ISSN:
0009-2940
Keywords:
Zirconium amides, imides
;
Hafnium amides, imides
;
Amides
;
Imides
;
ZrN double bond
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Synthesis and Structures of (Monoorganyl)amides and -imides of Zirconium and HafniumThe tetrahalides MCl4 (M = Zr 1 a, Hf 1 b) react with LiNHtBu with elimination of LiCl to yield [(tBuNH)2MNtBu]2 (3) (M = Zr 3a, Hf 3b). Compounds 3 are thermally instable and oli-gomerise above 100 °C with elimination of H2NtBu. The reactions of (η5-C5Me5)MCl3 (M = Zr 1 c, Hf 1 d) with LiNHR (R = tBu 2 a,2,4,6-Me3C6H2 2 b, 2, 6-iPr2C6H3 2 c) lead to (η5-C5Me5)M(NHR)3 (4) (R = tBu, M = Zr 4 a, Hf 4 b; R = 2, 4,6-Me3C6H2, M = Zr 4 c, Hf 4 d; R = 2,6-iPr2C6H3, M = Zr 4 e, Hf 4 f). Compounds 4 are thermally very stable and melt without decomposition. When 1 c and 1 d react with LiNHPh (2 d), dimers of composition [(η5-C5Me5)M(NHPh)NPh]2 (M = Zr 5 a, Hf 5 b) are obtained. The complexes (η5-C5Me5)2MCl2 (M = Zr 1 e, Hf 1 f) react with 2 b to form (η5-C5Me5)2M(NHR)2 (6) (M = Zr 6 a, Hf 6 b). Pyridine reacts with 4 e at 85 °C and replaces one molecule of 2,6-iPr2C6H3NH2 to give (η5-C5Me5)Zr-(NHR)NR · Py (7). The single crystal X-ray structures of 4 a, 4 f, 5 b and 7 are described.
Additional Material:
4 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19921250411
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