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  • Wiley-Blackwell  (6,007)
  • American Meteorological Society
  • 1980-1984  (6,784)
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  • 1
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Physics Edition 21 (1983), S. 859-868 
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The primary objective of this work is to check the utility of vapor-pressure osmometry as an experimental technique in obtaining thermodynamic data on polymer/solvent systems. The second objective is to obtain experimental values for the exchange energy parameters ΔP, X, and ζ of the theory of Sanchez and Lacombe. With respect to the first objective, solvent activities of polyiso-butylene/benzene mixtures have been measured at several concentrations up to 600 g/kg of the solvent and at two temperatures. From the activities, it is possible to determine free energies, entropies, and enthalpies and their concentration dependence. Satisfactory agreement has been found between the results obtained and data provided by other techniques such as membrane osmometry and the Cahn electrobalance. These and other data obtained by inverse gas chromatography for the same mixture in the range 35-200°C have been used in calculating the exchange energy parameter of the lattice fluid theory at different concentrations and temperatures.
    Additional Material: 2 Ill.
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  • 2
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    Journal of Biomedical Materials Research 15 (1981), S. 73-82 
    ISSN: 0021-9304
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine , Technology
    Notes: The interfacial shear properties of bone tissue growth into porous coated Ti-6A1-4V femoral implants have been examined as a function of the pore size of the porous surface. Three particle size range powders (297 μm, 420-500 μm, 595-707 μm) were used to fabricate cylindrical implants which were inserted into the femoral medullary canal of dogs for 6 months. Push-out tests on the removed femurs are reported and reveal: (i) that those implants residing in cortical bone exhibited significantly higher shear properties than the equivalent implants in cancellous bone and (ii) that the interfacial shear strength and stiffness decreased with increasing pore diameter within the range 175-325 μm. The extent of bone ingrowth into the surface of the implants was measured using quantitative optical microscopic techniques. This indicated that the percentage of bone which had grown into the surface was inversely proportional to the square root of the pore size and that further the shear properties of the interface were proportional to the extent of bone in-growth.
    Additional Material: 9 Ill.
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  • 4
    ISSN: 0021-9541
    Keywords: Life and Medical Sciences ; Cell & Developmental Biology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Medicine
    Notes: We have compared the subcellular sites of H2O2 and presumably also superoxide-(O2-) production, and certain aspects of metabolic responses (O2 consumption, O2- production) of stimulated neutrophils from human blood and those elicited into guinea pig peritonea. Stimulation was accomplished with either opsonized zymosan or phorbol-12-myristate-13-acetate (PMA). Striking quantitative differences were observed between these cell types with regard to the increased respiration and O2- production observed during stimulation. These differences were most apparent when opsonized zymosan served as the stimulating agent. They were minimized when the soluble stimulating agent, PMA, was used. With either stimulus, the subcellular sites of H2O2 production were the same for both types of neutrophils, i.e., the plasmalemma and phagosomal membranes. No H2O2 production could be detected cytochemically in the absence of stimulation.Treatment of both unstimulated human blood and elicited guinea pig peritoneal neutrophils with the nonpenetrating, covalently linking reagent, p-diazobenzenesulfonic acid, failed to diminish O2- production upon subsequent stimulation, in contrast to a previous report. These data are discussed in terms of the possible cytological arrangements of the respiratory enzyme(s), and the different modes of stimulation of neutrophil metabolism by various agents. Ancillary data on elicited mouse peritoneal neutrophils are presented.
    Additional Material: 9 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 27 (1981), S. 937-945 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Mathematical models have been developed for the design of bubble column slurry reactors, wherein the solids take part in the reaction and follow the shrinking core model. The cases of liquid film control, ash diffusion control, and chemical reaction control have been analyzed. Experiments were performed in a 22.2 mm i.d. continuous cocurrent bubble column slurry reactor for the removal of pyritic sulfur by oxidation from aqueous slurries of Upper Freeport, Lower Freeport, Kentucky No. 9, and Pittsburgh seam coals, in the temperature range of 430-480°K at 6.8 MPa total pressure. The theoretical predictions are found to be in good agreement with experimental results.
