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  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 29 (1983), S. 854-858 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Following secondary recovery processes in conventional light oil reservoirs, more than half the original oil in place may remain trapped as a discontinuous phase. During the previous recovery processes these oil ganglia have been pinched off by capillary forces and remain immobile while the continuous phase which surrounds them is able to flow freely. Furthermore if a portion of this oil is mobilized in a tertiary recovery process the conditions required to apply Darcy's equation to the flow of either phase are violated. These are also problems which are encountered during in-situ recovery techniques in tar sands where the mobilization of the heavy oil occurs as a discontinuous phase. In this paper the relevant flow equations are derived. Also a parameter is deduced which directly determines the criterion for mobilization.
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 26 (1980), S. 174-174 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 26 (1980), S. 832-839 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: For gas absorption accompanied by two consecutive second-order reactions, the reaction factors of the film and penetration theories were solved by the orthogonal collocation method. For equivalent definition of the other physico-chemical parameters, the reaction factors from the two theories differ only slightly. In film theory, it is shown that the film-bulk boundary condition is of importance only for small values of M. It is also shown that the difference between the point yields of the film and penetration theories is generally small, although it is larger than the difference in reaction factors for the two theories.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 26 (1980), S. 910-916 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A number of approaches to the optimal selection of sensor locations are presented, and some of these are applied to determine optimal thermocouple positions in a packed bed tubular reactor. As expected, the optimal locations were found to be those surrounding the hot spot location. The theory also revealed that for good state estimation and for goodlinear quadratic control of the reactor, only one or two well located temperature measurements are necessary rather than the entire temperature profile.
    Additional Material: 3 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 27 (1981), S. 489-495 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The discrimination of the fast second-order, pseudo-first-order and fast pseudo-first-order reaction models on the basis of the second-order reaction model justifies the use of the pseudo-first-order model in the prediction of the multiplicity regions. The use of the fast second-order reaction model leads to a certain pitfall regarding uniqueness and multiplicity. Finally, the use of the fast pseudo-first-order reaction model is justifiable not only because of the fair agreement between the multiplicity regions predicted by this model and the second-order model but also because of the analyticity of the uniqueness and multiplicity regions obtained by this model.
    Additional Material: 15 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 27 (1981), S. 613-619 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The objective of this paper is to point out the relationship between the relative gain array (RGA) and control system stability and design. Rigorous stability limits are presented for a general 2 × 2 system for several cases involving both steady state and dynamic interactions. These stability limits explicity involve the RGA. Two specific examples of interaction in distillation models are also discussed.
    Additional Material: 5 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 27 (1981), S. 481-489 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Steady-state behavior of a non-adiabatic gas-liquid CSTR is classified applying a second-order reaction model without any limitation on the reaction regime. Uniqueness and multiplicity regions are determined in the parameter space of reactivity versus liquid residence time, with the ignition and extinction points explicitly shown. An isola with five steady states is found possible for the adiabatic reactor; however, even a small heat loss reduces the number of steady states to three.
    Additional Material: 10 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 28 (1982), S. 714-720 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Experimental results for instantaneous and time-averaged local heat transfer coefficients, as well as local voidage and pressure are used to validate the Adams-Welty analytical model of heat transfer to a horizontal cylinder in large-particle fluidized beds. Results support the main assumptions of the model and show that the range of applicability is wider than originally expected.
    Additional Material: 11 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 29 (1983), S. 215-221 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The relation between the velocity and concentration fields for a fully developed turbulent flow which transfers mass to a pipe wall at large Schmidt numbers has been studied. Measurements of the fluctuations of the concentration gradient and the velocity gradient were obtained simultaneously at multiple locations on the wall. Spatial scales were calculated for the low frequency velocity fluctuations by passing the measured signals through low-pass filters. These scales are the same size as the scales of the concentration fluctuations. This result provides additional support for the notion that mass transfer to a boundary at high Schmidt numbers in controlled by low frequency velocity fluctuations which contain only a small fraction of the total turbulent energy.
    Additional Material: 13 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 27 (1981), S. 111-120 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A steady-state model is developed for a nonadiabatic bubble column with fast pseudo-nth-order reactions. A priori bounds are obtained for steady-state temperature and conversion, and analytic necessary and sufficient criteria are derived for the prediction of uniqueness and multiplicity of the steady states as a function of system physico-chemical parameters. For the special case of pseudo-first-order reactions, the occurrence of multiple steady states is shown to be more possible in a bubble column than in a gas-liquid CSTR for equivalent system parameters.
    Additional Material: 13 Ill.
    Type of Medium: Electronic Resource
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