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  • 1
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 89 (1988), S. 1203-1204 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Spin–lattice relaxation times for chlorine and deuterium isotopes in NH4ClO4 and ND4ClO4 have been measured over the temperature range 153 to 295 K. No evidence in support of the hypothesis that there is a phase transition near 180 K has been found in the results.
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  • 2
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 87 (1987), S. 5040-5041 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Specific heat measuremnts on high transition temperature perovskite superconductor were conducted from 5.3 K to 345 K. The sample was prepared by mixing stoichiometric amounts of Yttrium oxide, BaO, and CuO so as to yield a 1:2:3 ratio of metals. T he decrease in specific heat at the transition temperature - 91 K is discussed.(AIP)
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  • 3
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 91 (1989), S. 399-407 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The heat capacity of the orthorhombic salt: deuterated ammonium perchlorate, ND4 ClO4 , was measured from 7 to 345 K using adiabatic calorimetry. The heat capacity against temperature curve is smooth, continuous and without anomaly. Values of the standard molar thermodynamic quantities are presented up to 340 K. The heat capacities of ND4 ClO4 and NH4 ClO4 have been analyzed. The contributions to the vibrational heat capacity from the external optical modes of NH+4 or ND+4, ClO−4 and libration from the external modes of ClO−4 along with those of vibration from the internal optical modes of NH+4 or ND+4 and ClO−4, and the acoustic lattice modes for these ions have been calculated. The difference between the experimental and calculated heat capacity, called the residual heat capacity, equals the contribution from ammonium ion rotation and the thermal expansion of the lattice. With recent thermal expansion data, the correction from constant stress to constant strain has been applied and the derived rotational heat capacities of the NH+4 and ND+4 are determined to be in qualitative agreement with those derived from various rotational models.
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  • 4
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Review of Scientific Instruments 58 (1987), S. 928-931 
    ISSN: 1089-7623
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
    Notes: We investigate the factorial moments and photon correlation properties of two Sharp Corporation 780-nm laser diodes and assess their suitability for use in photon counting and correlation experiments.
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  • 6
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 85 (1986), S. 5963-5970 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: An analysis of the heat capacity of deuterated and undeuterated NH4ReO4 has been carried out in which the effects of the anisotropy of the thermal expansion have been considered, an approach hitherto not used for ammonium compounds. In the ammonium scheelites, the axial thermal expansion coefficients are very large, but of opposite sign, and as a result the volume of the scheelite lattice is nearly independent of temperature. It is shown that the correction from constant stress to constant strain results in a major contribution to the heat capacity of this highly anisotropic lattice. The difference between the experimental and calculated values of heat capacity, referred to as ΔCp, is expressed as the sum of the contributions from the anisotropy and the rotational heat capacity. The results of the analysis show that the rotational contribution is much smaller then previously thought. However, the exact contribution of the anisotropy cannot be calculated at this time because the elastic constants are not known. In calculating the heat capacity, maximum use has been made of external optical mode frequencies derived from spectroscopic measurements.
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  • 7
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Very low resistance nonalloyed ohmic contacts of Pt/Ti to 1.5×1019 cm−3 Zn-doped In0.53Ga0.47As have been formed by rapid thermal processing. These contacts were ohmic as deposited with a specific contact resistance value of 3.0×10−4 Ω cm2. Cross-sectional transmission electron microscopy showed a very limited interfacial reacted layer (20 nm thick) between the Ti and the InGaAs as a result of heating at 450 °C for 30 s. The interfacial layer contained mostly InAs and a small portion of other five binary phases. Heating at 500 °C or higher temperatures resulted in an extensive interaction and degradation of the contact. The contact formed at 450 °C, 30 s exhibited tensile stress of 5.6×109 dyne cm−2 at the Ti/Pt bilayer, but the metal adhesion remained strong. Rapid thermal processing at 450 °C for 30 s decreased the specific contact resistance to a minimum with an extremely low value of 3.4×10−8 Ω cm2 (0.08 Ω mm), which is very close to the theoretical prediction.
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  • 8
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 66 (1989), S. 4640-4644 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The fabrication and performance characteristics of a wide-bandwidth InGaAsP laser diode structure are described. The wide bandwidth is achieved using semi-insulating Fe-doped InP current blocking layers around the active region. The lasers have a bandwidth of 18 GHz at 20 mW, emit 50 mW in a single transverse and longitudinal mode, have rise and fall times of less than 40 ps, have low chirp (FWHM〈1 A(ring)) under modulation, and exhibit harmonic distortion characteristics in agreement with fundamental calculations using a rate equation model. Error-free transmission with no dispersion penalty has been obtained using these lasers in a transmission experiment at 8 Gb/s over 76 km of fiber.
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  • 9
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 65 (1989), S. 4319-4323 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Nonalloyed ohmic contacts of Pt/Ti to 5×1018 cm−3 doped p-InGaAsP (λg =1.3 μm) have been fabricated by rapid thermal processing of sputtered and e-gun-deposited metallizations. While the former as-deposited had a rectifying characteristic, the latter showed ohmic behavior prior to any heat treatment, with a specific contact resistance of 4×10−3 Ω cm2. Rapid thermal processing at temperatures higher than 400 °C caused the formation of ohmic contacts for the sputtered metals also, but with the evaporated metals producing slightly lower contact resistance. The lowest specific contact resistance values of 3.6–5.5×10−4 Ω cm2 for evaporated and sputtered metallizations, respectively, were achieved in both cases as a result of heating at 450 °C for 30 s. These heating conditions produced only a limited reaction at the Ti/InGaAsP interface, which was sharper for the e-gun-deposited contact, but had a significant effect on the stresses in the Ti/Pt bilayer. In both the sputtered and electron gun evaporated samples, the stresses were inverted from tensile as-deposited to compressive with values of 2.4×109 and 1.0×109 dyn cm−2, respectively, as a result of the heat treatment.
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  • 10
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 64 (1988), S. 5305-5307 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Radiation-induced changes in the magnetization of sintered Nd-Fe-B permanent magnets are known to vary widely among specimens produced by different manufacturers. Samples of Nd-Fe-B MAGNEQUENCH magnets, which are made from melt-spun ribbons, have not been studied and show a much reduced sensitivity to neutron irradiation than do sintered Nd-Fe-B magnets. All melt-spun ribbon-based MAGNEQUENCH magnets, i.e., epoxy-bonded, hot-pressed, and die-upset magnets, show essentially the same slow decrease in magnetic remanence with neutron dose. Measurements of the open-circuit remanence Br/Br 0 at various times during the irradiation show a decay of only 1.5% of the preirradiated value for the MAGNEQUENCH magnets after 1 h of irradiation, or a dose of 1.4×1016 neutrons/cm2, compared to a 4.6% drop in remanence for the best sintered Nd-Fe-B magnet (Sumitomo 30H) with the same irradiation dose. Moreover, after 5.3 h of irradiation, the remanence drops by only 3% for the MAGNEQUENCH magnets. Magnets made from melt-spun ribbons are thus the least sensitive to neutron irradiation so far measured for Nd-Fe-B permanent magnets, but are somewhat more sensitive than samarium-cobalt magnets.
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