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  • Polymer and Materials Science  (609)
  • 1960-1964  (409)
  • 1955-1959  (200)
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Year
  • 1
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 7 (1963), S. 1991-2002 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Infrared spectra indicate that carboxyl-substituted acrylic copolymers react appreci8bly with a butylated melamine-formaldehyde resin when heated at 120°C. for 30 min., but under these conditions acid catalysis is needed before epoxy- or amido-substituted copolymers will crosslink with the melamine-formaldehyde resin. Two methods have been used to synthesize hydroxyl-substituted acrylic copolymers. First, a glycidyl methacrylate copolymer was reacted with diethplamine. Second, an acrylic acid copolymer was heated under reflux with butylene oxide in the presence of a basic catalyst. This second method was used to esterify a vinyl toluene-acrylic acid-acrylamide copolymer which was subsequently treated with paraformaldehyde. The resulting hydroxy-methylolamido copolymer intercondensed when heated at 120°C. for 30 min., somewhat as did the hydroxy copolymer with melamine-formaldehyde resin blends.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 5 (1961), S. 527-533 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A system is described for automatic collection of stress-strain data for polymeric films on magnetic tape for subsequent automatic data reduction and computation of a variety of stress-strain parameters. Two shaft analog-to-digital encoders attached to a conventional tensile tester feed digital information to an incremental pulse recorder which stores all stress and strain data in two channels on 0.625-in. magnetic tape. Specimen information and test constants are inserted by the operator through a keyboard located at the tensile tester. The tape is subsequently fed into a standard digital computer through a special incremental pulse magnetic tape reader. The data pulses are internally stored and converted by means of a special program into eight significant stress-strain parameters for polymeric film samples, plus averages and standard deviations for groups of replicate determinations. These parameters include: corrected length of specimen, initial maximum tensile modulus, offset yield stress, strain at break, strain at maximum stress, maximum tensile stress, tensile stress at break, and work to break. While the program described applies to polymer film testing, both it and the digital recording equipment accessories are applicable with suitable modification, to any analog experimental data. Significant savings in man-hours and increased information output result from use of this system.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 6 (1962), S. S46 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Additional Material: 1 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 2 (1959), S. 368-370 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Additional Material: 2 Ill.
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  • 5
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The free-radical polymerization of vinyl fluoride has been studied with the use of organic peroxide and azo initiators over the temperature range of 60-150°C. and at pressures of 75-1000 atm. Molecular weights of the polymers by osmotic pressure or radiotracer techniques were found to vary over the range of 45,000 to 180,000 depending on polymerization conditions employed. Stabilized high molecular weight polyvinyl fluoride may be compression-molded into tough, high-impact strength bars, or the unstabilized material may be cast into films from solvents such as dimethylformamide. The films, which may be cold drawn, are tough, brilliantly clear, and have tensile strengths near 8000 lb./in.2 They are also extremely resistant to weathering, maintaining clarity and cold drawability even after ten years' exposure in Florida.
    Additional Material: 6 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 8 (1964), S. 1919-1919 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 1 (1959), S. 371-371 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Type of Medium: Electronic Resource
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  • 8
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Investigations of the viscoelastic aspects of the mechanical behavior of polymers have been limited almost exclusively to relatively simple conditions of homogeneous stress, that is, to tension or shear loadings. In the present work a study has been made from the viscoelastic standpoint of the response of several elastomers to a much more complex type of stress distribution arising from penetration up to failure by a cylindrical indentor for a range of temperatures and rates of penetration. The failure or “puncture point” was determined by a dip in the recorded curve of load versus depth of penetration. The puncture strength values were reduced to 25°C. by applying the ratio of absolute temperatures and plotted against the logarithm of the reciprocal of the rate of penetration. These curves were then shifted on the time scale to give a master curve after the manner of Tobolsky and of Ferry. The logarithms of the shift factors thus obtained were related to the reciprocal of the absolute temperature over the range studied. The results indicate a broader generality for the viscoelastic principle of time-temperature equivalence than has usually been supposed.
    Additional Material: 13 Ill.
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  • 9
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Measurements of the density of a large number of experimental isotactic polypropylenes have shown that the specific volume is linearly related to per cent crystallinity as determined from x-ray data. The density is also linearly related to the absorbance of certain absorption bands in the infrared spectrum of isotactic polypropylene. The infrared data allow a determination of the density of the amorphous polymer which is in good agreement with literature values and with a value determined from the x-ray data by extrapolation to zero crystallinity. It is found that there is a rough, approximately linear correlation between crystallinity (by density) of unextracted polypropylene and the per cent insoluble residue remaining after extraction with boiling n-heptane or after successive extraction with other solvents and heptane. In all instances, the amount of residue exceeds the crystalline content. The crystallinity-insolubility relationship is influenced by molecular weight (as judged by intrinsic viscosity). An increase in crystallinity at constant [η] corresponds to an increase in insolubility; at constant crystallinity, a larger [η] corresponds to greater insolubility. In terms of density, the unextracted polymer may not be regarded as simply a mixture of two well-defined components, since the density of insoluble residue increases with the density of the whole polymer.
    Additional Material: 6 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 7 (1963), S. 461-468 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The changes in solvent resistance and solution viscosity of polyethylene glycol and polypropylene glycol after heating with dicumyl peroxide at 140°C. are consistent with crosslinking of the former and degradation of the latter. Analytical work showed that in both cases all of the peroxide decomposed could be accounted for acetophenone and cumyl alcohol. In the case of polyethylene glycol, crosslinking results from abstraction of secondary hydrogen atoms and dimerization of the resulting radicals; in the case of polypropylene glycol abstraction of tertiary hydrogen atoms leads to radicals which break down by scission at a C—O bond to give a ketone and a more stable radical. This latter process proceeds with an efficiency of unity.
    Additional Material: 2 Ill.
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