecules when the latter have penetrated between the strands of the helix.
    Additional Material: 2 Tab.
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  • 6
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    Journal of Polymer Science 49 (1961), S. 437-454 
    ISSN: 0022-3832
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The precipitation chromatography method of Baker and Williams has been found to have advantages in efficiency and ease of operation over other methods for fractionation of polymers. Good fractionations according to molecular weight have been obtained on several polymers of widely different molecular weight distributions, including samples of polystyrenes and of a high molecular weight polyolefin.
    Additional Material: 7 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Letters 2 (1964), S. 915-919 
    ISSN: 0449-2986
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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