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  • 1990-1994  (23)
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  • 1
    ISSN: 1573-0581
    Keywords: Accretion model ; oceanic crust ; downhole measurements ; hydrothermalism ; mid-ocean ridge
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract Downhole measurements recorded in the context of the Ocean Drilling Program in Hole 504B, the deepest hole drilled yet into the oceanic crust, are analyzed in terms of accretion processes of the upper oceanic crust at intermediate spreading-rate. The upper part of the crust is found to support the non steady-state models of crustal accretion developed from seafloor observations (Kappel and Ryan, 1986; Gente, 1987). The continuous and vertical nature of borehole measurements provides stratigraphic and structural data that cannot be obtained solely from seafloor studies and, in turn, these models define a framework to analyze the structural, hydrological, and mineralogical observations made in the hole over the past decade. Due to the observed zonation with depth of alteration processes, and its relation to lava morphologies, the 650-m-thick effusive section penetrated in Hole 504B is postulated to be emplaced as the result of two main volcanic sequences. Massive lava flows are interpreted as corresponding to the onset of these sequences emplaced on the floor of the axial graben. The underlying lava made of structures with large porosity values and numerous cm-scale fractures is thus necessarily accreted at the end of the previous volcanic episode. On top of such high heterogeneous and porous intervals, the thick lava flows constitute crustal permeability barriers, thereby constraining the circulation of hydrothermal fluids. Accreted in the near vicinity of the magma chamber, the lower section is that exposed to the most intense hydrothermal circulation (such as black smokers activity). Once capped by a massive flow at the onset of the second volcanic phase, the lower interval is hydrologically separated from ocean-waters. A reducing environment develops then below it resulting, for example, in the precipitation of sulfides. Today, whereas the interval corresponding to the first volcanic episode is sealed by alteration minerals, the second-one is still open to fluid circulation in its upper section. Thus, upper part of the volcanic edifice is potentially never exposed to fluids reaching deep into the crust, while the lower one is near the ridge axis. Considering that most of the extrusives are emplaced within a narrow volcanic zone, the first unit extruded for a given vertical cross-section is necessarily emplaced at the ridge-axis. In Hole 504B, the 250-m-thickTransition Zone from dikes to extrusives is interpreted as the relict massive unit flooding the axial graben at the onset of the first volcanic sequence, and later ruptured by numerous dikes. Further from the axis, the same massive unit constitutes a potential permeability cap for vertical crustal sections accreted earlier. Also, the upper 50 meters of the basement might be considered as the far-end expression of massive outpours extruded near the ridge-axis.
    Type of Medium: Electronic Resource
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  • 2
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    PANGAEA
    In:  Supplement to: Alt, Jeffrey C; Anderson, Thomas F (1991): Mineralogy and isotopic composition of sulfur in layer 3 gabbros from the Indian Ocean, Hole 735B. In: Von Herzen, RP; Robinson, PT; et al. (eds.), Proceedings of the Ocean Drilling Program, Scientific Results, College Station, TX (Ocean Drilling Program), 118, 113-125, https://doi.org/10.2973/odp.proc.sr.118.155.1991
    Publication Date: 2024-01-09
    Description: Sulfide mineralogy, sulfur contents, and sulfur isotopic compositions were determined for samples from the 500-m gabbroic section of Ocean Drilling Program Hole 735B in the southwest Indian Ocean. Igneous sulfides (pyrrhotite, chalcopyrite, pentlandite, and troilite) formed by accumulation of immiscible sulfide droplets and crystallization from intercumulus liquids. Primary sulfur contents average around 600 ppm, with a mean sulfide d34S value near 0 per mil, similar to the isotopic composition of sulfur in mid-ocean ridge basalt glass. Rocks from a 48-m interval of oxide gabbros have much higher sulfur contents (1090-2530 ppm S) due to the increased solubility of sulfur in Fe-rich melts. Rocks that were locally affected by early dynamothermal metamorphism (e.g., the upper 40 m of the core) have lost sulfur, averaging only 90 ppm S. Samples from the upper 200 m of the core, which underwent subsequent hydrothermal alteration, also lost sulfur and contain an average of 300 ppm S. Monosulfide minerals in some of the latter have elevated d34S values (up to +6.9 per mil), suggesting local incorporation of seawater-derived sulfur. Secondary sulfides (pyrrhotite, chalcopyrite, pentlandite, troilite, and pyrite) are ubiquitous in trace amounts throughout the core, particularly in altered olivine and in green amphibole. Pyrite also locally replaces igneous pyrrhotite. Rocks containing secondary pyrite associated with late low-temperature smectitic alteration have low d34S values for pyrite sulfur (to - 16.6 per mil). These low values are attributed to isotopic fractionation produced during partial oxidation of igneous sulfides by cold seawater. The rocks contain small amounts of soluble sulfate (6% of total S), which is composed of variable proportions of seawater sulfate and oxidized igneous sulfur. The ultimate effect of secondary processes on layer 3 gabbros is a loss of sulfur to hydrothermal fluids, with little or no net change in d34S.
