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  • 1
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Biochemistry 32 (1993), S. 7104-7115 
    ISSN: 1520-4995
    Source: ACS Legacy Archives
    Topics: Biology , Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Copenhagen : International Union of Crystallography (IUCr)
    Acta crystallographica 50 (1994), S. 596-602 
    ISSN: 1399-0047
    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
    Topics: Chemistry and Pharmacology , Geosciences , Physics
    Notes: Cytochrome c2 serves as the secondary electron donor that reduces the photo-oxidized bacteriochlorophyll dimer in photosynthetic bacteria. Cytochrome c2 from Rhodobacter sphaeroides has been crystallized in three different forms. At high ionic strength, crystals of a hexagonal space group (P6122) were obtained, while at low ionic strength, triclinic (P1) and tetragonal (P41212) crystals were formed. The three-dimensional structures of the cytochrome in all three crystal forms have been determined by X-ray diffraction at resolutions of 2.20 Å (hexagonal), 1.95 Å, (triclinic) and 1.53 Å (tetragonal). The most significant difference observed was the binding of an imidazole molecule to the iron atom of the heme group in the hexagonal structure. This binding displaces the sulfur atom of Met l00, which forms the axial ligand in the triclinic and tetragonal structures.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Palo Alto, Calif. : Annual Reviews
    Annual Review of Biochemistry 63 (1994), S. 235-264 
    ISSN: 0066-4154
    Source: Annual Reviews Electronic Back Volume Collection 1932-2001ff
    Topics: Chemistry and Pharmacology , Biology
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Grass and forage science 49 (1994), S. 0 
    ISSN: 1365-2494
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: The effects of transfusing cores of grass silage with mixtures of oxygen and nitrogen containing 0%, 0·2%, 2%, 5% and 20% oxygen were investigated. Changes in populations of yeasts, lactobacilli and streptococci were measured and the relationship between populations after 7 days' transfusion and oxygen concentration were tested against the predictions of two models, based on Monod and logistic growth functions. Yeasts were related to oxygen by the Monod model, while lactobacilli and streptococci were related by the logistic model. The differences were ascribed to yeasts initiating deterioration by growing aerobically, while lactobacilli and streptococci grew fermentatively once the environment had changed following yeast growth. Dry-matter losses were related to oxygen by the Monod model. Changes in temperature were related to dry matter loss (through measurements of CO2 evolution) using a simple heat balance model.
    Type of Medium: Electronic Resource
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  • 5
    ISSN: 1520-4804
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Fatigue & fracture of engineering materials & structures 14 (1991), S. 0 
    ISSN: 1460-2695
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract— It is well known that the fatigue strength of a thick-walled cylinder is enhanced by autofrettage. However, this does not appear to have been explained from fracture mechanics. The present paper shows that two uncertainties arise when this is attempted. Firstly, the distribution of residual stress resulting from the autofrettage pressure must be estimated and secondly a realistic stress intensity factors for subsequent fatigue cracking must be defined. A number of available stress intensity solutions are modified with the author's predictions to the residual stress following an elastic-plastic autofrettage pressure in a closed cylinder of hardening material. A comparison with experiment has enabled the various approaches to be appraised. It is shown that a modified stress intensity factor of Bowie and Freese is most consistent with the propagation fatigue life observed in autofrettaged cylinders provided their solution is adapted to account for the propagation of a semi-elliptical crack front in the presence of residual stress. Other K1 estimates appear to lead to dangerously optimistic predictions particularly within the range of fluctuating pressure where failure occurs between 105 and 106 cycles. The contribution to fatigue failure from initiation cycles is expressed as a power function of the observed life for cyclic pressures in the region of the fatigue limit.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    [S.l.] : International Union of Crystallography (IUCr)
    Acta crystallographica 46 (1990), S. 915-922 
    ISSN: 1600-5724
    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
    Topics: Chemistry and Pharmacology , Geosciences , Physics
    Notes: An initial electron density distribution for a crystal structure may be directly derived from observed diffraction data by maximizing the product of the observed and calculated Patterson functions with respect to the electron density values within an envelope. This maximization problem may be formulated as an eigenvalue equation, in which potential electron density distributions are obtained as eigendensities (eigenvectors) of a symmetric matrix. Elements of this matrix depend only on the indices and intensities of the observed reflections, and on the coordinates of grid points inside the envelope. Eigendensities are calculated for a set of small envelopes (enclosing about 20% of the molecular volume) covering a unique region of the unit cell whose points are unrelated by space-group operations, origin shifts or changes in enantiomorph. On the basis of correlation coefficients between the observed and calculated values for both the Patterson function and structure factor amplitudes, a small set of eigendensities are selected for combination into a final electron density distribution. This electron density distribution may be Fourier transformed to yield calculated structure factors. Test calculations on lysozyme indicate that phase errors of less than 60° may be obtained for strong low-resolution reflections by this procedure. An extension of this approach to handle crystal structures containing non-crystallographic symmetry is described.
    Type of Medium: Electronic Resource
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  • 8
    ISSN: 1432-1157
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract Quantitative tectonic modelling demonstrates an interaction of flexure of the lithosphere underlying the western Betics with crustal thinning in the Alboran Basin and flank uplift in the Internal Zone. In the eastern Betics the flexural response is overprinted by post-thrusting extensional events. Lateral variations in thermal structure and rheology of the lithosphere along strike of the Betics shed light on changes in tectonic configuration and are consistent with evidence for lateral variations in the mode of extension in the Alboran Basin. Flexural modelling and subsidence analysis of Neogene basins in the Internal Zone of the Betics, with spatial development controlled by contrasts in lithosphere rheology, demonstrate that at least two extensional events have affected the orogenic evolution of the Betics. The first event appears to reflect Oligocene-Early Miocene rifting observed throughout the Western Mediterranean. The second phase, which caused the present configuration of the Betics, corresponds to Tortonian-Recent extension centered in the Alboran Basin.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Springer
    Zeitschrift für angewandte Mathematik und Physik 44 (1993), S. 306-313 
    ISSN: 1420-9039
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mathematics , Physics
    Notes: Abstract A two-dimensional, nonlinear, time-dependent, elliptic, numerical method coupled with an appropriate coordinate transformation is used to investigate the stability of free convection induced by an isothermally heated semi-infinite surface embedded in a fluid-saturated porous medium. It is found that the basic boundary layer flow is stable even to large amplitude disturbance for nondimensional distances of up to 1024 from the leading edge of the heated surface.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    [s.l.] : Nature Publishing Group
    Nature 344 (1990), S. 807-807 
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Type of Medium: Electronic Resource
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