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  • Wiley-Blackwell  (16)
  • Cambridge University Press  (3)
  • BioMed Central
  • 1995-1999  (13)
  • 1970-1974  (6)
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Year
  • 1
    Electronic Resource
    Electronic Resource
    Thiophosphoryl disulfides: Novel coupling agents for styrene-butadiene rubber/carboxylated nitrile rubber blends (1995)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 58 (1995), S. 981-993 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Thiophosphoryl disulfide was successfully used as a novel coupling agent to form a coherent blend comprising polar carboxylated nitrile rubber (XNBR) and nonpolar styrene-butadiene rubber (SBR) establishing close proximity between them through chemical bridging. The study reveals that XNBR in the presence of thiophosphoryl disulfide greatly improves the physical properties of SBR and thus acts as a reinforcing filler. It is noted that the physical properties of the vulcanizates obtained from the SBR-XNBR blend depend upon the SBR : XNBR ratio and the mode of cure. SEM studies corroborate the observed facts. © 1995 John Wiley & Sons, Inc.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1995.070580604
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  • 2
    Electronic Resource
    Electronic Resource
    Cure synergism in XNBR vulcanization in presence of thiophosphoryl disulfides and amine disulfide/thiazole accelerators (1996)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 60 (1996), S. 1349-1359 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The study deals with the vulcanization of carboxylated nitrile butadiene rubber (XNBR) having synergistic combinations of accelerators comprising thiophosphoryl disulfide as one of the components. Other constituent accelerators employed in the present investigation are 2-mercaptobenzothiazole (MBT), 2-mercaptobenzothiazyl disulfide (MBTS), bis(N-oxydiethylene)disulfide (ODDS), N-oxydiethylene 2-benzothiazole sulfenamide (OBTS), etc. The binary combinations of thiophosphoryl disulfides with OBTS exhibited the highest mutual activity in the respective areas, so far as the physical properties are concerned. Structural characterization of different thiophosphoryl disulfide-accelerated XNBR vulcanizates, including those formed from the synergistic combinations with OBTS, were studied using a methyl iodide probe. It was found that the amount of sulfidic crosslinks arising from the reaction between —COOH groups of XNBR and thiophosphoryl disulfides, actually controls the network structure as wellas the physical properties of the vulcanizates. © 1996 John Wiley & Sons, Inc.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Polymer-anchored metal complexes. III. Preparation, structural, thermal stability, dielectric, and conductivity characterization of polycondensates from Cu(II)-1, 10-phenanthroline and trimellitic anhydride/pryromellitic dianhydride (1995)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 56 (1995), S. 501-508 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Trimellitic anhydride and pyromellitic dianhydride have been polycondensed with Cu(II)-phenanthroline complex as a comonomer in the presence of anhydrous ZnCl2 under selective conditions. Elemental diffuse reflectance and infrared spectroscopic and X-ray diffraction (XRD) analysis data of these polymers have been correlated with the tentative structure Proposed for these polycondensates. Thermal stability and dielectric and conductivity characteristics of these polycondensates have been evaluated to understand the effect of the ligand and the anhydride moieties on these properties. Unlike the polymer-anchored 3d-metal complexes, these polycondensates fail to initiate the cationic polymerization of N-vinylcarbazole. © 1995 John Wiley & Sons, Inc.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1995.070560412
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  • 4
    Electronic Resource
    Electronic Resource
    Polymer anchored metal complexes. IV. X-ray photoelectron spectroscopic analysis of a polycondensate from Cu(II) 1, 10 phenanthroline and pyromellitic dianhydride (1996)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 61 (1996), S. 719-723 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Ferric chloride-initiated polymerization of pyrrole in presence of N-vinyl carbazole in aqueous suspension (1996)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 60 (1996), S. 143-146 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Additional Material: 4 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    A modeling study of anaerobic biofilm systems: I. Detailed biofilm modeling (1995)