    Keywords: 118-735B; DRILL; Drilling/drill rig; Joides Resolution; Leg118; Ocean Drilling Program; ODP; South Indian Ridge, South Indian Ocean
    Type: Dataset
    Format: application/zip, 2 datasets
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  • 3
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    PANGAEA
    In:  Supplement to: Alt, Jeffrey C (1993): Low-temperature alteration of basalts from the Hawaiian Arch, Leg 136. In: Wilkens, RH; Firth, J; Bender, J; et al. (eds.), Proceedings of the Ocean Drilling Program, Scientific Results, College Station, TX (Ocean Drilling Program), 136, 133-146, https://doi.org/10.2973/odp.proc.sr.136.214.1993
    Publication Date: 2024-01-09
    Description: The mineralogy and chemistry of altered basalts and the stable isotopic compositions of secondary vein carbonates were studied in cores from Ocean Drilling Program Hole 843B, located in 95-Ma crust of the Hawaiian Arch. Millimeter- to centimeter-sized dark alteration halos around veins are 5%-15% altered to celadonite and Fe-oxyhydroxides, plus minor saponite and calcite. Adjacent gray host rocks are about 15% altered to saponite and calcite. The dark halos are enriched in H2O+, CO2, FeT, K2O, MnO, and Fe3+/FeT and depleted in SiO2, Al2O3, MgO, and TiO2 relative to gray host rocks. Brown alteration halos occur around veins where veins are more abundant, and are similar to dark halos, but contain more Fe-oxyhydroxides and exhibit greater Fe2O3T contents and higher Fe3+/FeT. Stable isotopic compositions of vein carbonates are consistent with their precipitation from seawater at temperatures of 5°-40°C. Crosscutting relationships of veins and zoned vein and vesicle fillings reveal a sequence of secondary mineral formation and alteration conditions. Celadonite and Fe-oxyhydroxides formed and dark alteration halos developed relatively early, under oxidizing conditions at low temperatures (〈50°C). Saponite formed later at lower seawater/rock ratios and under more reducing conditions. Calcite and pyrite formed last in veins and vesicles from more evolved, seawaterderived fluids at temperatures of 5°-40°C. A second stage of celadonite, with compositions distinct from the early celadonite, also occurred relatively late (within the "calcite stage"), and may be related to refracturing of the crust and introduction of less-evolved seawater solutions into the rocks. Trends to higher K2O contents are attributed to alteration, but high K/Ti, Ba, and Zr contents indicate the presence of enriched or transitional MORB. CO2 contents of Pacific ODP cores exhibit a general increase with age suggesting progressive fixation of CO2 as calcite in the crust, but this could be complicated by local heterogeneities in fracturing and calcite formation in the crust.
