ISSN:
0009-2940
Keywords:
1,3,2-Diazaborinium Compounds
;
Calculations, AM1
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
1,3,2-Diazaborinium Compounds - New Cationic Boron HeteroarenesThe diazaborinium cation 9 is obtained by the reaction of the vinamidine boron chelate 8 with Et2O - BF3. The cyclic aluminium compound 13 forms with the dichloroboranes RBCl2 (R = Cl, Et, Ph) the cations 15,16a, and 16b. AM1 calculations demonstrate the π interaction of the boron with the nitrogen atoms as well as with the fluoro substituent.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19911241009
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