ISSN:
1573-9171
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Conclusions 1. The retention factors of 44 thioacetals, 5 thioketals, and 20 α,ω-bis(alkylthio)alkanes have been determined on four phases with differing polarity at 130°C. 2. Equations correlating the retention factors with the number of carbon atoms in the n-alkyl chain have been found for 13 homologous series of sulfur-containing compounds. 3. The energy contributions made by the sulfur atoms in -S(CH2)XS- and -SCH2S- groups to the differential molar free energy of solution have been determined from the retention factors and compared with the contributions made of -S- in sulfides and -SS- in disulfides.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00949217
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