    Keywords: 136-843B; DRILL; Drilling/drill rig; Joides Resolution; Leg136; North Pacific Ocean; Ocean Drilling Program; ODP
    Type: Dataset
    Format: application/zip, 3 datasets
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  • 4
    Publication Date: 2024-01-09
    Keywords: 136-843B; Aluminium; Aluminium oxide; Calcium; Calcium oxide; Calculated; Calculated based on oxygen number; Color description; DRILL; Drilling/drill rig; DSDP/ODP/IODP sample designation; Electron microprobe (EMP); Elements, total; Iron 2+; Iron 2+ and 3+; Iron 3+; Iron oxide, FeO; Joides Resolution; Leg136; Magnesium; Magnesium number; Magnesium oxide; Manganese; Manganese oxide; Mineral name; North Pacific Ocean; Ocean Drilling Program; ODP; Potassium; Potassium oxide; Sample code/label; Sample comment; Sample ID; Silicon; Silicon dioxide; Sodium; Sodium oxide; Sum; Titanium; Titanium dioxide
    Type: Dataset
    Format: text/tab-separated-values, 1210 data points
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  • 5
    Publication Date: 2024-01-09
    Keywords: 136-843B; Calculated; DEPTH, sediment/rock; DRILL; Drilling/drill rig; DSDP/ODP/IODP sample designation; Joides Resolution; Leg136; North Pacific Ocean; Ocean Drilling Program; ODP; Sample code/label; Temperature, calculated; δ13C; δ18O
    Type: Dataset
    Format: text/tab-separated-values, 40 data points
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  • 6
    Publication Date: 2024-01-09
    Keywords: 129-801B; 129-801C; DEPTH, sediment/rock; DRILL; Drilling/drill rig; Event label; Joides Resolution; Leg129; North Pacific Ocean; Ocean Drilling Program; ODP; Sample code/label; Sample comment; δ13C, carbonate; δ18O, carbonate; δ18O, silicate
    Type: Dataset
    Format: text/tab-separated-values, 96 data points
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  • 7
    Publication Date: 2024-01-09
    Keywords: 136-843B; Aluminium oxide; Barium; Calcium oxide; Calculated; Carbon dioxide; Chromium; Cobalt; Copper; Coulometric Karl Fischer titration; Coulometry; DEPTH, sediment/rock; DRILL; Drilling/drill rig; DSDP/ODP/IODP sample designation; Elements, total; Iron 2+/Iron total ratio; Iron oxide, Fe2O3; Iron oxide, FeO; Joides Resolution; Leg136; Loss on ignition; Magnesium oxide; Manganese oxide; Nickel; North Pacific Ocean; Ocean Drilling Program; ODP; Phosphorus pentoxide; Potassium oxide; Rubidium; Sample code/label; Silicon dioxide; Sodium oxide; Strontium; Titanium dioxide; Type; Water in rock; X-ray fluorescence (XRF); Yttrium; Zinc; Zirconium
    Type: Dataset
    Format: text/tab-separated-values, 431 data points
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  • 8
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    In:  Supplement to: Alt, Jeffrey C; Burdett, James W (1992): Sulfur in pacific deep-sea sediments (Leg 129) and implications for cycling of sediment in subduction zones. In: Larson, RL; Lancelot, Y; et al. (eds.), Proceedings of the Ocean Drilling Program, Scientific Results, College Station, TX (Ocean Drilling Program), 129, 283-294, https://doi.org/10.2973/odp.proc.sr.129.125.1992
    Publication Date: 2024-01-09
    Description: The mineralogy of S-bearing phases, S-contents, and S-isotopic compositions of sediments and interstitial waters were determined for three cores drilled during Leg 129 in the western Pacific. Pelagic clays, chalks, and radiolarites generally contain 350-1200 ppm S, with essentially all S present as sulfate. Volcanogenic turbidite units contain about 400 ppm S, with about 10%-20% of total sulfur as pyrite-S and the remainder as sulfate. A single claystone from the base of Hole 802A has high pyrite-S content (1200 ppm) and contains a component of metalliferous sediment. The single analyzed chert has the highest sulfur content (4020 ppm) with essentially all sulfur present as pyrite-S. Sulfate in pore waters ranges from seawater concentrations to nearly zero, and has d34S values ranging from seawater values (+20 per mil) to slightly enriched in 34S (+28 per mil). Pyrite sulfur has 34S values of -4.8 per mil to -37.1 per mil. These general trends are attributed to bacterial reduction of seawater sulfate, but the data do not fit simple models for downward diffusion of sulfate or closed-system reduction of buried sulfate. These complications are due to variations in the d34S of seawater sulfate in the past, uptake of sulfate by thaumasite (Ca3Si(OH)6CO3SO4-12H2O) without isotopic fractionation in the Unit II tuff in Hole 802A, the presence of cherts that act as barriers to diffusion, and possible variations in the magnitude of isotopic fractionation during bacterial sulfate reduction. The average sediment from Leg 129 contains around 850 ppm S (85% as sulfate, 15% as sulfide), with a bulk d34S of +12 per mil. The bulk sulfur isotopic composition of deep-sea sediment is highly dependent on the proportion of pyrite-sulfur present, which varies depending on the sedimentary environment and history. The sedimentary sulfur component during subduction thus likely varies from near seawater values (+20 per mil) to possibly strongly negative values (-20 per mil).