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 46 (1995), S. 43-53 
    Details
    ISSN: 0006-3592
    Keywords: acetate ; anaerobic biofilms ; mass transfer ; pH ; biofilm modeling ; Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A detailed model acetate-utilizing methanogenic biofilms accounting for the diffusion of neutral and ionic species, chemical equilibrium, electroneutrality, gas production within the biofilm, pH-dependent Monod kinetics, and the presence of a concentration boundary layer is presented. The model qualitatively fits the pH profiles that are reported for acetate-utilizing methanogenic aggregates. A sensitivity analysis on the biological parameters showed that the flux of acetate is sensitive to the maximum utilization rate, half-saturation constant, and biofilm density for the bulk conditions investigated. Criteria when traditional biofilm models can be used to predict the flux of acetate into the biofilm are established. If the maximum pH change predicted using a hypothetical system is within ±0.05, the traditional model predicts the flux to within ±5% of the value calculated with the model developed in this study. © 1995 John Wiley & Sons, Inc.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/bit.260460107
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  • 7
    Electronic Resource
    Electronic Resource
    A modeling study of anaerobic biofilm systems: II. Reactor modeling (1995)
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 46 (1995), S. 54-61 
    Details
    ISSN: 0006-3592
    Keywords: anaerobic biofilm ; CSTR ; reactors, nonide ; pH ; plug-flow reactors ; biofilm modeling ; Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A rigorous steady-state model of anaerobic biofilm reactors taking into account acid-base and gas-phase equilibria in the reactor in conjunction with detailed chemical equilibria and mass transfer in acetate-utilizing methanogenic biofilms is presented. The performances of ideal completely stirred tank reactors (CSTRs) and plug-flow reactors, as well as reactors with nonideal hydraulic conditions, are simulated. Decreasing the surface loading rate increases the acetate removal efficiency, while decreasing the influent pH and increasing the buffering capacity improves the removal efficiency only if the bulk pH of the reactor shifts toward more optimal values between 6.8 to 7.0. The reactor can have negative or positive removal efficiencies depending on the start-up conditions. The respiration coefficient plays a critical role in determining the minimum influent pH required for reactor recovery after failure. Having multiple CSTRs-in-series generally increases the overall removal efficiency for the influent conditions investigated. Monitoring of the influent feed quality is critical for plug-flow reactors, becasue failure of the initial sections of the reactor may cause a cascading effect that may lead to a rapid reactor failure. © 1995 John Wiley & Sons, Inc.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/bit.260460108
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  • 8
    Electronic Resource
    Electronic Resource
    Disturbance of metachromasia of dye/polyanion systems by stoichiometric amounts of cetylpyridinium chloride (1972)
    New York : Wiley-Blackwell
    Die Makromolekulare Chemie 151 (1972), S. 121-125 
    Details
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Die Störung der Metachromasie eines an einem Polyanion gebundenen Farbstoffs durch Cetylpyridiniumchlorid (CPCl) wurde quantitative abgeschätzt, indem die in der wässerigen Schicht verbliebenen Farbstoffmengen nach Schütteln der metachromatischen Lösung mit Tetrachlorkohlenstoff in An- und Abwesenheit von CPCl ermittelt wurden. Die Aufhebung der Metachromasie wurde außerdem aus der konduktometrischen Titration der Farbstoff/Polyanion-Lösung mit CPCl ermittelt. CPCl verdrängt die Farbstoffionen von den Polyanionen beinahe stöchiometrisch, was bei Natriumchlorid nicht der Fall ist. Dieses besondere Verhalten von CPCl wird seiner Neigung zur Bildung hydrophober Bindungen zugeschrieben. Es wurden Methylenblau und Kristallviolett als Farbstoffe sowie Chondroitinschwefelsäure und Heparin als Polyanionen verwendet
