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  • 2015-2019  (20)
  • 1985-1989  (51)
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  • 1
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Journal of the American Chemical Society 108 (1986), S. 876-880 
    ISSN: 1520-5126
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Review of Scientific Instruments 59 (1988), S. 2158-2162 
    ISSN: 1089-7623
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
    Notes: A method is described whereby a beam of positive hydrogen ions incident at grazing angles on an array of cesium-covered tungsten foils is used to produce H0 and H− particles by negative surface ionization. The results of these experiments indicate that the method can provide diagnostic beams of particles to hot plasmas and can also energy-analyze charge exchange neutrals emerging from hot plasmas.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    Journal of Mathematical Physics 27 (1986), S. 2807-2812 
    ISSN: 1089-7658
    Source: AIP Digital Archive
    Topics: Mathematics , Physics
    Notes: Starting from a Lippmann–Schwinger-type equation, which is very similar to that of quantum mechanical multiple scattering theory, Zeller and Dederichs [Phys. Status Solidi B 55, 831 (1973)] have developed the effective medium theory. This theory has found wide application in understanding the mechanical behavior of disordered solids. However, unlike the problem in quantum mechanics, this equation of the random elasticity is only approximate since this is a linear response theory. So, it is proposed in this work for the first time to go beyond this approximation to treat nonlinear properties of such solids of which the third-order elastic constant is a generic. Again, so far as the nonlinear elastic behavior of these solids is concerned, no work has been done except the simple Voigt- and Reuss-type averaging. Both are extreme approximations and are, moreover, known to lead to violation of the equilibrium condition. The salient feature of the present calculation is to get an exact formal solution of the problem in terms of an appropriate Green's function in a closed form. The result obtained is quite general and may be adopted to treat nonlinearity in any tensor property of disordered materials. Finally several approximations, including a self-consistent solution, have been discussed for obtaining the effective nonlinear static mechanical susceptibility.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 58 (1985), S. 1809-1813 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: A self-consistent solution for the effective elastic properties of polycrystalline and perfectly disordered multiphase composites has been discussed by using the T-matrix method under certain suitable approximations. Compared to the existing formulas these new relations for the disordered composites are very useful in practical situations for a quick and more accurate estimate of the effective elastic properties, in particular for a case where the composite has components with widely different values of the elastic constants. For comparison we have discussed the results based on Kröner's theory which also purports to solve the same problem. It is found that the two solutions do not agree. To resolve the difference we take help of Hill's exact solution of the composite problem when the components have equal rigidities. It is found that while Kröner's theory is inconsistent with the exact result the present self-consistent solution analytically reproduces it. Another interesting finding of the present investigation is that the approximations made in obtaining the self-consistent solution are exact in the limit of composites with equal-shear moduli. Finally it is indicated that although the results for composites have been derived for isotropic and cubic components it can be easily adapted for a composite with noncubic components.
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  • 5
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 57 (1985), S. 1844-1848 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: A simple procedure involving sound velocities in component crystallites has been developed to calculate the effective elastic properties of a hypothetical aggregate which is macroscopically homogeneous but has fluctuations on a microscopic scale, with the underlying assumption that the sound wave can distinguish between the different crystallites oriented at random. For comparison we have also employed the effective medium theory based on a static deformation scheme to calculate the effective elastic properties of the same hypothetical aggregate. Both the procedures use the identical set of input data. Although the assumptions on which the above dynamic and static methods are based are entirely different the results obtained from them for seventeen different aggregates are remarkably close to each other and also to experiments done on polycrystalline specimens using ultrasonic velocities. Finally, a critical discussion of the results and their consequences is presented.
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  • 6
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Annals of the New York Academy of Sciences 451 (1985), S. 0 
    ISSN: 1749-6632
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Natural Sciences in General
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Springer
    Colloid & polymer science 266 (1988), S. 501-508 
    ISSN: 1435-1536
    Keywords: Amorphous polymers ; mechanical properties ; birefringence ; thermal condcutivity ; thermal expansivity
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Uptil now it has not been possible to explain the different physical properties of amorphous polymers using a model based on a single conceptual scheme. In this paper, a phenomenological model is proposed which tries to explain the mechanical, optical and thermal properties (both thermal conductivity and expansivity) of amorphous polymers. The model has similarities with the composite model, proposed by the present authors, which has proved to be successful in interpreting the different physical properties of semicrystalline polymers. The present model considers the bulk form of the polymer as an aggregate of microscopic units possessing intrinsic physical properties. On drawing, the development of anisotropy in different physical properties is supposed to be due to the development of preferred orientation of these units. The development of the preferred orientation has been estimated directly from birefringence data. The agreement between the calculated and experimental values of the elastic modulus, thermal conductivity and thermal expansivity of PVC, PMMA and PS is found to be reasonable good.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Springer
    Heat and mass transfer 24 (1989), S. 169-175 
    ISSN: 1432-1181
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Description / Table of Contents: Zusammenfassung Es wurde eine theoretische Untersuchung der Wärme-, Massen- und Impulsübertragung eines verdampfenden kugelförmigen Fluidtropfens, welcher plötzlich in eine gleichgerichtete Fluidströmung höherer Temperatur eingeleitet wird, untersucht. Das Geschwindigkeitsprofil um den Fluidtropfen herum wurde als konstant und als ein Hadamard-Rybczynski-Profil angenommen. Unter Benutzung eines ADI-Schemas der Finiten-Differenzen-Methode wurden numerische Lösungen der Erhaltungsgleichungen für Energie und Dampfmasse gewonnen. Zeitliche Gesetzmäßigkeiten der durchschnittlichen Nusselt und Sherwood-Zahlen (Nu, Sh) und des Widerstandsbeiwertes (C D ) bis zur vollständigen Verdampfung des Tropfens wurden in Abhängigkeit von den zugehörigen Eingabeparametern nämlich der Anfangs-und momentanen Peclet-Zahl (Pe i ,Pe) der Lewis-Zahl und dem Verhältnis von freier Strömungstemperatur zur Eintrittstemperatur des Tropfens (T a ′ /T i ) berechnet. Ebenso werden die lokalen Nusselt und Sherwood-Zahlen in Abhängigkeit von der Peclet-Zahl im Bereich der stationären Verdampfung dargestellt. Es wurde festgestellt, daß Werte der Nusselt-Zahl im Bereich der stationären Verdampfung von Tropfen in guter Übereinstimmung mit den entsprechenden berechneten Größen aus der empirischen Gleichung von Eisenklam liegen.