    Keywords: 129-800A; 129-801A; 129-801B; 129-801C; 129-802A; DEPTH, sediment/rock; DRILL; Drilling/drill rig; DSDP/ODP/IODP sample designation; Event label; Joides Resolution; Leg129; North Pacific Ocean; Ocean Drilling Program; ODP; Sample code/label; Sample type; Sulfate; Sulfide; Sulfur, total; Sulfur of pyrite; δ34S; δ34S, pyrite; δ34S, sulfate
    Type: Dataset
    Format: text/tab-separated-values, 320 data points
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  • 9
    Publication Date: 2024-01-09
    Keywords: 129-800A; 129-801B; 129-801C; 129-802A; Aluminium oxide; Barium; Caesium; Calcium oxide; Carbon dioxide; Cerium; Chromium; Cobalt; Copper; DEPTH, sediment/rock; DRILL; Drilling/drill rig; DSDP/ODP/IODP sample designation; Dysprosium; Elements, total; Erbium; Europium; Event label; Gadolinium; Gallium; Hafnium; Holmium; Instrumental neutron activation analysis (INAA) (Reimann et al., 1998); Iron oxide, Fe2O3; Iron oxide, FeO; Joides Resolution; Laboratory; Lanthanum; Lead; Lead-206/Lead-204 ratio; Lead-207/Lead-204 ratio; Lead-208/Lead-204 ratio; Leg129; Lithologic unit/sequence; Loss on ignition; Lutetium; Magnesium oxide; Manganese oxide; Neodymium; Neodymium-143/Neodymium-144 ratio; Nickel; Niobium; North Pacific Ocean; Ocean Drilling Program; ODP; Phosphorus pentoxide; Potassium oxide; Praseodymium; Rubidium; Samarium; Sample code/label; Scandium; Silicon dioxide; Sodium oxide; Strontium; Strontium-87/Strontium-86 ratio; Sulfur, total; Tantalum; Terbium; Thorium; Titanium dioxide; Uranium; Vanadium; Water in rock; X-ray fluorescence (XRF); Ytterbium; Yttrium; Zinc; Zirconium
    Type: Dataset
    Format: text/tab-separated-values, 7755 data points
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  • 10
    Publication Date: 2024-01-09
    Keywords: 129-801C; Aluminium (IV); Aluminium (VI); Aluminium oxide; Calcium; Calcium oxide; Calculated based on oxygen number; DRILL; Drilling/drill rig; DSDP/ODP/IODP sample designation; Electron microprobe (EMP); Elements, total; Interlayer charge; Iron 2+ and 3+; Iron oxide, FeO; Joides Resolution; Leg129; Magnesium; Magnesium oxide; Manganese; Manganese oxide; Mineral name; North Pacific Ocean; Ocean Drilling Program; ODP; Potassium; Potassium oxide; Sample code/label; Silicon; Silicon dioxide; Sodium; Sodium oxide; Sum; Titanium; Titanium dioxide
    Type: Dataset
    Format: text/tab-separated-values, 147 data points
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