    Notes: The disturbance of metachromasia of a dye/polyanion system by cetyl pyridinium chloride (CPCl) has been estimated quantitatively from the difference of the amounts of dye left in the aqueous layer after carbon tetrachloride extraction of the metachromatic solution in the presence and absence of CPCl, as well as from conductometric titration of the dye/polyanion solution with CPCl. Results show that CPCl, unlike sodium chloride, displaces the dye ions from the polyanions almost stoichiometrically. This special behaviour of CPCl has been assigned to its tendency to form hydrophobic bonds. As dyes methylene blue and crystal violet, as polyanions chondroitin sulfate and heparin have been used.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/macp.1972.021510109
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  • 9
    Electronic Resource
    Electronic Resource
    Polymerization of N-vinylcarbazole by (3d)-transition metal oxides (1973)
    New York : Wiley-Blackwell
    Die Makromolekulare Chemie 163 (1973), S. 37-43 
    Details
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Die Substanzpolymerisation von N-Vinylcarbazol (NVC) wurde mit 3d-Metalloxid-Katalysatoren durchgeführt, und die folgende Reaktivitätsreihe für die untersuchten Oxide wurde vorgeschlagen: \documentclass{article}\pagestyle{empty}\begin{document}$$ {\rm V}_{\rm 2} {\rm O}_{\rm 5} {\rm 〉 MnO}_{\rm 2} {\rm 〉 TiO}_{\rm 2} {\rm 〉 Cr}_{\rm 2} {\rm O}_{\rm 3} {\rm 〉 NiO 〉 ZnO 〉 Cu}_{\rm 2} {\rm O 〉 CuO 〉 Co}_{\rm 3} {\rm O}_{\rm 4} {\rm andCoO} $$\end{document} wobei die Oxide des Kupfers und Kobalts nicht wirksam sind. Einige kinetische Untersuchungen wurden mit dem System NVC/MnO2 ausgeführt. Auf Grund der Verzögerung der Polymerisationsgeschwindigkeit bei Gegenwart von Wasser oder Thiophen wurde ein kationischer Mechanismus für die Polymerisation vorgeschlagen. Die Wirkungslosigkeit der Kupfer- und Kobaltoxide als Katalysatoren wurde vorläufig mit der Annahme gedeutet, daß sie eher oxydierend wirken als durch π-Komplex-Bindung. Rühren übt keinen Einfluß auf die Polymerisationsgeschwindigkeit aus.
    Notes: The bulk polymerization of N-Vinylcarbazole (NVC) is carried out using some 3 d-metal oxides as catalysts and the following order of reactivity is suggested for the various metal oxides studied: \documentclass{article}\pagestyle{empty}\begin{document}$$ {\rm V}_{\rm 2} {\rm O}_{\rm 5} {\rm 〉 MnO}_{\rm 2} {\rm 〉 TiO}_{\rm 2} {\rm 〉 Cr}_{\rm 2} {\rm O}_{\rm 3} {\rm 〉 NiO 〉 ZnO 〉 Cu}_{\rm 2} {\rm O 〉 CuO 〉 Co}_{\rm 3} {\rm O}_{\rm 4} {\rm andCoO} $$\end{document} the oxides of copper and cobalt being ineffective. Some kinetic studies are carried out with the NVC/MnO2 system. Endorsed by the observed retardation of the rate in the presence of water and thiophene a cationic mechanism is suggested for the polymerization. The incapability of the oxides of Cu and Co to act as good catalysts is tentatively explained by supposing that they act as oxidizing rather than π-complexing polymerization catalysts. Stirring does not show any influence on the rate of polymerization.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/macp.1973.021630103
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  • 10
    Electronic Resource
    Electronic Resource
    Gas treatment in trickle-bed biofilters: Biomass, how much is enough? (1997)
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 54 (1997), S. 583-594 
    Details
    ISSN: 0006-3592
    Keywords: trickle-bed biofilter ; mathematical model ; volatile organic compound (VOC) ; waste gas treatment ; biofiltration ; Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The objective of this article is to define and validate a mathematical model that desribes the physical and biological processes occurring in a trickle-bed air biofilter for waste gas treatment. This model considers a two-phase system, quasi-steady-state processes, uniform bacterial population, and one limiting substrate. The variation of the specific surface area with bacterial growth is included in the model, and its effect on the biofilter performance is analyzed. This analysis leads to the conclusion that excessive accumulation of biomass in the reactor has a negative effect on contaminant removal efficiency. To solve this problem, excess biomass is removed via full media fluidization and backwashing of the biofilter. The backwashing technique is also incorporated in the model as a process variable. Experimental data from the biodegradation of toluene in a pilot system with four packed-bed reactors are used to validate the model. Once the model is calibrated with the estimation of the unknown parameters of the system, it is used to simulate the biofilter performance for different operating conditions. Model predictions are found to be in agreement with experimental data. © 1997 John Wiley & Sons, Inc. Biotechnol Bioeng 54: 583-594, 1997.
    Additional Material: 8 Ill.
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