    Additional Material: 9 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    Surface and Interface Analysis 6 (1984), S. 174-183 
    ISSN: 0142-2421
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Physics
    Notes: Secondary ion mass spectrometry and glow discharge optical spectrometry are used to determine the depth profiles of Ni and Fe matrices implanted with B and P. These measurements enable the emission yields of secondary ions (for SIMS) or photons (for GDOS) emitted under ion bombardment to be quantified and consequently the implanted samples can be used as standards. The profiles obtained by both methods are in good agreement and independant of the surface roughness. They are compared to real distributions determined by Rutherford backscattering (RBS) and to theoretical ones predicted by the model of Winterbon, Sigmund and Sanders; the concentrations measured at the maximum of the distribution are smaller then the theoretical ones and the experimental profiles are wider than those given by the theory. The causes of the alterations in the profiles are discussed and the surface contamination of the samples is studied by mean of GDOS profiles.
    Additional Material: 8 Ill.
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  • 7
    ISSN: 0323-7648
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Determination of the particle size in PVC latices at average particle diameters smaller than 40 nm is achieved by ultracentrifugation combined with strioscopic detection. Bimodal distributions having maxima above and below 40 nm can be characterized by ultracentrifugation and separate detection by turbidimetric and strioscopic methods. Ultracentrifugation, electron microscopy, light scattering and turbidimetry provide comparable particle diameters of monomodal latices for corresponding average values.
    Notes: Die Bestimmung der Größe von PVC-Latexteilchen mit mittleren Teilchendurchmessern kleiner 40 nm gelingt durch Ultrazentrifugation mit schlierenoptischer Detektion. Bimodale Latices mit Verteilungsmaxima oberhalb und unterhalb 40 nm können durch Ultrazentrifugation und getrennte Detektion mittels Trübungsmessung und Schlierenoptik charakterisiert werden. Ultrazentrifugation, Elektronenmikroskopie, Lichtstreuung und Trübungsmessung führen bei monomodalen Latices für vergleichbare Mittelwerte zu gleichen mittleren Teilchendurchmessern.
    Additional Material: 2 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 2 (1982), S. 209-219 
    ISSN: 0271-2091
    Keywords: First Order Equation ; Hyperbolic Conservation Equation ; Discontinuous Solutions ; Least Squares ; Finite Differences ; Finite Elements ; Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Least square methods have been frequently used to solve fluid mechanics problems. Their specific usefulness is emphasized for the solution of a first-order conservation equation. On the one hand, the least square formulation embeds the first-order problem into equivalent second-order problem, better adapted to discretization techniques due to symmetry and positive-definiteness of the associated matrix. On the other hand, the introduction of a least square functional is convenient for finite element applications.This approach is applied to the model problem of the conservation of mass (the unknown is the density ρ) in a nozzle with a specified velocity field (u, v), possibly including jumps along lines simulating shock waves. This represent a preliminary study towards the solution of the steady Euler equations.A finite difference and a finite element method are presented. The choice of the finite difference scheme and of a continuous finite element representation for the groups of variables (ρu, ρv) is discussed in terms of conservation of mass flux. Results obtained with both methods are compared in two numerical tests with the same mesh system.
    Additional Material: 8 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 18 (1980), S. 3069-3080 
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Nucleophilic displacement of activated aromatic nitro groups with aryloxy anion is a versatile and useful reaction for the synthesis of aromatic ethers. Preparation of various aromatic monomers and polymers containing ether linkages is described.
    Additional Material: 6 Tab.
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  • 10
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 11 (1984), S. 535-538 
    ISSN: 0306-042X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: It is shown that a fast evaluation of field desorption mass spectrometric profiles can be obtained, using quotient spectra and calculation of quotient weight factors. The characteristics of a program developed for this purpose are described and as an example this approach has been applied to detect metabolites in urine samples.
    Additional Material: 2 Ill.
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