    Notes: Abstract A theoretical analysis is made of the heat, mass and momentum transfer from an evaporative liquid sphere which is suddenly introduced into a parallel stream of fluid at a higher temperature. The velocity field around the liquid sphere is assumed to be steady and of the Hadamard-Rybczynski type. Numerical solutions of energy and the vapour mass continuity equations have been carried out using the alternate direction implicit scheme of finite difference method. Temporal histories of the average Nusselt and Sherwood numbers (Nu, Sh) alongwith the drag coefficient (C D ) during the life time of an evaporating drop have been predicted in terms of the pertinent input parameters, namely, initial and instantaneous Peclet number (Pe i ,Pe), Lewis number (Le), and the ratio of free stream to initial droplet temperature (T a ′ /T i ). Variations of local Nusselt and Sherwood numbers withPe, in the region of steady state evaporation, have also been presented. Values ofNu for steady state droplet evaporation are found to be in fair agreement with the corresponding values evaluated from the empirical equation of Eisenklam [5].
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  • 9
    ISSN: 1435-1536
    Keywords: Orientation of polymer chains ; mechanical properties ; birefringence ; deformation scheme
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The computation of the orientational averages is a great problem in the case of semicrystalline polymers. In a previous communication [1] it has been shown that sinθ=f(λ) sinθ′ describes the orientational changes satisfactorily for a certain class of polymers. In this paper some alternative deformation schemes are also discussed. It has been concluded that birefringence provides a useful guideline in the choice of a deformation scheme.
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  • 10
    Electronic Resource
    Electronic Resource
    Springer
    Monatshefte für Chemie 116 (1985), S. 431-436 
    ISSN: 1434-4475
    Keywords: Cyclopentadienyl ; Titanium(IV) complexes ; Conductometric ; IR ; 1H-NMR
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Zusammenfassung Es wurden Titan(IV)-dithiocarbamat-Komplexe vom TypCpTi(S2CNHR)Cl2 undCpTi(S2CNHR)2Cl mitR=C8H5N2S, C9H5N2SCl2 und C9H7N2S mittels der Reaktion von Monocyclopentadienyltitan(IV)trichlorid mit dem Kaliumsalz der entsprechenden Dithiocarbaminsäure in wasserfreiem Dichlormethan dargestellt. Leitfähigkeitsmessungen und IR-Untersuchungen zeigen, daß diese Komplexe Nichtelektrolyte sind, bei denen alle Dithiocarbamat-Liganden zweizähnig sind. Demnach können 5-, bzw. 6-koordinierte Strukturen für die Komplexe des TypsCpTi(S2CNHR)Cl2, bzw.CpTi(S2CNHR)2Cl angenommen werden. Die1H-NMR Spektren zeigen eine rasche Rotation des Cyclopentadienylrings um die Metall-Ring Achse an.
    Notes: Abstract Titanium(IV) dithiocarbamato complexes of the typesCpTi(S2CNHR)Cl2 andCpTi(S2CNHR)2Cl, whereR=C8H5N2S, C9H5N2SCl2 and C9H7N2S, have been prepared by the reaction of monocyclopentadienyl titanium(IV) trichloride with the potassium salt of the appropriate dithiocarbamic acid in anhydrous dichloromethane. Conductance and infrared studies indicate that these complexes are non-electrolytes in which all dithiocarbamate ligands are bidentate. Therefore, 5 and 6 coordinate structures can be assigned toCpTi(S2CNHR)Cl2 andCpTi(S2CNHR)2Cl complexes, respectively.1H-NMR spectra indicate that there is rapid rotation of the cyclopentadienyl ring about the metal ring axis.
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