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  • 1
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Letters Edition 12 (1974), S. 723-727 
    ISSN: 0360-6384
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 17 (1973), S. 1693-1713 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The bending stress relaxation and subsequent recovery behavior were determined for merino wool, nylon, and Terylene fibers. The effect of four experimental parameters were investigated, viz., the level of bending strain (0.5-4%), the time of stress relaxation before release (1-1000 min), the relative humidity (0-85%), and the temperature (20°-60°C). For small strains the merino and nylon fibers displayed behavior characteristic of linear viscoelastic materials, while Terylene exhibited a degree of nonrecoverable set. It was possible to construct master recovery curves for fibers held bent for different times before release. These curves can be used as a more convenient means of presenting the results. A relationship was found, for each fiber type, between the percentage stress relaxation and the time taken to recover to a given level of set. This relationship appeared to be independent of the experimental conditions employed. Although the fibers were not linear viscoelastic under all conditions, recovery could be roughly predicted from their stress relaxation behavior at the particular test conditions using the Boltzmann superposition principle.
    Additional Material: 5 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 18 (1974), S. 3523-3536 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A generalized form of the equations of linear viscoelasticity is presented which enables theoretical treatment of situations where a material is not at equilibrium with its environment and/or is subjected to a changing environment. These generalized equations are used successfully to predict the recovery behavior of wool and nylon fibers from bending deformations in experiments involving conditions of changing temperature and relative humidity.
    Additional Material: 5 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-2: Polymer Physics 8 (1970), S. 1159-1168 
    ISSN: 0449-2978
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: ESR and electrical conductivity measurements have been made on a recently prepared polymer, polypropiolamide. The polymer was obtained as a fine powder which exhibited a nearly Lorentzian line with a width between derivative maxima of 5.2 ± 0.1 gauss and a g value of 2.0036 ± 0.0005. The signal intensity increased with increasing molecular weight. The signal was retained in a dilute solution in formic acid with a slight narrowing of the line. Permanent changes were produced in the spectra at room temperature by heat treatments of the polymer at temperatures up to 800°K. The changes were similar for samples sealed in tubes containing air, dry nitrogen gas and a vacuum of 3 × 10-5 mm of Hg. Spectra obtained at temperatures up to 500°K showed no dependence on the presence or absence of oxygen in the ambient atmosphere. The deresistance of pressed pellets of the polymer was measured in the temperature range 450°K to 525°K, and the results were described by the relation R = R0cE/kT. The activation energy E had a value of 1.2 ± 0.2 ev and the resistivity at 500°K was approximately 1013 ohm-em. The ESR signal is attributed to an intrinsic property of the polymer which is associated with a conjugated bond system along the polymer backbone. Neither the activation energy nor the magnitude of the resistivity suggest that the delocalized electrons associated with the conjugated bond system have produced unusual electrical characteristics in the polymer.
    Additional Material: 8 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Biopolymers 9 (1970), S. 445-457 
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The change in apparent molal volume φ of DNA on thermal denaturation in carbonate buffer at pH 11.0 has been determined by the dilatometric method. It was found that φ increases sigmoidally during the helix-coil transition. Several methods, including a colorimetric technique that closely simulates the conditions used in the dilatometric experiments, were employed to estimate the protons lost by the DNA during the transition. These measurements indicated that the extent of the proton loss depends on the counterion present, increasing in the order Li+ 〈 Na+ 〈 K+ 〈 Cs+. The major part of the volume changes observed during the denaturation is due to the volume changes expected to accompany the transfer of protons from the bases guanine and thym ne to carbonate ions. As has been previously reported for the denaturation of DNA at neutral pH, the volume change directly due to the change in shape of the polymer molecules is so small as to be experimentally undetectable.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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